Distortion Pathways of Transition Metal Coordination Polyhedra Induced by Chelating Topology

Chemical Reviews

Volumn 115, Issue 24, 2015, Pages 13447-13483

  Alvarez, Santiago ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; GEOMETRY; HYDROGEN BONDS; LIGANDS; METAL COMPLEXES; METALS; SPIN DYNAMICS; TOPOLOGY; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

CONTINUOUS SHAPE MEASURES; COORDINATION POLYHEDRA; DEGREE OF DISTORTION; INTERMOLECULAR HYDROGEN BONDING; INTERMOLECULAR INTERACTIONS; METAL COORDINATION; METAL-LIGAND BONDS; MULTIDENTATE LIGANDS;

COORDINATION REACTIONS;

EID: 84952333763     PISSN: 00092665     EISSN: 15206890     Source Type: Journal    
DOI: 10.1021/acs.chemrev.5b00537     Document Type: Article

References (212)

1. Aguilà, D.; Escribano, E.; Speed, S.; Talancón, D.; Yermán, L.; Alvarez, S. Calibrating the Coordination Chemistry Tool Chest: Metrics of Bi- and Tridentate Ligands Dalton Trans. 2009, 6610-6625 10.1039/b904938j
2. Alvarez, S.; Ruiz, E. Self-Assembly of Coordination Compounds: Design Principles. In Supramolecular Chemistry, From Molecules to Nanomaterials; Steed, J. W.; Gale, P. A., Eds.; John Wiley & Sons: Chichester, U.K., 2012; Vol. 5, pp 1993-2044.
3. Cordero, B.; Gómez, V.; Platero-Prats, A. E.; Revés, M.; Echeverría, J.; Cremades, E.; Barragán, F.; Alvarez, S. Covalent Radii Revisited Dalton Trans. 2008, 2832-2838 10.1039/b801115j
4. Halcrow, M. A. Spin-Crossover Materials: Properties and Applications; John Wiley and Sons: Chichester, U.K., 2013.
5. Real, J. A.; Gaspar, A. B.; Muñoz, M. C. Thermal, pressure and light switchable spin-crossover materials Dalton Trans. 2005, 2062-2079 10.1039/b501491c
6. Shatruk, M.; Phan, H.; Chrisostomo, B. A.; Suleimenova, A. Symmetry-breaking Structural Phase Transitions in Spin Crossover Complexes Coord. Chem. Rev. 2015, 289-290, 62-73 10.1016/j.ccr.2014.09.018
7. Garcia, Y.; Gütlich, P. Thermal Spin Crossover in Mn(II), Mn(III), Cr(II) and Co(III) Coordination Compounds. In Spin Crossover in Transition Metal Compounds II; Gütlich, P.; Goodwin, H. A., Eds.; Springer-Verlag: Heidelberg, 2004; pp 47-62.
8. Goodwin, H. A. Spin Crossover in Co(II) Systems. In Spin Crossover in Transition Metal Compounds II; Gütlich, P.; Goodwin, H. A., Eds.; Springer-Verlag: Heidelberg, 2004; pp 23-47.
9. Gütlich, P. Spin Crossover-Quo Vadis? Eur. J. Inorg. Chem. 2013, 2013, 581-591 10.1002/ejic.201300092
10. Alvarez, S.; Alemany, P.; Casanova, D.; Cirera, J.; Llunell, M.; Avnir, D. Shape Maps and Polyhedral Interconversion Paths Coord. Chem. Rev. 2005, 249, 1693-1708 10.1016/j.ccr.2005.03.031
11. Alvarez, S.; Avnir, D.; Llunell, M.; Pinsky, M. Continuous Symmetry Maps and Shape Classification. The Case of Six-coordinated Metal Compounds New J. Chem. 2002, 26, 996-1009 10.1039/b200641n
12. Zabrodsky, H.; Peleg, S.; Avnir, D. Continuous Symmetry Measures J. Am. Chem. Soc. 1992, 114, 7843-7851 10.1021/ja00046a033
13. Casanova, D.; Cirera, J.; Llunell, M.; Alemany, P.; Avnir, D.; Alvarez, S. Minimal Distortion Pathways in Polyhedral Rearrangements J. Am. Chem. Soc. 2004, 126, 1755-1763 10.1021/ja036479n
14. 6 Configuration Chem.-Eur. J. 2006, 12, 3162-3167 10.1002/chem.200501516
15. Alvarez, S.; Menjón, B.; Falceto, A.; Casanova, D.; Alemany, P. Stereochemistry of Complexes with Double and Triple Metal-Ligand Bonds: A Continuous Shape Measures Analysis Inorg. Chem. 2014, 53, 12151-12163 10.1021/ic5021077
16. Llunell, M.; Casanova, D.; Cirera, J.; Alemany, P.; Alvarez, S. SHAPE (2.1); Universitat de Barcelona: Barcelona, Spain, 2013.
17. Bai, Y.-L.; Tao, J.; Huang, R.-B.; Zheng, L.-S.; Zheng, S.-L.; Oshida, K.; Einaga, Y. Pressure Effects and Mössbauer Spectroscopic Studies on a 3D Mixed-Valence Iron Spin-crossover Complex with NiAs Topology Chem. Commun. 2008, 1753-1755 10.1039/b718456e
18. Chainok, K.; Neville, S. M.; Moubaraki, B.; Batten, S. R.; Murray, K. S.; Forsyth, C. M.; Cashion, J. D. Synthesis, Structures and Spin Crossover Properties of Infinite 3D Frameworks of Iron(II) Containing Organodinitrile Bridging Ligands Dalton Trans. 2010, 39, 10900-10909 10.1039/c0dt00447b
19. Bronisz, R. Tetrazol-2-yl as a Donor Group for Incorporation of a Spin-Crossover Function Based on Fe(II) Ions into a Coordination Network Inorg. Chem. 2007, 46, 6733-6739 10.1021/ic070223r
20. Ozarowski, A.; McGarvey, B. R. EPR study of manganese(II) and copper(II) in single crystals of the spin-crossover complex hexakis(1-propyltetrazole)iron(2+) Inorg. Chem. 1989, 28, 2262-2266 10.1021/ic00311a005
21. 2, and the analogous perchlorates. Their relation to spin crossover behaviour and comparison of Debye-Waller factors from structure determination and Mössbauer Acta Crystallogr., Sect. B: Struct. Sci. 1993, 49, 289-303 10.1107/S0108768192009042
22. 2 J. Appl. Crystallogr. 2004, 37, 589-595 10.1107/S0021889804011720
23. 2 spin-crossover compounds Acta Crystallogr., Sect. B: Struct. Sci. 2012, 68, 40-56 10.1107/S0108768111053298
24. 2 J. Appl. Crystallogr. 2001, 34, 229-238 10.1107/S0021889801000462
25. 2 Metal Complex from Laboratory and Synchrotron X-ray Powder Diffraction Data with Grid-search Techniques Acta Crystallogr., Sect. B: Struct. Sci. 2001, 57, 531-538 10.1107/S010876810100828X
26. 2 Obtained from Synchrotron Powder Diffraction Data Chem.-Eur. J. 2005, 11, 5855-5865 10.1002/chem.200500036
27. Roubeau, O.; Evangelisti, M.; Natividad, E. A Spin Crossover Ferrous Complex with Ordered Magnetic Ferric Anions Chem. Commun. 2012, 48, 7604-7606 10.1039/c2cc33709f
28. 4] Inorg. Chem. 2003, 42, 5645-5653 10.1021/ic034226p
29. Bailar, J. C. Problems in the Stereochemistry of Coordination Compounds J. Inorg. Nucl. Chem. 1958, 8, 165-175 10.1016/0022-1902(58)80179-7
