Enhanced reactivity in hydrogen atom transfer from tertiary sites of cyclohexanes and decalins via strain release: Equatorial c-h activation vs axial C-H deactivation

Journal of Organic Chemistry

Volumn 80, Issue 9, 2015, Pages 4710-4715

  Salamone, Michela ^a   Ortega, Vanesa B ^a   Bietti, Massimo ^a  

^a UNIVERSITY OF ROME TOR VERGATA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; ATOMS; CYCLOHEXANE; FREE RADICAL REACTIONS; HYDROGEN; ISOMERS; ORGANIC SOLVENTS; PHOTOLYSIS; RATE CONSTANTS;

C-H FUNCTIONALIZATION; CIS AND TRANS ISOMERS; ENHANCED REACTIVITY; HYDROGEN ATOM TRANSFERS (HAT); HYDROGEN-ATOM TRANSFER; LASER FLASH PHOTOLYSIS; METHYLCYCLOPENTANE; QUANTITATIVE EVALUATION;

ATOM LASERS;

1,2 DIMETHYLCYCLOHEXANE; 1,4 DIMETHYLCYCLOHEXANE; CUMYLOXYL RADICAL; CYCLOHEXANE DERIVATIVE; CYCLOPENTANE DERIVATIVE; DECALIN DERIVATIVE; FUNCTIONAL GROUP; HYDROGEN; METHYLCYCLOHEXANE; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CIS ISOMER; COVALENT BOND; EVALUATION STUDY; LASER FLASH PHOTOLYSIS; MECHANICAL TORSION; NORMAL VALUE; OBSERVED RATE CONSTANT; OXIDATION KINETICS; PHOTOLYSIS; PROTON TRANSPORT; QUANTITATIVE STUDY; TRANS ISOMER;

EID: 84928902572     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/acs.joc.5b00636     Document Type: Article

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