Hybrid alginate based aerogels by carbon dioxide induced gelation: Novel technique for multiple applications

Journal of Supercritical Fluids

Volumn 106, Issue , 2015, Pages 23-33

  Raman, S P ^a   Gurikov, Pavel ^a   Smirnova, Irina ^a  

^a HAMBURG UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Aerogels; Alginate; Biopolymer; Hybrid; Hydrogel; Thermal insulation

Indexed keywords

AEROGELS; ALGINATE; BIOMOLECULES; BIOPOLYMERS; CARBON DIOXIDE; CELLULOSE; FILLED POLYMERS; FILLER METALS; FILLERS; GELATION; HYDROGELS; PORE SIZE; SILICA; SILICATES; SODIUM ALGINATE; SUPERCRITICAL FLUID EXTRACTION; THERMAL CONDUCTIVITY; TITANIUM DIOXIDE;

ALGINATE SOLUTIONS; CARBOXY-METHYL CELLULOSE; FILLER MATERIALS; HIGH SPECIFIC SURFACE AREA; HYBRID; MULTIPLE APPLICATIONS; PRESSURIZED CARBON DIOXIDE; SUPERCRITICAL CO2;

THERMAL INSULATION;

EID: 84929915143     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2015.05.003     Document Type: Article

References (53)

