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Volumn 54, Issue 14, 2015, Pages 6928-6937

Design and Characterization of Phosphine Iron Hydrides: Toward Hydrogen-Producing Catalysts

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; HYDROGENASE; IRON DERIVATIVE; PHOSPHINE; PHOSPHINE DERIVATIVE;

EID: 84937719038     PISSN: 00201669     EISSN: 1520510X     Source Type: Journal    
DOI: 10.1021/acs.inorgchem.5b00911     Document Type: Article
Times cited : (21)

References (81)
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    • Bullock, M. R. Science 2013, 342, 1080-1083
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    • Bullock, M.R.1
  • 49
    • 84937718080 scopus 로고    scopus 로고
    • note
    • One-electron oxidized samples were prepared electrochemically by constant potential coulometry at -35 °C in fluorobenzene in a dry argon glovebox. The EPR spectra of [1Cl]+ and [2Cl]+ measured at X-band at 10 K (not shown) revealed well-resolved g-values of (2.314, 2.066, 2.005) and (2.327, 2.068, 2.001), respectively. This indicates that for these compounds the piano-stool geometry is maintained in frozen solution.
  • 51
    • 84937716493 scopus 로고    scopus 로고
    • note
    • EPR spectra of one-electron oxidized compounds (prepared as described above), [1H]+ and [2H]+, were composed of at least two species for which the g-values could not be exclusively identified. Moreover, the H/D exchange for [1H]+ and [2H]+ did not lead to any changes in the CW EPR or Q-Band ENDOR spectra at 2 K. This is, presumably, due to decomposition during the time course of coulometric one-electron oxidation in fluorobenzene. Trapping the stable Fe(III)-H species is in progress, but it is outside the scope of this work and will be reported in a separate paper.
  • 70
    • 84937692870 scopus 로고    scopus 로고
    • Bruker-AXS Inc. Madison, WI
    • SAINT, version 7.46A; Bruker-AXS Inc.: Madison, WI, 2008.
    • (2008) SAINT, Version 7.46A
  • 71
    • 84862132168 scopus 로고    scopus 로고
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    • SADABS, version 2009/1; Bruker-AXS Inc.: Madison, WI, 2009.
    • (2009) SADABS, Version 2009/1
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    • University of Göttingen: Göttingen
    • Sheldrick, G. M. SHELXL; University of Göttingen: Göttingen, 2013.
    • (2013) SHELXL
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.