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Volumn 137, Issue 13, 2015, Pages 4280-4283

Phosphinite-Ni(0) Mediated Formation of a Phosphide-Ni(II)-OCOOMe Species via Uncommon Metal-Ligand Cooperation

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; LIGANDS;

EID: 84926431706     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja513112r     Document Type: Article
Times cited : (55)

References (51)
  • 5
    • 80053954556 scopus 로고    scopus 로고
    • Inorg. Chem. 2011, 50, 9737 - 9914.
    • (2011) Inorg. Chem. , vol.50 , pp. 9737-9914
  • 7
    • 84898000543 scopus 로고    scopus 로고
    • Poulos, T. L. Chem. Rev. 2014, 114, 3919 - 3962
    • (2014) Chem. Rev. , vol.114 , pp. 3919-3962
    • Poulos, T.L.1
  • 35
    • 84926448435 scopus 로고    scopus 로고
    • note
    • According to DFT analysis on (PPP)NiCl (1) and (PPP)NiOPh (4), significant nickel d-orbital character can be found in HOMOs, while dx2-y2 character was found in the LUMO, suggesting that both complexes possess a d8 Ni(II) center. In fact, the HOMO for 1 and HOMO-1 for 4 possess the significant contribution of a central phosphorus atom indicating the presence of a Ni(II)-bound electron-rich phosphide moiety in both species; see Supporting Information. In addition, the nickel's oxidation state and the electronic nature of the central phosphorus atom in 1-5 and 7 can be evaluated by comparing their 31P NMR and XRD data; see Table S7.
  • 51
    • 84926448434 scopus 로고    scopus 로고
    • note
    • Product DMC (∼10%) generated from the reaction was detected by 1H NMR spectroscopy in toluene with internal standard 1,1,2,2-tetrachloroethane by comparison with an authentic sample of DMC; see Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.