Intramolecular insertions into unactivated C(sp3)-H bonds by oxidatively generated β-diketone-α-gold carbenes: Synthesis of cyclopentanones

Journal of the American Chemical Society

Volumn 137, Issue 16, 2015, Pages 5316-5319

  Wang, Youliang ^a   Zheng, Zhitong ^a   Zhang, Liming ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROCARBONS; KETONES; REACTION INTERMEDIATES; SUBSTRATES;

CATALYZED OXIDATION; DESIGN FEATURES; DIAZO CARBONYL COMPOUNDS; DIKETONES; GOLD-CARBENES; METAL CARBENES; SYNTHETIC METHODS; THORPE-INGOLD EFFECT;

GOLD;

1,3 DIKETONE; 2 OCTENE; ACETOPHENONE; CARBENOID; CYCLOPENTANONE DERIVATIVE; GOLD DERIVATIVE; LIGAND; OXIDE; OXYGEN; PHENYL GROUP; CARBENE; CYCLOPENTANE DERIVATIVE; CYCLOPENTANONE; GOLD; KETONE; METHANE;

ARTICLE; CATALYST; CONFORMATION; COVALENT BOND; DECARBOXYLATION; ELECTROPHILICITY; ISOMER; MASS FRAGMENTOGRAPHY; NUCLEOPHILICITY; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SUBSTITUTION REACTION; SYNTHESIS; ANALOGS AND DERIVATIVES; CHEMISTRY; HYDROGEN BOND; OXIDATION REDUCTION REACTION;

CYCLOPENTANES; GOLD; HYDROGEN BONDING; KETONES; METHANE; OXIDATION-REDUCTION;

EID: 84928790469     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b02280     Document Type: Article

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