Influence of the [2Fe]H subcluster environment on the properties of key intermediates in the catalytic cycle of [FeFe] hydrogenases: Hints for the rational design of synthetic catalysts

Angewandte Chemie - International Edition

Volumn 48, Issue 19, 2009, Pages 3503-3506

  Bruschi, Maurizio ^a   Greco, Claudio ^a   Kaukonen, Markus ^b   Fantucci, Piercarlo ^a   Ryde, Ulf ^b   De Gioia, Luca ^a  

^a UNIVERSITY OF MILANO BICOCCA   (Italy)

^b LUND UNIVERSITY   (Sweden)

Author keywords

Bioinorganic chemistry; Density functional calculations; Enzyme catalysis hydrogen; Quantum chemistry

Indexed keywords

[FEFE]HYDROGENASES; BIO-INSPIRED; BIOINORGANIC CHEMISTRY; CATALYTIC CYCLES; COFACTORS; DENSITY FUNCTIONAL CALCULATIONS; ENZYME CATALYSIS HYDROGEN; HYDRIDE LIGANDS; RATIONAL DESIGN; RELATIVE STABILITIES; THEORETICAL STUDY;

BIOCHEMISTRY; CATALYSIS; CATALYSTS; CHEMICAL PROPERTIES; CHEMICAL STABILITY; ENZYMES; HYDROGEN; QUANTUM THEORY;

QUANTUM CHEMISTRY;

HYDROGEN; HYDROGENASE; IRON;

CATALYSIS; CHEMICAL MODEL; CHEMISTRY; ENZYME STABILITY; PROTEIN CONFORMATION;

CATALYSIS; ENZYME STABILITY; HYDROGEN; HYDROGENASE; IRON; MODELS, CHEMICAL; PROTEIN CONFORMATION;

EID: 70349784948     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200900494     Document Type: Article

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