Synthesis and structure of the Mn(II) complexes with tripyrazolylborate ligands: Mn[HB(pz)3]2 and Mn[HB(3,5-Me2-pz) 3]2

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Volumn 34, Issue 7, 2004, Pages 1149-1163

  Yong, Heng Xing ^a   Aoki, Katsuyuki ^b   Feng, Ying Bai ^a  

^a LIAONING NORMAL UNIVERSITY   (China)

^b TOYOHASHI UNIVERSITY OF TECHNOLOGY   (Japan)

Author keywords

Crystal structure; Mn(II) complexes; Tripyrazolylborate

Indexed keywords

BORIC ACID; MANGANESE DERIVATIVE;

ARTICLE; CRYSTALLIZATION; INFRARED SPECTROSCOPY; STRUCTURE ANALYSIS; X RAY ANALYSIS; X RAY DIFFRACTION;

EID: 3242801190     PISSN: 00945714     EISSN: None     Source Type: Journal    
DOI: 10.1081/SIM-120039263     Document Type: Article

References (13)

1. Sigel, A.; Sigel, H., Eds. Metal Ions in Biological Systems: Marcel Dekker: New York, 2000; Vol. 37.
2. Helleman, I.; Stock, C.C. Activation of enzymes. V. The specificity of arginase and the non inzymatic hydrolysis of guanidino compounds activating metal ions and liver arginase. J. Biol. Chem. 1983, 125, 771-793.
3. Hashino, N.; Fukuda, Y.; Sone, K. Studies on mixed chelates. Part IX. A new mixed nickel(II) chelate which assumes 4-, 5-, and 6-coordinate structures in various organic solvents. Transition Met. Chem. 1979, 4, 183-186.
4. Scrutton, M.C. Metal enzymes. In Inorganic Biochemistry; Neth CODEN: 300SAX Conference, Rutger Med. Sch., Rutgers State Univ., New Brunswick, NJ, USA; Eichhorn, Gunther Louis, Eds.; Elsevier: Amsterdam, 1973; Vol. 1, 381-437.
5. Schellenberger, A. Structure and mechanism of action of the active center of yeast pyruvate decarboxylase. Angew. Chem. Int. Ed. Engl. 1976, 41, 1024-1035.
6. Reglinski, J.; Garner, M.; Cassidy, I.D.; Slavin, P.A.; Spicer, M.D.; Armstrong, D.R. Sodium hydrotris(methimazolyl)borates, a novel soft tridentate ligand: preparation, structure and comparisons with sodium hydrotris(pyrazolyl) borate. J. Chem. Soc. Dalton Trans. 1999, 13, 2119-2126.
7. Trofimenko, S. Boron-pyrazole chemistry. IV. Carbon-and boron-substituted poly(1-pyrazolyl)borates. J. Am. Chem. Soc. 1967, 89, 6288-6295.
8. Sheldrick, G.M. Phase annealing in SHELX-90: direct methods for larger structures. Acta Crystallogr. 1990, A46 (6), 467-473.
9. Sheldrick, G.M. Refinement of twinned structures with SHELXL97. Ada Cryst. 1998, B54 (4), 443-449.
10. Farrugia, L.J. ORTEP-3 for windows - a version of ORTEP-III with a graphical user interface (GUI). J. Appl. Cryst. 1997, 30 (5), 565-571.
11. Schoenberg, A.R.; Anderson, W.P. Photochemical reactions of poly(1-pyrazolyl)boratotricarbonylmanganese(I) with phosphorus donor ligands. Inorg. Chem. 1972, 1 (11), 85-87.
12. 4). J. Coord. Chem. 2002, 55, 1241-1247.
13. 2O (pyr = 2-pyrazinecarboxylic acid; dipic = pyridine-2,6-dicarboxylic acid; chedam = chelidamic acid; (4-hydroxypyridine-2, 6-dicarboxylic acid); bipy = 2,2-bipyridine). Polyhedron 2002, 21, 1063-1071.