메뉴 건너뛰기




Volumn 43, Issue 35, 2004, Pages 4589-4594

Challenges in engineering spin crossover: Structures and magnetic properties of six alcohol solvates of iron(II) tris(2-picolylamine) dichloride

Author keywords

Crystal engineering; Magnetic properties; Solvate complexes; Spin crossover; Structure elucidation

Indexed keywords

CRYSTAL STRUCTURE; ENGINEERING; INTERMETALLICS; IRON; PHASE TRANSITIONS; SOLVENTS; SPIN GLASS;

EID: 5344224095     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460736     Document Type: Article
Times cited : (170)

References (30)
  • 4
    • 33748878612 scopus 로고
    • P. Gütlich, A. Hauser, H. Spiering, Angew. Chem. 1994, 106, 2109; Angew. Chem. Int. Ed. Engl. 1994, 33, 2024.
    • (1994) Angew. Chem. Int. Ed. Engl. , vol.33 , pp. 2024
  • 9
    • 0042865993 scopus 로고    scopus 로고
    • V. Niel, A. L. Thompson, M. C. Muñoz, A. Galet, A. E. Goeta, J. A. Real, Angew. Chem. 2003, 115, 3890; Angew. Chem. Int. Ed. 2003, 42, 3760.
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 3760
  • 10
    • 0003775629 scopus 로고    scopus 로고
    • Cerius2, San Diego
    • Solvent volumes and Connolly surfaces have been calculated with program Cerius2 using a test sphere of diameter 1 Å. Cerius2, Molecular Simulations, San Diego, 1997.
    • (1997) Molecular Simulations
  • 13
    • 0041859574 scopus 로고    scopus 로고
    • D. Chernyshov, M. Hostettler, K. W. Törnroos, H.-B. Bürgi, Angew. Chem. 2003, 115, 3955; Angew. Chem. Int. Ed. 2003, 42, 3825.
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 3825
  • 14
    • 33747086876 scopus 로고    scopus 로고
    • IUCr & Kluwer
    • This is a non-standard setting of layer-group 17 (International Tables of Crystallography, Vol. E, IUCr & Kluwer, 2002) chosen to be compatible with the space group symmetries.
    • (2002) International Tables of Crystallography, Vol. E
  • 15
    • 5344254866 scopus 로고    scopus 로고
    • note
    • [10]
  • 16
    • 5344244327 scopus 로고    scopus 로고
    • note
    • The two different, if very similar packing modes observed in this family of structures may be related to the ellipsoidal shape of the exposed hydrocarbon part of the solvent molecules. Methanol and tert-butyl alcohol seem to fit the wedge shaped cavities formed by two pyridine rings of a single complex in the next layer, if successive layers are packed across twofold axes. For all other solvents an optimal fit seems to require stacking of layers across centers of inversion.
  • 18
    • 33748222980 scopus 로고
    • P. Gütlich, P. Poganiuch, Angew. Chem. 1991, 103, 1015; Angew. Chem. Int. Ed. Engl. 1991, 30, 975.
    • (1991) Angew. Chem. Int. Ed. Engl. , vol.30 , pp. 975
  • 26
    • 5344236346 scopus 로고    scopus 로고
    • note
    • Detailed results of these studies will be published elsewhere.
  • 30
    • 5344256026 scopus 로고    scopus 로고
    • note
    • CCDC-239326-239331 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/ conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.