Gas-Phase Detection of HSOH: Synthesis by Flash Vacuum Pyrolysis of Di-tert-butyl Sulfoxide and Rotational-Torsional Spectrum

Chemistry - A European Journal

Volumn 9, Issue 22, 2003, Pages 5501-5510

  Winnewisser, Gisbert ^a   Lewen, Frank ^a   Thorwirth, Sven ^a   Behnke, Markus ^b   Hahn, Josef ^a   Gauss, Jürgen ^c   Herbst, Eric ^b  

^a UNIVERSITY OF COLOGNE   (Germany)

^b OHIO STATE UNIVERSITY   (United States)

^c JOHANNES GUTENBERG UNIVERSITY   (Germany)

Author keywords

Ab initio calculations; Flash vacuum pyrolysis; Mass spectrometry; Oxasulfanes; Rotational spectroscopy

Indexed keywords

HYDROGEN PEROXIDE; LEAST SQUARES APPROXIMATIONS; MASS SPECTROMETRY; MICROWAVE SPECTROSCOPY; OPTIMIZATION; PYROLYSIS;

QUANTUM NUMBERS;

SYNTHESIS (CHEMICAL);

HYDROGEN PEROXIDE; N4 SULFANILYLSULFANILAMIDE; OXADISULFANE; SULFOXIDE; SULFUR DERIVATIVE; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; ARTICLE; FLASH VACUUM PYROLYSIS; GAS; MASS SPECTROMETRY; PYROLYSIS; QUANTUM CHEMISTRY; ROTATION; SPECTROSCOPY; SPECTRUM; SYNTHESIS;

EID: 0346458665     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200305192     Document Type: Article

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54. Note added in proof (September 9, 2003): Initiated by a seminar at the ETH Zürich presented by one of us (G.W., fall 2001), M. Quack and M. Willeke computed the torsional tunneling splitting for the vibrational ground state of HSOH (M. Quack and M. Willeke, Helv. Chim. Acta 2003, 86, 1641-1653) in good agreement with the present experimental results. We thank Prof. M. Quack (ETH Zürich) for drawing our attention to his results.