1. Smirnova, I., Arlt, W., Synthesis of silica aerogels: influence of the supercritical CO2 on the sol–gel process. J. Sol–Gel Sci. Technol. 28 (2003), 175–184.
2. Aerogels Handbook. Aegerter, M.A., Leventis, N., Koebel, M.M., (eds.), 2011, Springer New York, New York, NY.
3. Nguyen, S.T., Feng, J., Ng, S.K., Wong, J.P.W., Tan, V.B.C., Duong, H.M., Advanced thermal insulation and absorption properties of recycled cellulose aerogels. Colloids Surf. A: Physicochem. Eng. Aspects 445 (2014), 128–134.
4. Fischer, F., Rigacci, A., Pirard, R., Berthon-Fabry, S., Achard, P., Cellulose-based aerogels. Polymer 47 (2006), 7636–7645.
5. Rudaz, C., Courson, R., Bonnet, L., Calas-Etienne, S., Sallée, H., Budtova, T., Aeropectin: fully biomass-based mechanically strong and thermal superinsulating aerogel. Biomacromolecules 15 (2014), 2188–2195.
6. Cai, J., Liu, S., Feng, J., Kimura, S., Wada, M., Kuga, S., et al. Cellulose-silica nanocomposite aerogels by in situ formation of silica in cellulose gel. Angew. Chem. 124 (2012), 2118–2121.
7. Grishechko, L.I., Amaral-Labat, G., Szczurek, A., Fierro, V., Kuznetsov, B.N., Pizzi, A., et al. New tannin–lignin aerogels. Ind. Crops Prod. 41 (2013), 347–355.
8. Gurikov, P., Raman, S.P., Weinrich, D., Fricke, M., Smirnova, I., A novel approach to alginate aerogels: carbon dioxide induced gelation. RSC Adv. 5 (2015), 7812–7818.
9. Quraishi, S., Martins, M., Barros, A.A., Gurikov, P., Raman, S.P., Smirnova, I., Novel non-cytotoxic alginate–lignin hybrid aerogels as scaffolds for tissue engineering. J. Supercrit. Fluids, 2015, 10.1016/j.supflu.2014.12.026 accepted.
10. García-González, C.A., Alnaief, M., Smirnova, I., Polysaccharide-based aerogels–Promising biodegradable carriers for drug delivery systems. Carbohydr. Polym. 86 (2011), 1425–1438.
11. Betz, M., García-González, C.A., Subrahmanyam, R.P., Smirnova, I., Kulozik, U., Preparation of novel whey protein-based aerogels as drug carriers for life science applications. J. Supercrit. Fluids 72 (2012), 111–119.
12. Comin, L.M., Temelli, F., Saldaña, M.D.A., Barley β-glucan aerogels as a carrier for flax oil via supercritical CO2. J. Food Eng. 111 (2012), 625–631.
13. Monakhova, Y., Agulhon, P., Quignard, F., Tanchoux, N., Tichit, D., New mixed lanthanum- and alkaline-earth cation-containing basic catalysts obtained by an alginate route. Catal. Today 189 (2012), 28–34.
14. Kayser, H., Müller, C.R., García-González, C.A., Smirnova, I., Leitner, W., Domínguez de María, P., Dried chitosan-gels as organocatalysts for the production of biomass-derived platform chemicals. Appl. Catal. A: Gen. 445–446 (2012), 180–186.
15. Mallepally, R.R., Bernard, I., Marin, M.A., Ward, K.R., McHugh, M.A., Superabsorbent alginate aerogels. J. Supercrit. Fluids 79 (2013), 202–208.
16. Escudero, R.R., Robitzer, M., Di Renzo, F., Quignard, F., Alginate aerogels as adsorbents of polar molecules from liquid hydrocarbons: hexanol as probe molecule. Carbohydr. Polym. 75 (2009), 52–57.
17. Trens, P., Valentin, R., Quignard, F., Cation enhanced hydrophilic character of textured alginate gel beads. Colloids Surf. A: Physicochem. Eng. Aspects 296 (2007), 230–237.
18. Wu, Z.-Y., Li, C., Liang, H.-W., Chen, J.-F., Yu, S.-H., Ultralight, flexible, and fire-resistant carbon nanofiber aerogels from bacterial cellulose. Angew. Chem. Int. Ed. 52 (2013), 2925–2929.
19. Agulhon, P., Constant, S., Chiche, B., Lartigue, L., Larionova, J., Di Renzo, F., et al. Controlled synthesis from alginate gels of cobalt–manganese mixed oxide nanocrystals with peculiar magnetic properties. Catal. Today 189 (2012), 49–54.
20. Lu, X., Arduini-Schuster, M.C., Kuhn, J., Nilsson, O., Fricke, J., Pekala, R.W., Thermal conductivity of monolithic organic aerogels. Science 255 (1992), 971–972.
21. Lee, J.K., Gould, G.L., Rhine, W., Polyurea based aerogel for a high performance thermal insulation material. J. Sol–Gel Sci. Technol. 49 (2009), 209–220.
22. Della Porta, G., Del Gaudio, P., De Cicco, F., Aquino, R.P., Reverchon, E., Supercritical drying of alginate beads for the development of aerogel biomaterials: optimization of process parameters and exchange solvents. Ind. Eng. Chem. Res. 52 (2013), 12003–12009.
23. Brown, Z.K., Fryer, P.J., Norton, I.T., Bridson, R.H., Drying of agar gels using supercritical carbon dioxide. J. Supercrit. Fluids 54 (2010), 89–95.
24. Floren, M.L., Spilimbergo, S., Motta, A., Migliaresi, C., Carbon dioxide induced silk protein gelation for biomedical applications. Biomacromolecules 13 (2012), 2060–2072.
25. Mallepally, R.R., Marin, M.A., McHugh, M.A., CO2-assisted synthesis of silk fibroin hydrogels and aerogels. Acta Biomater. 10 (2014), 4419–4424.
26. Perez-Cantu, L., Schreiber, A., Schütt, F., Saake, B., Kirsch, C., Smirnova, I., Comparison of pretreatment methods for rye straw in the second generation biorefinery: effect on cellulose, hemicellulose and lignin recovery. Bioresour. Technol. 142 (2013), 428–435.
