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Several control experiments established unequivocally that the stereoselectivity of the reactions in Fig. 1 is due to intramolecular conformational effects We define helical excess in a manner analogous to enantiomeric excess, but with regard to helix screw sense: he is the difference in population of P and M conformers as a percentage of the total. Suginome has exmployed the term 'screw sense excess' (se), generally quantified by CD, for the same quantity: see ref. 55 and 56
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This value was recalculated to higher precision using the data reported in ref. 34. This more precise value was the one used to extrapolate values for control of helical excess in ref. 31 Ref. 17 uses the term 'helix conductivity', which may be interpreted as the value 1 - f
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It may be noted that the model will also accommodate the case where the more energetically favourable arrangement is one with alternating helix sense, corresponding to an antiferromagnetic array, in which case L = -1/ln(1 - 2p)
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