Effect of different plasticisers on the mechanical and barrier properties of extruded cast PHBV films

European Polymer Journal

Volumn 68, Issue , 2015, Pages 302-312

  Jost, Verena ^a,b   Langowski, Horst Christian ^a,b  

^a FRAUNHOFER INSTITUTE FOR PROCESS ENGINEERING AND PACKAGING IVV   (Germany)

^b TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

Mechanical properties; Permeability; PHBV; Plasticiser

Indexed keywords

BIODEGRADABLE POLYMERS; ELASTIC MODULI; FRACTURE MECHANICS; FUNCTIONAL GROUPS; MECHANICAL PROPERTIES; OIL SHALE; PLASTICIZERS; POLYETHYLENE GLYCOLS; POLYETHYLENES; POLYMERS; PROPYLENE; SOLVENTS; SOYBEAN OIL; TENSILE STRENGTH;

BIODEGRADABLE THERMOPLASTICS; CONVENTIONAL POLYMERS; CRYSTALLINITIES; ELONGATION AT BREAK; MECHANICAL AND BARRIERS; OXYGEN PERMEABILITY; PHBV; PROPYLENE GLYCOLS;

MECHANICAL PERMEABILITY;

EID: 84929310075     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2015.04.012     Document Type: Article

References (46)

1. C. Thellen A processing, characterization and marine biodegradation study of melt-extruded Polyhydroxyalkanoate (PHA) films J Polym Environ 16 1 2008 1 11 10.1007/s10924-008-0079-6
2. Lemoigne M. Produits de dehydration et de polymerisation de l'acide ß-oxobutyrique. Bulletin de la Société chimique de France; 1926.
3. L.L. Wallen, and W.K. Rohwedder Poly-. beta.-hydroxyalkanoate from activated sludge Environ Sci Technol 8 6 1974 576 579 10.1021/es60091a007
4. K. Sudesh, H. Abe, and Y. Doi Synthesis, structure and properties of polyhydroxyalkanoates: biological polyesters Prog Polym Sci 25 10 2000 1503 1555 10.1016/S0079-6700(00)00035-6
5. R.A.J. Verlinden Bacterial synthesis of biodegradable polyhydroxyalkanoates J Appl Microbiol 102 6 2007 1437 1449 10.1111/j.1365-2672.2007.03335.x
6. G. Menges Werkstoffkunde Kunststoffe vol. 6 2011 Carl Hanser Verlag München
7. L. Savenkova Mechanical properties and biodegradation characteristics of PHB-based films Process Biochem 35 6 2000 573 579 10.1016/s0032-9592(99)00107-7
8. P.J. Barham Crystallization and morphology of a bacterial thermoplastic: poly-3-hydroxybutyrate J Mater Sci 19 9 1984 2781 2794 10.1007/BF01026954
9. A.J. Domb Degradable polymer blends. I. Screening of miscible polymers J Polym Sci, Part A: Polym Chem 31 8 1993 1973 1981 10.1002/pola.1993.080310805
10. S. Modi, K. Koelling, and Y. Vodovotz Assessment of PHB with varying hydroxyvalerate content for potential packaging applications Eur Polymer J 47 2 2011 179 186 10.1016/j.eurpolymj.2010.11.010
11. X. Wang Miscibility, crystallization kinetics, and mechanical properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(PHBV)/poly(3-hydroxybutyrate-co-4-hydroxybutyrate)(P3/4HB) blends J Appl Polym Sci 117 2 2010 838 848 10.1002/app.31215
12. H.-J. Endres, and A. Siebert-Raths Engineering biopolymers markets, manufacturing, properties, and applications 2011 Carl Hanser Verlag Munich
13. J.L. Audic, L. Lemiegre, and Y.M. Corre Thermal and mechanical properties of a polyhydroxyalkanoate plasticized with biobased epoxidized broccoli oil J Appl Polym Sci 131 6 2014 39983 (1) 39983 (7) 10.1002/app.39983
14. D.G. Brunel Natural additives for Poly(Hydroxybutyrate-CO-Hydroxyvalerate) - PHBV: effect on mechanical properties and biodegradation Mater Res-Ibero-Am J Mater 17 5 2014 1145 1156 10.1590/1516-1439.235613
15. S.E.M. Catoni Influence of Poly(Ethylene Grycol)-(PEG) on the properties of influence of Poly(3-Hydroxybutyrate-CO-3-Hydroxyvalerate)-PHBV Polimeros-Cienc E Tecnol 23 3 2013 320 325 10.4322/polimeros.2013.037
16. M.P. Arrieta Combined effect of poly(hydroxybutyrate) and plasticizers on polylactic acid properties for film intended for food packaging J Polym Environ 22 4 2014 460 470 10.1007/s10924-014-0654-y
17. A.M. El-Hadi Development of novel biopolymer blends based on poly(l-lactic acid), poly((R)-3-hydroxybutyrate), and plasticizer Polym Eng Sci 54 6 2014 1394 1402 10.1002/pen.23676
18. Patrícia S. de O. Patrício, Fabiano V. Pereira, Meriane C. dos Santos, Patterson P. de Souza, Juan P.B. Roa, and Rodrigo L. Orefice Increasing the elongation at break of polyhydroxybutyrate biopolymer: effect of cellulose nanowhiskers on mechanical and thermal properties J Appl Polym Sci 127 5 2013 3613 3621 10.1002/app.37811
19. L. Martino Understanding external plasticization of melt extruded PHBV-wheat straw fibers biodegradable composites for food packaging J Appl Polym Sci 2015 10.1002/APP.41611
20. B. Fei Modified poly(3-hydroxybutyrate-co-3-hydroxyvalerate) using hydrogen bonding monomers Polymer 45 18 2004 6275 6284 10.1016/j.polymer.2004.07.008
21. G.J.M. Dekoning Crystallization phenomena in bacterial poly (R)-3-hydroxybutyrate. 3. Toughening via texture changes Polymer 35 21 1994 4598 4605 10.1016/0032-3861(94)90809-5
