The Interaction of Cobalt with CeO2(111) Prepared on Cu(111)

Journal of Physical Chemistry C

Volumn 119, Issue 17, 2015, Pages 9324-9333

  Vári, Gábor ^a   Óvári, László ^a   Papp, Christian ^b   Steinrück, Hans Peter ^b   Kiss, János ^a   Kónya, Zoltán ^a  

^a UNIVERSITY OF SZEGED   (Hungary)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CERIUM OXIDE; COBALT; REDOX REACTIONS; SURFACE REACTIONS;

CERIA FILMS; CO COVERAGE; COPPER CRYSTALS; CU(1 1 1); LOW ENERGY ION SCATTERING SPECTROSCOPY; ULTRA-THIN;

X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 84928816214     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/acs.jpcc.5b00626     Document Type: Article

References (65)

1. Trovarelli, A., Fornasiero, P., Eds. Catalysis by Ceria and Related Materials, 2nd ed.; Catalytic Science Series; Imperial College Press: London, 2013; Vol. 12.
2. Sun, C.; Li, H.; Chen, L. Nanostructured Ceria-Based Materials: Synthesis, Properties, and Applications Energy Environ. Sci. 2012, 5, 8475
3. 2-Containing Materials Catal. Rev. Sci. Eng. 1996, 38, 439-520
4. Park, S.; Vohs, J. M.; Gorte, R. J. Direct Oxidation of Hydrocarbons in a Solid-Oxide Fuel Cell Nature 2000, 404, 265-267
5. Deluga, G. A.; Salge, J. R.; Schmidt, L. D.; Verykios, X. E. Renewable Hydrogen from Ethanol by Autothermal Reforming Science 2004, 303, 993-997
6. Mattos, L. V.; Jacobs, G.; Davis, B. H.; Noronha, F. B. Production of Hydrogen from Ethanol: Review of Reaction Mechanism and Catalyst Deactivation Chem. Rev. 2012, 112, 4094-4123
7. 2(111) J. Catal. 2013, 307, 132-139
8. Ferencz, Z.; Erdohelyi, A.; Baán, K.; Oszkó, A.; Óvári, L.; Kónya, Z.; Papp, C.; Steinrück, H.-P.; Kiss, J. Effects of Support and Rh Additive on Co-Based Catalysts in the Ethanol Steam Reforming Reaction ACS Catal. 2014, 4, 1205-1218
9. Varga, E.; Ferencz, Z.; Oszkó, A.; Erdohelyi, A.; Kiss, J. Oxidation States of Active Catalytic Centers in Ethanol Steam Reforming Reaction on Ceria Based Rh Promoted Co Catalysts: An XPS Study J. Mol. Catal. A Chem. 2015, 397, 127-133
10. Soykal, I. I.; Sohn, H.; Singh, D.; Miller, J. T.; Ozkan, U. S. Reduction Characteristics of Ceria under Ethanol Steam Reforming Conditions: Effect of the Particle Size ACS Catal. 2014, 4, 585-592
11. Royer, S.; Duprez, D. Catalytic Oxidation of Carbon Monoxide over Transition Metal Oxides ChemCatChem 2011, 3, 24-65
12. Llorca, J.; Homs, N.; Sales, J.; de la Piscina, P. R. Efficient Production of Hydrogen over Supported Cobalt Catalysts from Ethanol Steam Reforming J. Catal. 2002, 209, 306-317
13. Lin, S. S.-Y.; Kim, D. H.; Ha, S. Y. Hydrogen Production from Ethanol Steam Reforming over Supported Cobalt Catalysts Catal. Lett. 2008, 122, 295-301
14. Llorca, J.; Homs, N.; de la Piscina, P. R. In Situ DRIFT-Mass Spectrometry Study of the Ethanol Steam-Reforming Reaction over Carbonyl-Derived Co/ZnO Catalysts J. Catal. 2004, 227, 556-560
15. Song, H.; Ozkan, U. S. The Role of Impregnation Medium on the Activity of Ceria-Supported Cobalt Catalysts for Ethanol Steam Reforming J. Mol. Catal. A Chem. 2010, 318, 21-29
16. Bayram, B.; Soykal, I. I.; von Deak, D.; Miller, J. T.; Ozkan, U. S. Ethanol Steam Reforming over Co-Based Catalysts: Investigation of Cobalt Coordination Environment under Reaction Conditions J. Catal. 2011, 284, 77-89
17. Hyman, M. P.; Vohs, J. M. Reaction of Ethanol on Oxidized and Metallic Cobalt Surfaces Surf. Sci. 2011, 605, 383-389
