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Volumn 357, Issue 9, 2015, Pages 2011-2016

Tert-Butyl Sulfoxides: Key Precursors for Palladium-Catalyzed Arylation of Sulfenate Salts

Author keywords

cross coupling; diastereoselectivity; palladium; sulfenate salts; sulfoxides

Indexed keywords


EID: 84931287919     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201500368     Document Type: Article
Times cited : (54)

References (51)
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    • During the manuscript preparation, Walsh reported the use of tert-butyl phenyl sulfoxide to provide benzenesulfenate.
    • During the manuscript preparation, Walsh reported the use of tert-butyl phenyl sulfoxide to provide benzenesulfenate:, M. Zhang, T. Jia, I. K. Sagamanova, M. A. Pericás, P. J. Walsh, Org. Lett. 2015, 17, 1164-1167.
    • (2015) Org. Lett. , vol.17 , pp. 1164-1167
    • Zhang, M.1    Jia, T.2    Sagamanova, I.K.3    Pericás, M.A.4    Walsh, P.J.5
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    • Formation of the transient arenesulfenic acid was evidenced by a trapping experiment with methyl propiolate, as described in the Supporting Information. See.
    • Formation of the transient arenesulfenic acid was evidenced by a trapping experiment with methyl propiolate, as described in the Supporting Information. See:, M. C. Aversa, A. Barattucci, P. Bonaccorsi, A. Contini, J. Phys. Org. Chem. 2009, 22, 1048-1057.
    • (2009) J. Phys. Org. Chem. , vol.22 , pp. 1048-1057
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    • Polar solvents are generally preferred with triflates, due to the intermediacy of a cationic (σ-aryl)palladium complex.
    • Polar solvents are generally preferred with triflates, due to the intermediacy of a cationic (σ-aryl)palladium complex:, A. Jutand, A. Mosleh, Organometallics 1995, 14, 1810-1817.
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    • Jutand, A.1    Mosleh, A.2


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