22. Y. Parulekar, and A.K. Mohanty Extruded biodegradable cast films from polyhydroxyalkanoate and thermoplastic starch blends: fabrication and characterization Macromol Mater Eng 292 12 2007 1218 1228 10.1002/mame.200700125
23. D. Jagadeesh Preparation and properties of propylene glycol plasticized wheat protein isolate novel green films J Polym Environ 21 4 2013 930 936 10.1007/s10924-013-0572-4
24. O. Orliac Effects of various plasticizers on the mechanical properties, water resistance and aging of thermo-moulded films made from sunflower proteins Ind Crops Prod 18 2 2003 91 100 10.1016/s0926-6690(03)00015-3
25. H. Li, and M.A. Huneault Comparison of sorbitol and glycerol as plasticizers for thermoplastic starch in TPS/PLA blends J Appl Polym Sci 119 4 2011 2439 2448 10.1002/app.32956
26. D. Muscat Comparative study of film forming behaviour of low and high amylose starches using glycerol and xylitol as plasticizers J Food Eng 109 2 2012 189 201 10.1016/j.jfoodeng.2011.10.019
27. V.P. Ghiya Biodegradability of cellulose acetate plasticized with citrate esters J Macromol Sci, Part A 33 5 1996 627 638 10.1080/10601329608010883
28. J.S. Choi, and W.H. Park Effect of biodegradable plasticizers on thermal and mechanical properties of poly(3-hydroxybutyrate) Polym Testing 23 4 2004 455 460 10.1016/j.polymertesting.2003.09.005
29. M. Rahman, and C.S. Brazel The plasticizer market: an assessment of traditional plasticizers and research trends to meet new challenges Prog Polym Sci 29 12 2004 1223 1248 10.1016/j.progpolymsci.2004.10.001
30. J.S. Choi, and W.H. Park Thermal and mechanical properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) plasticized by biodegradable soybean oils Macromol Symp 197 1 2003 65 76 10.1002/masy.200350707
31. R. Sothornvit, and J.M. Krochta Plasticizer effect on mechanical properties of β-lactoglobulin films J Food Eng 50 3 2001 149 155 10.1016/S0260-8774(00)00237-5
32. S. Wong, R. Shanks, and A. Hodzic Properties of poly(3-hydroxybutyric acid) composites with flax fibres modified by plasticiser absorption Macromol Mater Eng 287 10 2002 647 655 10.1002/1439-2054(200210)287:10<647::aid-mame647>3.0.co;2-7
33. C.J.R. Verbeek, and L.E. van den Berg Extrusion processing and properties of protein-based thermoplastics Macromol Mater Eng 295 1 2010 10 21 10.1002/mame.200900167
34. T.A. Osswald, and G. Menges Materials science of polymers for engineers 2012 Hanser Publishers, Munich; Hanser Publications Cincinnati, Munich, Germany 614
35. M. Scandola Polymer blends of natural poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and a synthetic atactic poly(3-hydroxybutyrate). Characterization and biodegradation studies Macromolecules 30 9 1997 2568 2574 10.1021/ma961431y
36. H. Sato Infrared spectroscopy and X-ray diffraction studies of thermal behavior and lamella structures of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (P(HB-co-HV)) with PHB-type crystal structure and PHV-type crystal structure Macromolecules 44 8 2011 2829 2837 10.1021/ma102723n
37. A. Javadi Processing and characterization of solid and microcellular PHBV/PBAT blend and its RWF/nanoclay composites Compos A Appl Sci Manuf 41 8 2010 982 990 10.1016/j.compositesa.2010.04.002
38. Elias H.G., Makromoleküle: Band 3: Industrielle Polymere und Synthesen. Wiley; 2009.
39. M. Avella, E. Martuscelli, and M. Raimo Review properties of blends and composites based on poly(3-hydroxy)butyrate (PHB) and poly(3-hydroxybutyrate-hydroxyvalerate) (PHBV) copolymers J Mater Sci 35 3 2000 523 545 10.1023/A:1004740522751
40. S. Modi, K. Koelling, and Y. Vodovotz Miscibility of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with high molecular weight poly(lactic acid) blends determined by thermal analysis J Appl Polym Sci 124 4 2012 3074 3081 10.1002/app.35343
41. Wypych G. Handbook of plasticizers. ChemTec Pub; 2004.
42. M. Corrêa Elaboration and characterization of nano-biocomposites based on plasticized poly(hydroxybutyrate-co-hydroxyvalerate) with organo-modified montmorillonite J Polym Environ 20 2 2012 283 290 10.1007/s10924-011-0379-0
43. D.F. Parra Influence of poly (ethylene glycol) on the thermal, mechanical, morphological, physical-chemical and biodegradation properties of poly (3-hydroxybutyrate) Polym Degrad Stab 91 9 2006 1954 1959 10.1016/j.polymdegradstab.2006.02.008
44. V. Jost Influence of plasticiser on the barrier, mechanical and grease resistance properties of alginate cast films Carbohydr Polym 110 2014 309 319 10.1016/j.carbpol.2014.03.096
45. C. Courgneau Effect of crystallization on barrier properties of formulated polylactide Polym Int 61 2 2012 180 189
46. M. Erceg, T. Kovačić, and I. Klarić Thermal degradation of poly(3-hydroxybutyrate) plasticized with acetyl tributyl citrate Polym Degrad Stab 90 2 2005 313 318 10.1016/j.polymdegradstab.2005.04.048