27. Muzzarelli, C., Tosi, G., Francescangeli, O., Muzzarelli, R.A.A., Alkaline chitosan solutions. Carbohydr. Res. 338 (2003), 2247–2255.
28. Gavillon, R., Budtova, T., Aerocellulose: new highly porous cellulose prepared from cellulose-NaOH aqueous solutions. Biomacromolecules 9 (2007), 269–277.
29. Ebert, H.-P., Bock, V., Nilsson, O., Fricke, J., The hot-wire method applied to porous materials of low thermal conductivity. High Temp. High Pressures 25 (1993), 391–402.
30. Draget, K.I., Skjåk-Bræk, G., Smidsrød, O., Alginate based new materials. Int. Jo. Biol. Macromol. 21 (1997), 47–55.
31. Quignard, F., Valentin, R., Di Renzo, F., Aerogel materials from marine polysaccharides. New J. Chem., 32, 2008, 1300.
32. Pawar, S.N., Edgar, K.J., Alginate derivatization: a review of chemistry, properties and applications. Biomaterials 33 (2012), 3279–3305.
33. Donati, I., Asaro, F., Paoletti, S., Experimental evidence of counterion affinity in alginates: the case of nongelling ion Mg 2+. J. Phys. Chem. B 113 (2009), 12877–12886.
34. Topuz, F., Henke, A., Richtering, W., Groll, J., Magnesium ions and alginate do form hydrogels: a rheological study. Soft Matter, 8, 2012, 4877.
35. Baes, C.F., Mesmer, R.E., The Hydrolysis of Cations. 1976, J Wiley Sons, N. Y, 174.
36. Donati, I., Paoletti, S., Material properties of alginates. Rehm, B.H.A., (eds.) Alginates Biology and Applications, 2009, Springer Berlin Heidelberg, Berlin Heidelberg, 1–53.
37. Agulhon, P., Robitzer, M., David, L., Quignard, F., Structural regime identification in ionotropic alginate gels: influence of the cation nature and alginate structure. Biomacromolecules 13 (2012), 215–220.
38. Horga, R., Di Renzo, F., Quignard, F., Ionotropic alginate aerogels as precursors of dispersed oxide phases. Appl. Catal. A: Gen. 325 (2007), 251–255.
39. Garmo, Ø.A., Røyset, O., Steinnes, E., Flaten, T.P., Performance study of diffusive gradients in thin films for 55 elements. Anal. Chem. 75 (2003), 3573–3580.
40. Draget, K.I., Gåserød, O., Aune, I., Andersen, P.O., Storbakken, B., Stokke, B.T., et al. Effects of molecular weight and elastic segment flexibility on syneresis in Ca-alginate gels. Food Hydrocolloids 15 (2001), 485–490.
41. Jørgensen, T.E., Sletmoen, M., Draget, K.I., Stokke, B.T., Influence of oligoguluronates on alginate gelation, kinetics, and polymer organization. Biomacromolecules 8 (2007), 2388–2397.
42. Robitzer, M., David, L., Rochas, C., Di Renzo, F., Quignard, F., Supercritically-dried alginate aerogels retain the fibrillar structure of the hydrogels. Macromol. Symp. 273 (2008), 80–84.
43. Davidovich-Pinhas, M., Bianco-Peled, H., A quantitative analysis of alginate swelling. Carbohydr. Polym. 79 (2010), 1020–1027.
44. Li, L., Fang, Y., Vreeker, R., Appelqvist, I., Mendes, E., Reexamining the egg-box model in calcium–alginate gels with X-ray diffraction. Biomacromolecules 8 (2007), 464–468.
45. Wang, Z., Kale, G.M., Ghadiri, M., Novel ion-exchange process for the preparation of metal oxide nanopowders from sodium alginate. J. Am. Ceram. Soc. 95 (2012), 3124–3129.
46. Sriamornsak, P., Investigation of pectin as a carrier for oral delivery of proteins using calcium pectinate gel beads. Int. J. Pharm. 169 (1998), 213–220.
47. Tho, I., Arne Sande, S., Kleinebudde, P., Cross-linking of amidated low-methoxylated pectin with calcium during extrusion/spheronisation: Effect on particle size and shape. Granulation across the length scales - 2nd International Workshop on Granulation Granulation across the length scales - 2nd International Workshop on Granulation 60 (2005), 3899–3907.
48. Mohamadnia, Z., Zohuriaan-Mehr, M.J., Kabiri, K., Jamshidi, A., Mobedi, H., pH-sensitive IPN hydrogel beads of carrageenan-alginate for controlled drug delivery. J. Bioact. Compat. Polym. 22 (2007), 342–356.
49. Swimm, K., Reichenauer, G., Vidi, S., Ebert, H.-P., Gas pressure dependence of the heat transport in porous solids with pores smaller than 10 μm. Int. J. Thermophys. 30 (2009), 1329–1342.
50. Russo, R., Giuliani, A., Immirzi, B., Malinconico, M., Romano, G., Alginate/polyvinylalcohol blends for agricultural applications: structure-properties correlation, mechanical properties and greenhouse effect evaluation. Macromol. Symp. 169 (2001), 241–250.
51. Kim, J.O., Choi, J.Y., Park, J.K., Kim, J.H., Jin, S.G., Chang, S.W., et al. Development of clindamycin-loaded wound dressing with polyvinyl alcohol and sodium alginate. Biol. Pharm. Bull. 31 (2008), 2277–2282.
52. Cho, S.H., Lim, S.M., Han, D.K., Yuk, S.H., Im, G.I., Lee, J.H., Time-dependent alginate/polyvinyl alcohol hydrogels as injectable cell carriers. journal of biomaterials science. Polym. Ed. 20 (2009), 863–876.
53. Luo, H., Lu, H., Leventis, N., The compressive behavior of isocyanate-crosslinked silica aerogel at high strain rates. Mech. Time-Depend. Mater. 10 (2006), 83–111.