30. Kepert, D. L. Inorganic Stereochemistry; Springer: New York, 1982.
31. Alvarez, S. Relationships Between Temperature, Magnetic Moment and Continuous Symmetry Measures in Spin Crossover Complexes J. Am. Chem. Soc. 2003, 125, 6795-6802 10.1021/ja0283450
32. Cremades, E.; Echeverría, J.; Alvarez, S. The Trigonal Prism in Coordination Chemistry Chem.-Eur. J. 2010, 16, 10380-10396 10.1002/chem.200903032
33. Zhang, R.-H.; Hong, Q.-M.; Yang, J.-M.; Zhang, H.-L.; Blackburnb, G. M.; Zhou, Z.-H. Syntheses, Spectroscopies and Structures of Zinc Complexes with Malate Inorg. Chim. Acta 2009, 362, 2643-2649 10.1016/j.ica.2008.12.001
34. Turner, D. L.; Stone, K. H.; Stephens, P. W.; Vaid, T. P. Cadmium and Zinc Thiolate and Selenolate Metal-organic Frameworks Dalton Trans. 2010, 39, 5070-5073 10.1039/b926156g
35. 113Cd NMR Spectroscopy and Single Crystal X-ray Diffraction Inorg. Chim. Acta 2005, 358, 3165-3173 10.1016/j.ica.2005.04.029
36. Zemskova, S. M.; Glinskaya, L. A.; Klevtsova, R. F.; Fedotov, M. A.; Larionov, S. V. Structure and Properties of Mono-and Heterometallic Cadmium, Zinc, and Nickel Complexes Containing Diethyldithiocarbamate ions and Ethylenediamine Molecules J. Struct. Chem. 1999, 40, 284-292 10.1007/BF02903658
37. 2 [M = zinc(II), cadmium(II)] Complexes Polyhedron 1992, 11, 2951-2956 10.1016/S0277-5387(00)83600-1
38. 3] J. Chem. Soc., Dalton Trans. 1982, 493-503 10.1039/dt9820000493
39. Fan, J.; Zhu, H.-F.; Okamura, T.-a.; Sun, W.-Y.; Tang, W.-X.; Ueyama, N. Discrete and Infinite Cage-Like Frameworks with Inclusion of Anionic and Neutral Species and with Interpenetration Phenomena Chem.-Eur. J. 2003, 9, 4724-4731 10.1002/chem.200305089
40. 2-Pyrazolato Ligands Angew. Chem., Int. Ed. 2002, 41, 1591-1594 10.1002/1521-3773(20020503)41:9<1591::AID-ANIE1591>3.0.CO;2-D
41. 8] Chem.-Eur. J. 2001, 7, 127-138 10.1002/1521-3765(20010105)7:1<127::AID-CHEM127>3.0.CO;2-1
42. Greaney, T. M.; Raston, C. L.; White, A. H.; Maslen, E. N. Crystal Structure of Potassium Tris(acetylacetonato)cadmate(II) Monohydrate J. Chem. Soc., Dalton Trans. 1975, 876-879 10.1039/dt9750000876
43. Gromilov, S. A.; Baidina, I. A.; Prokhorova, S. A.; Stabnikov, P. A. Crystal and Molecular Structure of Monomeric Y(III) Dipivaloylmethanate. Arrangement of Adsorbed Layers J. Struct. Chem. 1995, 36, 496-501 10.1007/BF02578537
44. Rosa, P.; Mézailles, N.; Ricard, L.; Mathey, F.; Le Floch, P. Dianionic Homoleptic Biphosphinine Complexes of Group 4 Metals Angew. Chem., Int. Ed. 2000, 39, 1823-1826 10.1002/(SICI)1521-3773(20000515)39:10<1823::AID-ANIE1823>3.0.CO;2-5
45. Martin, J. L.; Takats, J. Crystal and Molecular Structure of Tetraphenylarsonium Tris(benzenedithiolato)tantalate(V) Inorg. Chem. 1975, 14, 1358-1364 10.1021/ic50148a031
46. 0 Metal Six-coordination: Two Geometrical Isomers of [metal tris(norbornane-exo-2,3-dithiolate)]- (metal = niobium, tantalum) and Their Interconversion J. Am. Chem. Soc. 1989, 111, 7766-7777 10.1021/ja00202a017
47. 3] Inorg. Chem. 1990, 29, 68-73 10.1021/ic00326a014
48. 2S,S′)cuprate(II) Acta Crystallogr., Sect. E: Struct. Rep. Online 2004, 60, m1872-m1874 10.1107/S1600536804027473
49. 10 Metal Complexes of Ethylenediamine Aust. J. Chem. 2005, 58, 578-584 10.1071/CH05109
50. Rây, P.; Dutt, N. K. Kinetics and Mechanism of Racemization of Optically Active Cobaltic Trisbiguanide Complex J. Indian Chem. 1943, 20, 81-92
51. IV Complexes of a Ligand Analogue of Acetylacetonate Inorg. Chem. 2007, 46, 8024-8031 10.1021/ic062473y
52. 3 Z. Anorg. Allg. Chem. 2010, 636, 2422-2432 10.1002/zaac.201000160
53. 2O Cryst. Struct. Commun. 1982, 11, 829-834
54. Maiti, R.; Shang, M.; Graham Lappin, A. A ruthenium(IV) Complex with Six Sulfur Donor Atoms Chem. Commun. 1999, 2349-2350 10.1039/a905243g
55. Terzis, A.; Filippakis, S.; Mentzafos, D.; Petrouleas, V.; Malliaris, A. Structure and Magnetic Behavior of Iron(III) Dithiocarbamate Complexes Exhibiting S = 1/2 ⇄ S = 5/2 Thermal Equilibrium. Study of the Tris(N-methyl-N-n-butyldithiocarbamato)iron Homologue Inorg. Chem. 1984, 23, 334-337 10.1021/ic00171a013
56. Isfort, C. S.; Kreickmann, T.; Pape, T.; Frohlich, R.; Hahn, F. E. Helical Complexes Containing Diamide-Bridged Benzene-o-dithiolato/Catecholato Ligands Chem.-Eur. J. 2007, 13, 2344-2357 10.1002/chem.200601167
57. Hahn, F. E.; Offermann, M.; Isfort, C. S.; Pape, T.; Frohlich, R. Heterobimetallic Triple-Stranded Helicates with Directional Benzene-o-dithiol/Catechol Ligands Angew. Chem., Int. Ed. 2008, 47, 6794-6797 10.1002/anie.200801172
58. Wang, K.; McConnachie, J. M.; Stiefel, E. I. Syntheses of Metal Dithiolene Complexes from Thiometalates by Induced Internal Redox Reactions Inorg. Chem. 1999, 38, 4334-4341 10.1021/ic990204k
59. 3] Inorg. Chem. 1976, 15, 1589-1595 10.1021/ic50161a024
60. n- (n = 0, 1, 2): Trigonal-Prismatic versus Octahedral Coordination in Tris(benzene-1,2-dithiolato) Complexes Eur. J. Inorg. Chem. 2002, 2002, 3007-3009 10.1002/1099-0682(200211)2002:11<3007::AID-EJIC3007>3.0.CO;2-I
