Copper-catalyzed enantioselective allylic alkylation of terminal alkyne pronucleophiles

Journal of the American Chemical Society

Volumn 136, Issue 39, 2014, Pages 13932-13939

  Harada, Ayumi ^a   Makida, Yusuke ^a   Sato, Tatsunori ^a   Ohmiya, Hirohisa ^a   Sawamura, Masaya ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; ALLYLATION; CATALYSIS; COPPER; HYDROCARBONS; LIGANDS; SUBSTITUTION REACTIONS;

ALLYLIC ALKYLATION; ALLYLIC PHOSPHATES; CHIRAL N-HETEROCYCLIC CARBENES; HIGH ENANTIOSELECTIVITY; PHENOLIC HYDROXY GROUP; REACTION PATHWAYS; SELECTIVE SUBSTITUTION; STEREOGENIC CENTERS;

ENANTIOSELECTIVITY;

1,10 PHENANTHROLINE; ALKENE; ALKYNE; CARBENE; COPPER; HYDROXYL GROUP; LEWIS ACID; NUCLEOPHILE; PHOSPHATE; TOLUENE;

ALKYLATION; ALKYNYLATION; ARTICLE; CATALYSIS; CHEMICAL BOND; ENANTIOMER; ENANTIOSELECTIVITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; HYDROGEN BOND; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STOICHIOMETRY; SUBSTITUTION REACTION;

EID: 84949116882     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5084333     Document Type: Article

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