18. Martono, E.; Hyman, M. P.; Vohs, J. M. Reaction Pathways for Ethanol on Model Co/ZnO(0001) Catalysts Phys. Chem. Chem. Phys. 2011, 13, 9880-9886
19. Batista, M. S.; Santos, R. K. S.; Assaf, E. M.; Assaf, J. M.; Ticianelli, E. A. Characterization of the Activity and Stability of Supported Cobald Catalysts for the Steam Reforming of Ethanol J. Power Sources 2003, 124, 99-103
20. Freund, H.-J. Clusters and Islands on Oxides: From Catalysis via Electronics and Magnetism to Optics Surf. Sci. 2002, 500, 271-299
21. Diebold, U. The Surface Science of Titanium Dioxide Surf. Sci. Rep. 2003, 48, 53-229
22. Fu, Q.; Wagner, T. Interaction of Nanostructured Metal Overlayers with Oxide Surfaces Surf. Sci. Rep. 2007, 62, 431-498
23. 2(110): A LEIS and STM Study J. Phys. Chem. C 2008, 112, 18011-18016
24. 2(110) Surface Studied by STM and LEIS Langmuir 2010, 26, 2167-2175
25. 2(110) J. Catal. 2012, 289, 179-189
26. Mullins, D. R.; Radulovic, P. V.; Overbury, S. H. Ordered Cerium Oxide Thin Films Grown on Ru(0001) and Ni(111) Surf. Sci. 1999, 429, 186-198
27. 2(1 1 1) Films Grown on Ru(0 0 0 1) as Studied by Scanning Tunneling Microscopy Surf. Sci. 2006, 600, 5004-5010
28. Siokou, A.; Nix, R. M. Interaction of Methanol with Well-Defined Ceria Surfaces: Reflection/Absorption Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Temperature-Programmed Desorption Study J. Phys. Chem. B 1999, 103, 6984-6997
29. Matolín, V.; Libra, J.; Matolínová, I.; Nehasil, V.; Sedláček, L.; Šutara, F. Growth of Ultra-Thin Cerium Oxide Layers on Cu(111) Appl. Surf. Sci. 2007, 254, 153-155
30. 2(111) Ultra-Thin Films on Cu(111) Thin Solid Films 2008, 516, 6120-6124
31. 2: A Model Study J. Catal. 2010, 275, 181-185
32. 2(111) Thin Films on Cu(111) J. Phys. Chem. C 2011, 115, 7496-7503
33. Rodriguez, J. A.; Graciani, J.; Evans, J.; Park, J. B.; Yang, F.; Stacchiola, D.; Senanayake, S. D.; Ma, S.; Pérez, M.; Liu, P. Water-Gas Shift Reaction on a Highly Active Inverse CeOx/Cu(111) Catalyst: Unique Role of Ceria Nanoparticles Angew. Chem., Int. Ed. 2009, 48, 8047-8050
34. Vári, G.; Óvári, L.; Kiss, J.; Kónya, Z. LEIS and XPS Investigation into the Growth of Cerium and Cerium Dioxide on Cu(111) Phys. Chem. Chem. Phys. 2015, 17, 5124-5132
35. Alexandrou, M.; Nix, R. M. The Growth, Structure and Stability of Ceria Overlayers on Pd(111) Surf. Sci. 1994, 321, 47-57
36. Weast, R. C.; Astle, M. J., Eds. CRC Handbook of Chemistry and Physics, 60th ed.; CRC Press: Boca Raton, FL, 1979.
37. 2/YSZ(100) Model Catalysts J. Catal. 2012, 291, 79-86
38. Zhou, J.; Baddorf, A. P.; Mullins, D. R.; Overbury, S. H. Growth and Characterization of Rh and Pd Nanoparticles on Oxidized and Reduced CeOx(111) Thin Films by Scanning Tunneling Microscopy J. Phys. Chem. C 2008, 112, 9336-9345
39. Lu, J. L.; Gao, H. J.; Shaikhutdinov, S.; Freund, H. J. Gold Supported on Well-Ordered Ceria Films: Nucleation, Growth and Morphology in CO Oxidation Reaction Catal. Lett. 2007, 114, 8-16
40. Hyman, M. P.; Martono, E.; Vohs, J. M. Studies of the Structure and Interfacial Chemistry of Co Layers on ZnO(0001) J. Phys. Chem. C 2010, 114, 16892-16899
41. Dumont, J.; Mugumaoderha, C. M.; Seldrum, T.; Frising, F.; Moisson, C.; Turover, D.; Sporken, R. Formation of (Zn,Co)O by Annealing of Co Overlayers on ZnO J. Vac. Sci. Technol., B: Microelectron. Nanometer Struct. 2007, 25, 1536