61. Chiu, W.-H.; Peng, S.-M.; Che, C.-M. Bis(amido)ruthenium(IV) Complexes with 2,3-Diamino-2,3-dimethylbutane. Crystal Structure and Reversible Ru(IV)-Amide/Ru(III)-Amine and Ru(IV)-Amide/Ru(II)- Amine Redox Couples in Aqueous Solution Inorg. Chem. 1996, 35, 3369-3374 10.1021/ic951145n
62. Qi, Y.; Li, Y.-G.; Wang, E.; Zhang, Z.; Chang, S. Metal-controlled Self-assembly of Arsenic-vanadium-cluster Backbones with Organic Ligands Dalton Trans. 2008, 2335-2345 10.1039/b713115a
63. Katz, B. A.; Strouse, C. E. Molecular Transformations in the Solid State. Crystallographic Resolution of the Spin Isomers of Tris(2-picolylamine)iron(II) Dichloride and the Structural Relationship Between the Methanol and Ethanol Solvates J. Am. Chem. Soc. 1979, 101, 6214-6221 10.1021/ja00515a010
64. Mikami, M.; Konno, M.; Saito, Y. The Structures of High-spin (298, 150 K) and Low-spin (90 K) States and the Spin Phase-transition Mechanism of a Spin Crossover Complex; Tris([alpha]-picolylamine)iron(II) Chloride-ethanol Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1980, 36, 275-287 10.1107/S0567740880003093
65. 2·EtOH Angew. Chem., Int. Ed. 2003, 42, 3825-3830 10.1002/anie.200351834
66. 2.EtOH-The Superstructure Under Continuous Irradiation J. Appl. Crystallogr. 2005, 38, 528-536 10.1107/S0021889805009891
67. Törnroos, K. W.; Hostettler, M.; Chernyshov, D.; Vangdal, B.; Bürgi, H.-B. Interplay of Spin Conversion and Structural Phase Transformations: Re-Entrant Phase Transitions in the 2-Propanol Solvate of Tris(2-picolylamine)iron(II) Dichloride Chem.-Eur. J. 2006, 12, 6207-6215 10.1002/chem.200600547
68. II tris(2-picolylamine) Dichloride New J. Chem. 2009, 33, 1277-1282 10.1039/b823514g
69. Greenaway, A. M.; Sinn, E. High-spin and Low-spin α-picolylamine Iron(II) Complexes. Effect of Ligand Reversal on Spin State J. Am. Chem. Soc. 1978, 100, 8080-8084 10.1021/ja00494a009
70. Greenaway, A. M.; O'Connor, C. J.; Schrock, A.; Sinn, E. High- and Low-Spin Interconversion in a Series of (α-picolylamine)iron(II) Complexes Inorg. Chem. 1979, 18, 2692-2695 10.1021/ic50200a011
71. Hostettler, M.; Tornroos, K. W.; Chernyshov, D.; Vangdal, B.; Bürgi, H.-B. Challenges in Engineering Spin Crossover: Structures and Magnetic Properties of Six Alcohol Solvates of Iron(II) Tris(2-picolylamine) Dichloride Angew. Chem., Int. Ed. 2004, 43, 4589-4594 10.1002/anie.200460736
72. 2+ Inorg. Chim. Acta 2008, 361, 4047-4054 10.1016/j.ica.2008.03.122
73. 2O Z. Naturforsch., B: J. Chem. Sci. 2008, 63, 183-186
74. 2 Unit Fused to a Keggin Polyoxotungstate Anion Aust. J. Chem. 2010, 63, 252-256 10.1071/CH09437
75. 5- Clusters and Transition Metal Complexes J. Mol. Struct. 2008, 885, 161-167 10.1016/j.molstruc.2007.10.025
76. Alvarez, S. A Cartography of the van der Waals Territory Dalton Trans. 2013, 42, 8617-8636 10.1039/c3dt50599e
77. 1/2 and T(LIESST) Chem.-Eur. J. 2007, 13, 5503-5514 10.1002/chem.200601312
78. Martak, F.; Onggo, D.; Ismunandar; Nugroho, A. A.; Meetsma, A. 2009. Accessible from the Cambridge Structural Database (refcode UDUYOJ). https://summary.ccdc.cam.ac.uk/structure-summary-form (accessed September 14, 2015).
79. Halepoto, D. M.; Holt, D. G. L.; Larkworthy, L. F.; Leigh, G. J.; Povey, D. C.; Smith, G. W. Spin Crossover in Chromium(II) Complexes and the Crystal and Molecular Structure of the High Spin Form of Bis[1,2-bis(diethylphosphino)ethane]di-iodochromium(II) J. Chem. Soc., Chem. Commun. 1989, 1322-1323 10.1039/c39890001322
80. Karunadasa, H. I.; Arquero, K. D.; Berben, L. A.; Long, J. R. Enhancing the Magnetic Anisotropy of Cyano-Ligated Chromium(II) and Chromium(III) Complexes via Heavy Halide Ligand Effects Inorg. Chem. 2010, 49, 4738-4740 10.1021/ic1002995
81. 2] (X = S, Se) System: Structural, Magnetic, Calorimetric and Photomagnetic Studies Inorg. Chim. Acta 1999, 291, 279-288 10.1016/S0020-1693(99)00128-0
82. 2]: Syntheses, Characterization and Magnetic Properties Inorg. Chim. Acta 2007, 360, 4125-4132 10.1016/j.ica.2007.06.006
83. Yamada, M.; Hagiwara, H.; Torigoe, H.; Matsumoto, N.; Kojima, M.; Dahan, f.; Tuchagues, J.-P.; Re, N.; Iijima, S. A Variety of Spin-Crossover Behaviors Depending on the Counter-Ion Chem.-Eur. J. 2006, 12, 4536-4549 10.1002/chem.200500972
84. 3tren] Probed by High-pressure and Lowerature X-ray Diffraction Phys. Rev. B: Condens. Matter Mater. Phys. 2005, 72, 214408 10.1103/PhysRevB.72.214408
85. 2 Compounds: Correlation of the Structural Data with Magnetic and Mössbauer Spectroscopy Data J. Appl. Crystallogr. 2007, 40, 1135-1144 10.1107/S0021889807048571
86. McDaniel, A. M.; Rappe, A. K.; Shores, M. P. Structural and Electronic Comparison of 1st Row Transition Metal Complexes of a Tripodal Iminopyridine Ligand Inorg. Chem. 2012, 51, 12493-12502 10.1021/ic301909u
87. 3 Coord. Chem. Rev. 1987, 77, 89-163 10.1016/0010-8545(87)85033-6
88. Li, S.-N.; Ren, Y.-W.; Li, J.; Zhang, F.-X.; Hu, M.-C. {Tris[2-(2-pyridylmethyleneimino)ethyl]amine}manganese(II) bis(perchlorate) Acta Crystallogr., Sect. E: Struct. Rep. Online 2006, 62, m498-m499 10.1107/S1600536806004454
89. 2N,N′)ethyl]amine}cadmium(II) bis(perchlorate) Acta Crystallogr., Sect. E: Struct. Rep. Online 2007, 63, m346-m347 10.1107/S1600536806056261
