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Volumn 6, Issue 4, 2015, Pages 2286-2291

Exploiting parameter space in MOFs: A 20-fold enhancement of phosphate-ester hydrolysis with UiO-66-NH2

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; FUNCTIONAL GROUPS; HYDROGEN BONDS; JAVA PROGRAMMING LANGUAGE; PROBES;

EID: 84925004230     PISSN: 20416520     EISSN: 20416539     Source Type: Journal    
DOI: 10.1039/c4sc03613a     Document Type: Article
Times cited : (276)

References (71)
  • 8
    • 0000737686 scopus 로고
    • For phosphate-based nerve agents, specificiy may be ambiguous. Specificiy may refer to the bond that is being broken (e.g., Me, F, or iso-propyl group in Sarin). Alternatively, specificity may refer to the specific phosphate targeted (i.e., some enzymes are only efficient at hydrolyzing one specific nerve agent and not all nerve agents equilly). Lastly, given the stereogenic phosphorous centre, specificiy may refer to the specific enantiomer (e.g., Sarin), or pairs of enantiomers (e.g., Soman)
    • H. P. Benschop L. P. A. De Jong Acc. Chem. Res. 1988 21 368
    • (1988) Acc. Chem. Res. , vol.21 , pp. 368
    • Benschop, H.P.1    De Jong, L.P.A.2
  • 71
    • 54249103593 scopus 로고    scopus 로고
    • 2 after 1.8 min of catalysis (Fig. S5 in the ESI) demonstrates that the hydrolysis is heterogeneous. Furthermore, no leached zirconium is observed via ICP-AES analysis of the remaining solution Scanning-Electron Micrographs (SEMs) of UiO-66 and UiO-67 demonstrate that the particles sizes of these MOFs are similar
    • J. H. Cavka S. Jakobsen U. Olsbye N. Guillou C. Lamberti S. Bordiga K. P. Lillerud J. Am. Chem. Soc. 2008 130 13850
    • (2008) J. Am. Chem. Soc. , vol.130 , pp. 13850
    • Cavka, J.H.1    Jakobsen, S.2    Olsbye, U.3    Guillou, N.4    Lamberti, C.5    Bordiga, S.6    Lillerud, K.P.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.