42. Napetschnig, E.; Schmid, M.; Varga, P. Pd, Co and Co-Pd Clusters on the Ordered Alumina Film on NiAl(1 1 0): Contact Angle, Surface Structure and Composition Surf. Sci. 2007, 601, 3233-3245
43. 2-Supported Cobalt and Cobalt Oxide Langmuir 1994, 10, 178-187
44. Brongersma, H. H.; Draxler, M.; de Ridder, M.; Bauer, P. Surface Composition Analysis by Low-Energy Ion Scattering Surf. Sci. Rep. 2007, 62, 63-109
45. Shirley, D. A. High-Resolution X-ray Photoemission Spectrum of the Valence Bands of Gold Phys. Rev. B 1972, 5, 4709-4714
46. Napetschnig, E.; Schmid, M.; Varga, P. Growth of Ce on Rh(111) Surf. Sci. 2004, 556, 1-10
47. Staudt, T.; Lykhach, Y.; Hammer, L.; Schneider, M. A.; Matolín, V.; Libuda, J. A Route to Continuous Ultra-Thin Cerium Oxide Films on Cu(111) Surf. Sci. 2009, 603, 3382-3388
48. 2(110) Surf. Sci. 1999, 441, 10-20
49. 2(110): Evidence for Encapsulation Surf. Sci. 1995, 339, 83-95
50. Kürnsteiner, P.; Steinberger, R.; Primetzhofer, D.; Goebl, D.; Wagner, T.; Druckmüllerova, Z.; Zeppenfeld, P.; Bauer, P. Matrix Effects in the Neutralization of He Ions at a Metal Surface Containing Oxygen Surf. Sci. 2013, 609, 167-171
51. Fujimori, A. Correlation Effects in the Electronic Structure and Photoemission Spectra of Mixed-Valence Cerium Compounds Phys. Rev. B 1983, 28, 4489-4499
52. 2 Surfaces: An XPS, UPS and HREELS Study Surf. Sci. 1994, 321, 71-80
53. Nelin, C. J.; Bagus, P. S.; Ilton, E. S.; Chambers, S. A.; Kuhlenbeck, H.; Freund, H.-J. Relationships between Complex Core Level Spectra and Materials Properties Int. J. Quantum Chem. 2010, 110, 2752-2764
54. 2(111) Surfaces Surf. Sci. Spectra 2004, 11, 73
55. Skála, T.; Šutara, F.; Prince, K. C.; Matolín, V. Cerium Oxide Stoichiometry Alteration via Sn Deposition: Influence of Temperature J. Electron Spectrosc. Relat. Phenom. 2009, 169, 20-25
56. Wagner, C. D.; Riggs, W. M.; Davis, L. E.; Moulder, J. F. Handbook of X-Ray Photoelectron Spectroscopy; Muilenberg, G. E., Ed.; Perkin-Elmer Corporation: Eden Praire, MN, 1979.
57. Lin, S. S. Y.; Kim, D. H.; Engelhard, M. H.; Ha, S. Y. Water-Induced Formation of Cobalt Oxides over Supported Cobalt/Ceria-Zirconia Catalysts under Ethanol-Steam Conditions J. Catal. 2010, 273, 229-235
58. Chuang, T. J.; Brundle, C. R.; Rice, D. W. Interpretation of the X-ray Photoemission Spectra of Cobalt Oxides and Cobalt Oxide Surfaces Surf. Sci. 1976, 59, 413-429
59. Schenck, C. V.; Dillard, J. G.; Murray, J. W. Surface Analysis and the Adsorption of Co(II) on Goethite J. Colloid Interface Sci. 1983, 95, 398-409
60. Schmid, M.; Kaftan, A.; Steinrück, H.-P.; Gottfried, J. M. The Electronic Structure of Cobalt(II) Phthalocyanine Adsorbed on Ag(111) Surf. Sci. 2012, 606, 945-949
61. Perkins, C. L.; Henderson, M. A.; Peden, C. H. F.; Herman, G. S. Self-Diffusion in Ceria J. Vac. Sci. Technol., A 2001, 19, 1942
62. Jacobs, J.-P.; Reijne, S.; Elfrink, R. J. M.; Mikhailov, S. N.; Brongersma, H. H. Quantification of the Composition of Alloy and Oxide Surfaces Using Low-Energy Ion Scattering J. Vac. Sci. Technol., A 1994, 12, 2308-2313
63. 4 on CoO(100) J. Vac. Sci. Technol., A 1996, 14, 1637-1642
64. 2(1 1 0): XPS and LEIS Studies Appl. Surf. Sci. 2006, 252, 8624-8629
65. x Substrates with Different Stoichiometry and Defectivity J. Phys. Chem. C 2008, 112, 3187-3190