90. Qian, M.; Gou, S.-H.; He, L.; Zhou, Y.-M.; Duan, C.-Y. [Tris(2-pyridyl-κN-methyleneamino-κN-ethyl)amine-κN]manganese(II) diperchlorate Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1999, 55, 742-744 10.1107/S0108270198017624
91. Park, G.; Przyborowska, A. M.; Ye, N.; Tsoupas, N. M.; Bauer, C. B.; Broker, G. A.; Rogers, R. D.; Brechbiel, M. W.; Planalp, R. P. Steric Effects Caused by N-alkylation of the Tripodal Chelator N,N′,N″-tris(2-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane (tachpyr): Structural and Electronic Properties of the Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) Complexes Dalton Trans. 2003, 318-324 10.1039/b209228j
92. II Complexes Eur. J. Inorg. Chem. 2005, 2005, 3971-3982 10.1002/ejic.200500382
93. Monteiro, B.; Roitershtein, D.; Ferreira, H.; Ascenso, J. R.; Martins, A. M.; Domingos, A.; Marques, N. Triamidotriazacyclononane Complexes of Group 3 Metals. Synthesis and Crystal Structures Inorg. Chem. 2003, 42, 4223-4231 10.1021/ic034090v
94. Schlager, O.; Wieghardt, K.; Grondey, H.; Rufinska, A.; Nuber, B. The Hexadentate Ligand 1,4,7-Tris(o-aminobenzyl)-1,4,7-triazacyclononane and Its Complexes with Zinc(II), Cadmium(II), and Mercury(II) in Solution and in the Solid State Inorg. Chem. 1995, 34, 6440-6448 10.1021/ic00130a008
95. 3 = 16-methyl-l,4,7,10,13-pentaoxa-16-azacyclooctadecane) Inorg. Chim. Acta 1992, 196, 35-41 10.1016/S0020-1693(00)82957-6
96. 2, Containing 7-coordinate Cadmium Koord. Khim. 1989, 15, 1629-1635
97. Ruiz-Martínez, A.; Casanova, D.; Alvarez, S. Association/Dissociation Paths and Ill-defined Coordination Numbers Chem.-Eur. J. 2010, 16, 6567-6581 10.1002/chem.200902996
98. Ababei, R.; Pichon, C.; Roubeau, O.; Li, Y.-G.; Brefuel, N.; Buisson, L.; Guionneau, P.; Mathonière, C.; Clérac, R. Rational Design of a Photomagnetic Chain: Bridging Single-Molecule Magnets with a Spin-Crossover Complex J. Am. Chem. Soc. 2013, 135, 14840-14853 10.1021/ja407570n
99. Guionneau, P.; Sánchez Costa, J.; Létard, J.-F. Revisited Crystal Symmetry of the High-spin Form of the Iron(II) Spin-crossover Complex Dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) Monohydrate Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2004, 60, m587-m589 10.1107/S010827010402445X
100. Guionneau, P.; Le Gac, F.; Kaiba, A.; Costa, J. S.; Chasseau, D.; Létard, J.-F. A Reversible Metal-Ligand Bond Break Associated to a Spin-crossover Chem. Commun. 2007, 3723-3725 10.1039/b707836f
101. Hayami, S.; Gu, Z.-Z.; Einaga, Y.; Kobayasi, Y.; Ishikawa, Y.; Yamada, Y.; Fujishima, A.; Sato, O. A Novel LIESST Iron(II) Complex Exhibiting a High Relaxation Temperature Inorg. Chem. 2001, 40, 3240-3242 10.1021/ic000708e
102. Létard, J.-F.; Costa, J. S.; Guionneau, P.; Marcen, S. 2009. Accessible from the Cambridge Structural Database (refcode XEZMEU03). https://summary.ccdc.cam.ac.uk/structure-summary-form (accessed September 14, 2015).
103. 2] Complex Dalton Trans. 2015, 44, 6711-6714 10.1039/C5DT00357A
104. 2 Inorg. Chem. 2005, 44, 5696-5705 10.1021/ic050500z
105. 6 and [AgL′(SCN)] J. Chem. Soc., Dalton Trans. 1991, 1487-1490 10.1039/dt9910001487
106. Haselhorst, G.; Stoetzel, S.; Strassburger, A.; Walz, W.; Wieghardt, K.; Nuber, B. Synthesis and Co-ordination Chemistry of the Macrocycle 1,4,7-triisopropyl-1,4,7-triazacyclononane J. Chem. Soc., Dalton Trans. 1993, 83-90 10.1039/dt9930000083
107. Baker, M. V.; Brown, D. H.; Skelton, B. W.; White, A. H. An Investigation of 1,4,7-tri(4-alkynyl)-1,4,7-triazacyclononanes: Ligand Synthesis and Metal Coordination Chemistry J. Chem. Soc., Dalton Trans. 2000, 4607-4616 10.1039/b007324p
108. + in Water: a Theoretical and Experimental Study Inorg. Chem. 2009, 48, 4963-4970 10.1021/ic9002803
109. Bambirra, S.; van Leusen, D.; Tazelaar, C. G. J.; Meetsma, A.; Hessen, B. Rare Earth Metal Alkyl Complexes with Methyl-Substituted Triazacyclononane-amide Ligands: Ligand Variation and Ethylene Polymerization Catalysis Organometallics 2007, 26, 1014-1023 10.1021/om060870a
110. Yang, Y.-S.; Gu, W.; Qian, J.; Gao, F.-X.; Yan, S.-P. Syntheses, Structures, and Spectroscopic Properties of Copper(II) and Cobalt(III) Complexes Containing 1,4,7-tribenzyl-1,4,7-triazacyclononane Ligand J. Coord. Chem. 2007, 60, 1681-1690 10.1080/00958970601108067
111. 4 (L = 1,4,7-Trimethyl-1,4,7-triazacyclononane) Acta Chem. Scand. 1992, 46, 38-42 10.3891/acta.chem.scand.46-0038
112. 3N)cadmium(II) naphthalene-1,5-disulfonate Acta Crystallogr., Sect. E: Struct. Rep. Online 2007, 63, m939-m941 10.1107/S1600536807009191
113. Fu, M.-L.; Guo, G.-C.; Liu, X.; Liu, B.; Cai, L.-Z.; Huang, J.-S. Syntheses, Structures and Properties of Three Selenoarsenates Templated by Transition Metal Complexes Inorg. Chem. Commun. 2005, 8, 18-21 10.1016/j.inoche.2004.10.021
114. 2+ Clusters Z. Anorg. Allg. Chem. 2003, 629, 532-538 10.1002/zaac.200390086
115. Fu, M.-L.; Guo, G.-C.; Liu, B.; Wu, A.-Q.; Huang, J.-S. Two New Thiostannates Templated by Transition Metal Complexes Wuji Huaxue Xuebao (Chin. J. Inorg. Chem.) 2005, 21, 25-29
116. 2 Z. Naturforsch., B: J. Chem. Sci. 2013, 68, 605-610 10.5560/znb.2013-3039
