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Volumn 45, Issue 11, 2006, Pages 1767-1770

Catalytic decomposition of simulants for chemical warfare V agents: Highly efficient catalysis of the methanolysis of phosphonothioate esters

Author keywords

Chemical warfare; Lanthanum; Methanolysis; Phosphorus zinc

Indexed keywords

CATALYTIC METHANOLYSIS; METHANOLYSIS; PHOSPHONOTHIOATE ESTERS; PHOSPHORUS ZINC;

EID: 33746299717     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200503182     Document Type: Article
Times cited : (49)

References (23)
  • 1
    • 33746289399 scopus 로고    scopus 로고
    • note
    • The content of the information discussed herein does not necessarily reflect the position or the policy of the federal government of the United States of America, and no official endorsement should be inferred.
  • 5
    • 33746307407 scopus 로고    scopus 로고
    • note
    • -1.
  • 9
    • 33746319216 scopus 로고    scopus 로고
    • note
    • - ion reacts with phosphoniothioates to give exclusive P-S cleavage, although these reactions are not catalytic and are carried out under alkaline conditions.
  • 18
    • 33746273031 scopus 로고    scopus 로고
    • note
    • 3+-catalyzed methanolysis of 5a must be essentially complete early in the NMR experiment because if it were not the summation of the 256 scans over five minutes would have revealed the presence of starting material in the first few scans.
  • 19
    • 33746285898 scopus 로고    scopus 로고
    • note
    • sPH 9.1.
  • 20
    • 33746306876 scopus 로고    scopus 로고
    • note
    • -1.
  • 21
    • 11844261429 scopus 로고    scopus 로고
    • The predicted rate constants assume that the Brønsted relationships of Equations (2) and (3), which are derived for aryl thiols, are followed by a primary alkyl thiol. Previous studies indicate that methanolysis and hydrolysis of carboxylate esters bearing aryloxy groups are up to tenfold less reactive than those bearing primary alkoxyl groups, presumably because of steric effects; see: a) N. E. Sunderland, A. A. Neverov, R. S. Brown, Org. Biomol. Chem. 2005, 3, 65;
    • (2005) Org. Biomol. Chem. , vol.3 , pp. 65
    • Sunderland, N.E.1    Neverov, A.A.2    Brown, R.S.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.