A model of the [FeFe] hydrogenase active site with a biologically relevant azadithiolate bridge: A spectroscopic and theoretical investigation

Angewandte Chemie - International Edition

Volumn 50, Issue 6, 2011, Pages 1439-1443

  Erdem, Özlen F ^a   Schwartz, Lennart ^b   Stein, Matthias ^c   Silakov, Alexey ^a   Kaur Ghumaan, Sandeep ^b   Huang, Ping ^b   Ott, Sascha ^b   Reijerse, Edward J ^a   Lubitz, Wolfgang ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^b UPPSALA UNIVERSITY   (Sweden)

^c MAX PLANCK INSTITUTE FOR DYNAMICS OF COMPLEX TECHNICAL SYSTEMS   (Germany)

Author keywords

density functional calculations; ENDOR spectroscopy; enzyme models; EPR spectroscopy; hydrogenases

Indexed keywords

DENSITY-FUNCTIONAL CALCULATIONS; ENDOR SPECTROSCOPY; ENZYME MODELS; EPR SPECTROSCOPY; HYDROGENASES;

ATOMIC SPECTROSCOPY; DENSITY FUNCTIONAL THEORY; ENZYMES; PARAMAGNETIC RESONANCE;

ELECTRON SPIN RESONANCE SPECTROSCOPY;

HETEROCYCLIC COMPOUND; HYDROGENASE; IRON HYDROGENASE; IRON SULFUR PROTEIN; THIOL DERIVATIVE;

ARTICLE; CHEMISTRY; ELECTROCHEMICAL ANALYSIS; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; INFRARED SPECTROSCOPY; METABOLISM; THEORETICAL MODEL;

AZA COMPOUNDS; CATALYTIC DOMAIN; ELECTROCHEMICAL TECHNIQUES; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDROGENASE; IRON-SULFUR PROTEINS; MODELS, THEORETICAL; SPECTROSCOPY, FOURIER TRANSFORM INFRARED; SULFHYDRYL COMPOUNDS;

EID: 79551678796     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201006244     Document Type: Article

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