117. Schweinfurth, D.; Demeshko, S.; Hohloch, S.; Steinmetz, M.; Brandenburg, J. G.; Dechert, S.; Meyer, F.; Grimme, S.; Sarkar, B. Spin Crossover in Fe(II) and Co(II) Complexes with the Same Click-Derived Tripodal Ligand Inorg. Chem. 2014, 53, 8203-8212 10.1021/ic500264k
118. Schweinfurth, D.; Krzystek, J.; Schapiro, I.; Demeshko, S.; Klein, J.; Telser, J.; Ozarowski, A.; Su, C.-Y.; Meyer, F.; Atanasov, M.; Neese, F.; Sarkar, B. Electronic Structures of Octahedral Ni(II) Complexes with "Click" Derived Triazole Ligands: A Combined Structural, Magnetometric, Spectroscopic, and Theoretical Study Inorg. Chem. 2013, 52, 6880-6882 10.1021/ic3026123
119. Schweinfurth, D.; Weisser, F.; Bubrin, D.; Bogani, L.; Sarkar, B. Cobalt Complexes with "Click"-Derived Functional Tripodal Ligands: Spin Crossover and Coordination Ambivalence Inorg. Chem. 2011, 50, 6114-6121 10.1021/ic200246v
120. Reger, D. L.; Sirianni, E.; Horger, J. J.; Smith, M. D.; Semeniuc, R. F. Supramolecular Architectures of Metal Complexes Controlled by a Strong π···π Stacking, 1,8-Naphthalimide Functionalized Third Generation Tris(pyrazolyl)methane Ligand Cryst. Growth Des. 2010, 10, 386-393 10.1021/cg901000d
121. 113Cd Solution NMR Chemical Shifts, and Investigations of Fluxional Processes of Bis[poly(pyrazolyl)borato]cadmium Complexes Inorg. Chem. 1993, 32, 5216-5222 10.1021/ic00075a046
122. -, through Steric Contact Bull. Chem. Soc. Jpn. 2003, 76, 1365-1373 10.1246/bcsj.76.1365
123. 113Cd Solution NMR Study of Bis[poly(pyrazolyl)borato]cadmium Complexes Polyhedron 1998, 17, 17-26 10.1016/S0277-5387(97)00271-4
124. 3] (pz = pyrazolyl) J. Am. Chem. Soc. 1995, 117, 10998-11005 10.1021/ja00149a024
125. McWhinnie, W. R.; Monsef-Mirzai, Z.; Perry, M. C.; Shaikh, N.; Hamor, T. A. Some Hydridotris(3,5-dimethylpyrazolyl)borate Complexes of Zinc, Cadmium and Mercury-Synthetic, Structural and NMR Investigations Polyhedron 1993, 12, 1193-1199 10.1016/S0277-5387(00)88211-X
126. II Cations Chem. Commun. 2011, 47, 10416-10418 10.1039/c1cc13627e
127. Reger, D. L.; Collins, J. E.; Myers, S. M.; Rheingold, A. L.; Liable-Sands, L. M. Syntheses of Cationic, Six-Coordinate Cadmium(II) Complexes Containing Tris(pyrazolyl)methane Ligands. Influence of Charge on Cadmium-113 NMR Chemical Shifts Inorg. Chem. 1996, 35, 4904-4909 10.1021/ic951554j
128. Cingolani, A.; Martini, D.; Marchetti, F.; Pettinari, C.; Ricciutelli, M.; Skelton, B. W.; White, A. H. Synthesis, Spectroscopic and Structural Characterisation of Cd(II) and Zn(II) Derivatives of Tris(3,4,5-trimethylpyrazol-1-yl)methane Inorg. Chim. Acta 2003, 350, 641-650 10.1016/S0020-1693(03)00111-7
129. Reger, D. L.; Wright, T. D.; Semeniuc, R. F.; Grattan, T. C.; Smith, M. D. Supramolecular Structures of Cadmium(II) Coordination Polymers: A New Class of Ligands Formed by Linking Tripodal Tris(pyrazolyl)methane Units Inorg. Chem. 2001, 40, 6212-6219 10.1021/ic010574k
130. 2 Synth. React. Inorg. Met.-Org. Chem. 2004, 34, 1149-1163 10.1081/SIM-120039263
131. - for First-series Transition Metals and Cd J. Chem. Soc., Dalton Trans. 2001, 3564-3571 10.1039/b106006f
132. Kunz, K.; Bolte, M.; Lerner, H.-W.; Wagner, M. Photochemistry of Cymantrenyl Scorpionates: Formation of a Novel Tritopic Cyclopentadienyl/Scorpionate Hybrid Ligand Organometallics 2009, 28, 3079-3087 10.1021/om900190r
133. 2 (M = Co, Mn) Complexes: Synthesis, Structure and Magnetic Properties Dalton Trans. 2010, 39, 3489-3494 10.1039/b924203a
134. + Cation Inorg. Chem. 2010, 49, 2793-2798 10.1021/ic902296d
135. Yi, W.; Zhang, J.; Zhang, F.; Zhang, Y.; Chen, Z.; Zhou, X. Versatile Reactivity of Scorpionate-Anchored Yttrium-Dialkyl Complexes towards Unsaturated Substrates Chem.-Eur. J. 2013, 19, 11975-11983 10.1002/chem.201300610
136. 3) Organometallics 1997, 16, 349-353 10.1021/om960481o
137. Cingolani, A.; Effendy; Martini, D.; Pellei, M.; Pettinari, C.; Skelton, B. W.; White, A. H. Silver Derivatives of Tris(pyrazol-1-yl)methanes. A Silver(I) Nitrate Complex Containing a Tris(pyrazolyl)methane Coordinated in a Bridging Mode Inorg. Chim. Acta 2002, 328, 87-95 10.1016/S0020-1693(01)00690-9
138. 2 (pz = Pyrazolyl): Observation of Unusual Spin-Crossover Behavior Inorg. Chem. 2000, 39, 4674-4675 10.1021/ic000721z
139. 2 (pz = Pyrazolyl Ring): Observation of a Thermally Induced Spin State Change from All High Spin to an Equal High Spin-Low Spin Mixture, Concomitant with the Onset of Nonmerohedral Twinning Inorg. Chem. 2001, 40, 2870-2874 10.1021/ic010056+
140. Forshaw, A. P.; Smith, J. M.; Ozarowski, A.; Krzystek, J.; Smirnov, D.; Zvyagin, S. A.; Harris, T. D.; Karunadasa, H. I.; Zadrozny, J. M.; Schnegg, A.; Holldack, K.; Jackson, T. A.; Alamiri, A.; Barnes, D. M.; Telser, J. Low-Spin Hexacoordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes Inorg. Chem. 2013, 52, 144-159 10.1021/ic301630d
141. 2 Inorg. Chem. 2007, 46, 3792-3794 10.1021/ic070187w
142. Chen, F.; Wang, G.-F.; Li, Y.-Z.; Chen, X.-T.; Xue, Z.-L. Syntheses, Structures and Electrochemical Properties of Homoleptic Ruthenium(III) and Osmium(III) Complexes Bearing Two Tris(carbene)borate Ligands Inorg. Chem. Commun. 2012, 21, 88-91 10.1016/j.inoche.2012.04.020
143. Frankel, R.; Kernbach, U.; Bakola-Christianopoulou, M.; Plaia, U.; Suter, M.; Ponikwar, W.; Noth, H.; Moinet, C.; Fehlhammer, W. P. Homoleptic Carbene Complexes: Part VIII. Hexacarbene Complexes J. Organomet. Chem. 2001, 617-618, 530-545 10.1016/S0022-328X(00)00713-0
144. Kernbach, U.; Ramm, M.; Luger, P.; Fehlhammer, W. P. A Chelating Triscarbene Ligand and Its Hexacarbene Iron Complex Angew. Chem., Int. Ed. Engl. 1996, 35, 310-312 10.1002/anie.199603101
145. Arif, A. M.; Hefner, J. G.; Jones, R. A.; Whittlesley, B. R. Mononuclear Chromium Complexes of the Tripod Ligand (tripod = 1,1,1-[tris((dimethylphosphino)methyl)ethane Inorg. Chem. 1986, 25, 1080-1084 10.1021/ic00228a005
146. n+ (M = Co, Rh; n = 0, 1, 2 or 3) Series of Complexes Containing Tripodal Tridentate Phosphine, 1,1,1-tris(dimethylphosphinomethyl)ethane Inorg. Chim. Acta 2005, 358, 2501-2512 10.1016/j.ica.2005.02.008
147. 2O Bull. Chem. Soc. Jpn. 1992, 65, 2748-2755 10.1246/bcsj.65.2748
148. 3 Ions in Aqueous Solution Can. J. Chem. 2001, 79, 1344-1351 10.1139/v01-119
149. Kashiwabara, K.; Ozeki, Y.; Kita, M.; Fujita, J.; Nakajima, K. Synthesis and Crystal Structure of Bis(1,1,1-tris(dimethylphosphinomethyl)ethane)iron(II) Tetrafluoroborate Dihydrate Bull. Chem. Soc. Jpn. 1995, 68, 3453-3457 10.1246/bcsj.68.3453
150. Kershaw Cook, L. J.; Mohammed, R.; Sherborne, G.; Roberts, T. D.; Alvarez, S.; Halcrow, M. Spin-state Behaviour of Iron(II)Dipyrazolylpyridine Complexes. New Insights from Crystallographic and Solution Measurements Coord. Chem. Rev. 2015, 289-290, 2-12 10.1016/j.ccr.2014.08.006
151. Hayami, S.; Komatsu, Y.; Shimizu, T.; Kamihata, H.; Lee, Y. H. Spin-crossover in Cobalt(II) Compounds Containing Terpyridine and its Derivatives Coord. Chem. Rev. 2011, 255, 1981-1990 10.1016/j.ccr.2011.05.016
152. Craig, G. A.; Roubeau, O.; Aromí, G. Spin State Switching in 2,6-bis(pyrazol-3-yl)pyridine (3-bpp) Based Fe(II) Complexes Coord. Chem. Rev. 2014, 269, 13-31 10.1016/j.ccr.2014.02.002
153. n (M = Fe, Ru; n = 3+, 2+, 1+, 0, 1-): A Mössbauer Spectroscopic and DFT Study Eur. J. Inorg. Chem. 2012, 2012, 4605-4621 10.1002/ejic.201200232
154. Hu, L.; Liu, W.; Li, C.-H.; Zhou, X.-H.; Zuo, J.-L. Iron(II) Complexes Based on π-Conjugated Terpyridine Ligands with Tetrathiafulvalene or Its Radical Analogue Eur. J. Inorg. Chem. 2013, 2013, 6037-6048 10.1002/ejic.201301151
155. Liu, P.; Liu, Y.; Wong, E. L.-M.; Xiang, S.; Che, C.-M. Iron Oligopyridine Complexes as Efficient Catalysts for Practical Oxidation of Arenes, Alkanes, Tertiary Amines and N-acyl Cyclic Amines with Oxone Chem. Sci. 2011, 2, 2187-2195 10.1039/c1sc00234a
156. Dell'Amico, D. B.; Calderazzo, F.; Englert, U.; Labella, L.; Marchetti, F. The First Crystallographically Established Bis-qtpy (qtpy = 2,2′:6′,2″:6″,2⌄-quaterpyridine) Metal Complex J. Chem. Soc., Dalton Trans. 2001, 357-358 10.1039/b100360g
157. Brauchli, S. Y.; Constable, E. C.; Harris, K.; Häussinger, D.; Housecroft, C. E.; Rösel, P. J.; Zampese, J. A. Towards Catenanes Using π-stacking Interactions and Their Influence on the Spin-State of a Bis(2,2′:6′,2″-terpyridine)iron(II) Domain Dalton Trans. 2010, 39, 10739-10748 10.1039/c0dt00743a
158. Constable, E. C.; Baum, G.; Bill, E.; Dyson, R.; van Eldik, R.; Fenske, D.; Kaderli, S.; Morris, D.; Neubrand, A.; Neuburger, M.; Smith, D. R.; Wieghardt, K.; Zehnder, M.; Zuberbühler, A. D. Control of Iron(II) Spin States in 2,2′:6′,2″-Terpyridine Complexes through Ligand Substitution Chem.-Eur. J. 1999, 5, 498-508 10.1002/(SICI)1521-3765(19990201)5:2<498::AID-CHEM498>3.3.CO;2-M
159. Pelascini, F.; Wesolek, M.; Peruch, F.; De Cian, A.; Kyritsakas, N.; Lutz, P. J.; Kress, J. Iron Complexes of Terdentate Nitrogen Ligands: Formation and X-ray Structure of Three New Dicationic Complexes Polyhedron 2004, 23, 3193-3199 10.1016/j.poly.2004.10.001
160. Falceto, A.; Carmona, E.; Alvarez, S. Electronic and Structural Effects of Low Hapticity Coordination of Arene Rings to Transition Metals Organometallics 2014, 33, 6660-6668 10.1021/om5009583
161. Kershaw Cook, L. J.; Thorp-Greenwood, F. L.; Comyn, T. P.; Cespedes, O.; Chastanet, G.; Halcrow, M. A. Unexpected Spin-Crossover and a Low-Pressure Phase Change in an Iron(II)/Dipyrazolylpyridine Complex Exhibiting a High-spin Jahn-Teller Distortion Inorg. Chem. 2015, 54, 6319-6330 10.1021/acs.inorgchem.5b00614
162. Cipressi, J.; Brown, S. N. Octahedral to Trigonal Prismatic Distortion Driven by Subjacent Orbital π Antibonding Interactions and Modulated by Ligand Redox Noninnocence Chem. Commun. 2014, 50, 7956-7959 10.1039/c4cc03404j
163. Hills, A.; Hughes, D. L.; Leigh, G. J.; Sanders, J. R. Reactions of Vanadium(IV) Halide Complexes Containing Schiff-base Ligands with Hydrazines; Preparation and Structure of [N,N′-ethylenebis(salicylideneiminato)]bis-(phenylhydrazine)vanadium(III) Iodide J. Chem. Soc., Dalton Trans. 1991, 325-329 10.1039/dt9910000325
164. Zhang, S.; Lai, L.; Shao, M.; Tang, Y. Preparation and Structure of Chloro[N,N ′-ethylenebis(salicylideneiminato)] tetrahydrofuranTitanium(III) Acta Phys.-Chim. Sin. 1985, 1, 335-339 10.3866/PKU.WHXB19850407
165. Pasquali, M.; Marchetti, F.; Landi, A.; Floriani, C. Preparations and structures of NN′-ethylenebis(salicylideneiminato)-titanium(III) Derivatives J. Chem. Soc., Dalton Trans. 1978, 545-549 10.1039/dt9780000545
166. Chen, H.; White, P. S.; Gagné, M. R. Synthesis and Reactivity of Titanium(IV)-Salen Complexes Containing Oxygen and Chloride Ligands Organometallics 1998, 17, 5358-5366 10.1021/om980414p
167. Seredyuk, M.; Piñeiro-López, L.; Muñoz, M. C.; Martínez-Casado, F. J.; Molnár, G.; Rodriguez-Velamazán, J. A.; Bousseksou, A.; Real, J. A. Homoleptic Iron(II) Complexes with the Ionogenic Ligand 6,6′-Bis(1H-tetrazol-5-yl)-2,2′-bipyridine: Spin Crossover Behavior in a Singular 2D Spin Crossover Coordination Polymer Inorg. Chem. 2015, 54, 7424-7432 10.1021/acs.inorgchem.5b01001
168. 57Fe Mössbauer, and Biological Activity Studies Dalton Trans. 2009, 9870-9880 10.1039/b912676g
169. -: Syntheses, Structures, Magnetic Properties, and Density Functional Theoretical Study Chem.-Eur. J. 2010, 16, 3524-3535 10.1002/chem.200902047
170. Booysen, I. N.; Maikoo, S.; Akerman, M. P.; Xulu, B. Novel Ruthenium(II) and (III) Compounds with Multidentate Schiff Base Chelates Bearing Biologically Significant Moieties Polyhedron 2014, 79, 250-257 10.1016/j.poly.2014.05.021
171. Griffith, G. A.; Al-Khatib, M. J.; Patel, K.; Singh, K.; Solan, G. A. Solid and Solution State Flexibility of Sterically Congested Bis(imino)bipyridine Complexes of Zinc(II) and Nickel(II) Dalton Trans. 2009, 185-196 10.1039/B811309B
172. Wang, Z.; Reibenspies, J.; Motekaitis, R. J.; Martell, A. E. Unusual Stabilities of 6,6′-bis(aminomethyl)-2,2′-bipyridyl Chelates of Transition-metal Ions and Crystal Structures of the Ligand and its Copper(II) and Nickel(II) Complexes J. Chem. Soc., Dalton Trans. 1995, 1511-1518 10.1039/dt9950001511
173. 2] Chem. Mater. 2009, 21, 1123-1136 10.1021/cm803414q
174. Bonnet, S.; Siegler, M. A.; Costa, J. S.; Molnar, G.; Bousseksou, A.; Spek, A. L.; Gamez, P.; Reedijk, J. A Two-step Spin Crossover Mononuclear Iron(II) Complex with a [HS-LS-LS] Intermediate Phase Chem. Commun. 2008, 5619-5621 10.1039/b811746b
175. Arcis-Castillo, Z.; Zheng, S.; Siegler, M. A.; Roubeau, O.; Bedoui, S.; Bonnet, S. Tuning the Transition Temperature and Cooperativity of bapbpy-Based Mononuclear Spin-Crossover Compounds: Interplay between Molecular and Crystal Engineering Chem.-Eur. J. 2011, 17, 14826-14836 10.1002/chem.201101301
176. Krüger, H.-J. Spin Transition in Octahedral Metal Complexes Containing Tetrazamacrocyclic Ligands Coord. Chem. Rev. 2009, 253, 2450-2459 10.1016/j.ccr.2009.06.004
177. Buffet, J.-C.; Okuda, J. Scandium Alkyl and Amide Complexes containing a Cyclen-derived (NNNN) Macrocyclic Ligand: Synthesis, Structure and Ring-opening Polymerization Activity Toward Lactide Monomers Dalton Trans. 2011, 40, 7748-7754 10.1039/c1dt10075k
178. Ohashi, M.; Konkol, M.; Del Rosal, I.; Poteau, R.; Maron, L.; Okuda, J. Rare-Earth Metal Alkyl and Hydride Complexes Stabilized by a Cyclen-Derived [NNNN] Macrocyclic Ancillary Ligand J. Am. Chem. Soc. 2008, 130, 6920-6921 10.1021/ja801771u
179. Yokoyama, A.; Han, J. E.; Cho, J.; Kubo, M.; Ogura, T.; Siegler, M. A.; Karlin, K. D.; Nam, W. Chromium(IV)-Peroxo Complex Formation and Its Nitric Oxide Dioxygenase Reactivity J. Am. Chem. Soc. 2012, 134, 15269-15272 10.1021/ja307384e
180. Hazari, S. K.; Roy, T. G.; Dey, B. K.; Das, S. C.; Tiekink, E. R. T. Synthesis, Characterisation and Antifungal Activities of Some New Copper(II) Complexes of Isomeric 3,5,7,7,10,12,14,14-Octamethyl-1,4,8,11-Tetraazacyclotetradecanes Met.-Based Drugs 1997, 4, 255-265 10.1155/MBD.1997.255
181. Sen, R.; Bhattacharya, A.; Mal, D.; Bhattacharjee, A.; Gütlich, P.; Mukherjee, A. K.; Solzi, M.; Pernechele, C.; Koner, S. A Cyano-bridged Bimetallic Ferrimagnet: Synthesis, X-ray Structure and Magnetic Study Polyhedron 2010, 29, 2762-68 10.1016/j.poly.2010.06.022
182. Koningsbruggen, P. J. v.; Maeda, Y.; Oshio, H. Iron(III) Spin Crossover Compounds. In Topics in Current Chemistry; Gütlich, P.; Goodwin, H. A., Eds.; Springer: Berlin/Heidelberg, 2004; Vol. 233, pp 259-324. 10.1007/b95409
183. 2 Pentadentate Schiff-Base Ligand and 4-Aminopyridine Bull. Chem. Soc. Jpn. 2005, 78, 1279-1282 10.1246/bcsj.78.1279
184. Imatomi, S.; Sato, T.; Hamamatsu, T.; Kitashima, R.; Matsumoto, N. Spin-Crossover Behavior of Isomorphous Bi- and Mononuclear Iron(III) Complexes Bull. Chem. Soc. Jpn. 2007, 80, 2375-2377 10.1246/bcsj.80.2375
185. Lloris, J. M.; Martínez-Máñez, R.; Pardo, T.; Soto, J.; Padilla-Tosta, M. E. Binding, Electrochemical and Metal Extraction Properties of the New Redox-active Polyazacycloalkane 1,4,7,10,13,16-hexa(ferrocenylmethyl)-1,4,7,10,13,16-hexaazacyclooctadecane J. Chem. Soc., Dalton Trans. 1998, 2635-2642 10.1039/a802394h
186. Assey, G.; Butcher, R. J.; Gultneh, Y.; Yisgedu, T. [2,2′-(2,6,9,13-Tetraazatetradecane-1,14-diyl)diphenolato]iron(III) Iodide Acta Crystallogr., Sect. E: Struct. Rep. Online 2010, 66, m711-m712 10.1107/S1600536810018787
187. Arulsamy, N.; Glerup, J.; Hodgson, D. J. Mononuclear Iron(II), Manganese(II), and Nickel(II) and Tetranuclear Iron(III) Complexes of a New Hexadentate Ligand Inorg. Chem. 1994, 33, 3043-3050 10.1021/ic00092a006
188. Zhang, H.-X.; Zheng, S.-T.; Yang, G.-Y. Pentaethylenehexaminemanganese(II) Pentaborate Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2004, 60, m241-m243 10.1107/S0108270104007942
189. Xu, G.-H.; Wang, C.; Guo, P. Poly[[(pentaethylenehexamine)manganese(II)] [hepta-μ-selenido-tritin(IV)]]: a Tin-selenium Net with Remarkable Flexibility Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2009, 65, m171-m173 10.1107/S0108270109010956
190. Butcher, R. J.; Pourian, M.; Jasinski, J. P. {1,4-Bis[3-(3-methoxy-2-oxidobenzylideneamino)propyl]piperazine}iron(III) Tetrafluoridoborate Acta Crystallogr., Sect. E: Struct. Rep. Online 2007, 63, m1913-m1914 10.1107/S1600536807028413
191. 2 End Product Inorg. Chim. Acta 2005, 358, 437-443 10.1016/j.ica.2004.07.034
192. III Spin Crossover Complexes Dalton Trans. 2010, 39, 4903-4910 10.1039/c001067g
193. 4-bis(pyridoxylidene)triethylenetetramine Polyhedron 2014, 81, 428-435 10.1016/j.poly.2014.06.029
194. 2] Symmetrical Schiff Base Ligand: Syntheses, Crystal Structures, Electrical Conductivity and Optical Properties Polyhedron 2008, 27, 3359-3370 10.1016/j.poly.2008.07.034
195. Lin, H.-J.; Siretanu, D.; Dickie, D. A.; Subedi, D.; Scepaniak, J. J.; Mitcov, D.; Clérac, R.; Smith, J. M. Steric and Electronic Control of the Spin State in Three-Fold Symmetric, Four-Coordinate Iron(II) Complexes J. Am. Chem. Soc. 2014, 136, 13326-13332 10.1021/ja506425a
196. Nieto, I.; Cervantes-Lee, F.; Smith, J. M. A new synthetic route to bulky "second generation" tris(imidazol-2-ylidene)borate ligands: synthesis of a four coordinate iron(II) complex Chem. Commun. 2005, 3811-3813 10.1039/b505985b
197. Cowley, R. E.; Bontchev, R. P.; Sorrell, J.; Sarracino, O.; Feng, Y.; Wang, H.; Smith, J. M. Formation of a Cobalt(III) Imido from a Cobalt(II) Amido Complex. Evidence for Proton-Coupled Electron Transfer J. Am. Chem. Soc. 2007, 129, 2424-2425 10.1021/ja066899n
198. Cho, J.; Yap, G. P. A.; Riordan, C. G. Structural, Spectroscopic, and Electrochemical Properties of a Series of High-Spin Thiolatonickel(II) Complexes Inorg. Chem. 2007, 46, 11308-11315 10.1021/ic701743z
199. DuPont, J. A.; Yap, G. P. A.; Riordan, C. G. Influence of Ligand Electronic Effects on the Structure of Monovalent Cobalt Complexes Inorg. Chem. 2008, 47, 10700-10707 10.1021/ic800813u
200. Camalli, M.; Caruso, F. P NMR Study on the Ag(triphos)X Series (triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane, X = anion). Crystal and Molecular Structure of Ag(triphos)I Inorg. Chim. Acta 1990, 169, 189-194 10.1016/S0020-1693(00)80516-2
201. Alvarez, S.; Avnir, D. Continuous Chirality Measures of Tetrtacoordinate Bis-chelate Metal Complexes Dalton Trans. 2003, 562-569 10.1039/b208837a
202. 2: Synthesis, Structure and Spectroscopy Dalton Trans. 2010, 39, 437-445 10.1039/B912332F
203. Pogozhev, D.; Baudron, S. A.; Hosseini, M. W. Combination of Hydrogen and Coordination Bonding for the Construction of One-dimensional Networks Based on a 7-azaindole Appended Dipyrrin CrystEngComm 2010, 12, 2238-2244 10.1039/b927348d
204. Béziau, A.; Baudron, S. A.; Fluck, A.; Hosseini, M. W. From Sequential to One-Pot Synthesis of Dipyrrin Based Grid-Type Mixed Metal-Organic Frameworks Inorg. Chem. 2013, 52, 14439-14448 10.1021/ic402892f
205. March, F. C.; Couch, D. A.; Emerson, K.; Fergusson, J. E.; Robinson, W. T. Dipyrromethene Complexes of Transition Metals. Part II. Stereochemistry of Complexes of Cobalt(II), Nickel(II), Copper(II), Zinc(II), Cadmium(II), Mercury(II), and Palladium(II) and Crystal Structure Analysis of the Palladium Complex J. Chem. Soc. A 1971, 440-448 10.1039/j19710000440
206. Kido, H.; Shin, J.-Y.; Shinokubo, H. Selective Synthesis of a [32]Octaphyrin(1.0.1.0.1.0.1.0) Bis(palladium) Complex by a Metal-Templated Strategy Angew. Chem., Int. Ed. 2013, 52, 13727-13730 10.1002/anie.201306905
207. Béziau, A.; Baudron, S. A.; Guenet, A.; Hosseini, M. W. Luminescent Coordination Polymers Based on Self-Assembled Cadmium Dipyrrin Complexes Chem.-Eur. J. 2013, 19, 3215-3223 10.1002/chem.201203133
208. Irrgang, T.; Schareina, T.; Kempe, R. The Development of an Enantioselective Nickel Hydrosilylation Catalyst System via Multi-substrate Screening J. Mol. Catal. A: Chem. 2006, 257, 48-52 10.1016/j.molcata.2006.04.002
209. Edwards, A. J.; Retbøll, M.; Wenger, E. The Tetrahedral Tetrakis(phosphine) Complex [bis(diphenylphosphino)butane-κP,P]nickel(0)-benzene (1/2.5) Acta Crystallogr., Sect. E: Struct. Rep. Online 2002, 58, m375-m377 10.1107/S1600536802011121
210. 2 and Ethylene: The Transformation of a Nickelalactone into a Nickel-acrylate Complex Chem. Commun. 2006, 2510-2512 10.1039/b603540j
211. 4 Inorg. Chem. 1981, 20, 4101-4107 10.1021/ic50226a013
212. Allen, F. H. The Cambridge Structural Database: A Quarter of a Million Crystal Structures and Rising Acta Crystallogr., Sect. B: Struct. Sci. 2002, 58, 380-388 10.1107/S0108768102003890