Environmental TEM study of electron beam induced electrochemistry of Pr0.64Ca0.36MnO3 catalysts for oxygen evolution

Journal of Physical Chemistry C

Volumn 119, Issue 10, 2015, Pages 5301-5310

  Mildner, Stephanie ^a   Beleggia, Marco ^b,c   Mierwaldt, Daniel ^a   Hansen, Thomas W ^b   Wagner, Jakob B ^b   Yazdi, Sadegh ^b   Kasama, Takeshi ^b   Ciston, Jim ^d   Zhu, Yimei ^e   Jooss, Christian ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

^b TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^c HAHN MEITNER INSTITUT   (Germany)

^d LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^e BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANODIC OXIDATION; CALCIUM COMPOUNDS; ELECTRIC GROUNDING; ELECTRIC POTENTIAL; ELECTRIC VARIABLES MEASUREMENT; ELECTROCATALYSTS; ELECTRON BEAMS; ELECTRON HOLOGRAPHY; ELECTRONIC STATES; ELECTROSTATICS; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; MANGANESE COMPOUNDS; OXYGEN; PRASEODYMIUM COMPOUNDS; SECONDARY EMISSION; SILICA;

ELECTROCHEMICAL EXPERIMENTS; ELECTROCHEMICAL REACTIONS; ELECTROSTATIC MODELING; ELECTROSTATIC POTENTIALS; ENVIRONMENTAL TRANSMISSION ELECTRON MICROSCOPY; HIGH ENERGY ELECTRON BEAMS; OFF-AXIS ELECTRON HOLOGRAPHY; SECONDARY ELECTRON EMISSIONS;

ELECTRONS;

EID: 84924599218     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp511628c     Document Type: Article

References (42)

1. Lipkowski, J.; Ross, P. N. Frontiers in Electrochemistry. Electrocatalysis; Wiley-VCH: New York, 1998.
2. Hutchings, G. J.; Desmartin-Chomel, A.; Olier, R.; Volta, J.-C. Role of the Product in the Transformation of a Catalyst to its Active State Nature 1994, 368, 41-45
3. Trotochaud, L.; Boettcher, S. W. Precise Oxygen Evolution Catalysts: Status and Opportunities Scr. Mater. 2014, 74, 25-32
4. 2+ Science 2008, 321, 1072-1075
5. Arrigo, R.; Hävecker, M.; Schuster, M. E.; Ranjan, C.; Stotz, E.; Knop-Gericke, A.; Schlögl, R. In Situ Study of the Gas-Phase Electrolysis of Water on Platinum by NAP-XPS Angew. Chem., Int. Ed. 2013, 52, 11660-11664
6. 2) Environments Nano Lett. 2011, 11, 847-853
7. Gorlin, Y.; Lassalle-Kaiser, B.; Benck, J. D.; Gul, S.; Webb, S. M.; Yachandra, V. K.; Yano, J.; Jaramillo, T. F. In Situ X-ray Absorption Spectroscopy Investigation of a Bifunctional Manganese Oxide Catalyst with High Activity for Electrochemical Water Oxidation and Oxygen Reduction J. Am. Chem. Soc. 2013, 135, 8525-8534
8. Boyes, E. D.; Gai, P. L. Environmental High Resolution Electron Microscopy and Applications to Chemical Science Ultramicroscopy 1997, 67, 219-232
9. Hansen, T. W.; Wagner, J. B.; Hansen, P. L.; Dahl, S.; Topsøe, H.; Jacobsen, C. J. H. Atomic-Resolution in Situ Transmission Electron Microscopy of a Promoter of a Heterogeneous Catalyst Science 2001, 294, 1508-1510
10. Chang, L. Y.; Barnard, A. S.; Gontard, L. C.; Dunin-Borkowski, R. E. Resolving the Structure of Active Sites on Platinum Catalytic Nanoparticles Nano Lett. 2010, 10, 3073-3076
11. Hansen, P. L.; Wagner, J. B.; Helveg, S.; Rostrup-Nielsen, J. R.; Clausen, B. S.; Topsøe, H. Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals Science 2002, 295, 2053-2055
12. Helveg, S.; López-Cartes, C.; Sehested, J.; Hansen, P. L.; Clausen, V.; Rostrup-Nielsen, J. R.; Abild-Pedersen, F.; Nørskov, J. K. Atomic-Scale Imaging of Carbon Nanofibre Growth Nature 2004, 427, 426-429
13. Hansen, T. W.; Wagner, J. B.; Dunin-Borkowski, R. E. Aberration Corrected and Monochromated Environmental Transmission Electron Microscopy: Challenges and Prospects for Materials Science Mater. Sci. Technol. 2010, 26, 1338-1344
14. Egerton, R. F.; Li, P.; Malac, M. Radiation Damage in the TEM and SEM Micron 2004, 35, 399-409
15. Schattschneider, P.; Jouffrey, B. Plasmons and Related Excitations Springer Ser. Opt. Sci. 1995, 71, 151-224
16. Downing, K. H.; McCartney, M. R.; Glaeser, R. M. Experimental Characterization and Mitigation of Specimen Charging on Thin Films with One Conducting Layer Microsc. Microanal. 2004, 10, 783-789
17. Bockris, J. O. M.; Otagawa, T. The Electrocatalysis of Oxygen Evolution on Perovskites J. Electrochem. Soc. 1984, 131, 290-302
18. Suntivich, J.; May, K. J.; Gasteiger, H. A.; Goodenough, J. B.; Shao-Horn, Y. A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles Science 2011, 334, 1383-1385
19. Vojvodic, A.; Nørskov, J. K. Optimizing Perovskites for the Water-Splitting Reaction Science 2011, 334, 1355-1356
20. Yang, C.-K.; Yamazaki, Y.; Aydin, A.; Haile, S. M. Thermodynamic and Kinetic Assessments of Strontium-Doped Lanthanum Manganite Perovskites for Two-Step Thermochemical Water Splitting J. Mater. Chem. A 2014, 2, 13612-13623
21. 2O) as Biomimetic Oxygen-Evolving Catalysts Angew. Chem., Int. Ed. 2010, 49, 2233-2237
22. Zaharieva, I.; Najafpour, M. M.; Wiechen, M.; Haumann, M.; Kurz, P.; Dau, H. Synthetic Manganese-Calcium Oxides Mimic the Water-Oxidizing Complex of Photosynthesis Functionally and Structurally Energy Environ. Sci. 2011, 4, 2400-2408
23. Brimblecombe, R.; Koo, A.; Dismukes, G. C.; Swiegers, G. F.; Spiccia, L. Solar Driven Water Oxidation by a Bioinspired Manganese Molecular Catalyst J. Am. Chem. Soc. 2010, 132, 2892-2894
24. Matsumoto, Y.; Sato, E. Electrocatalytic Properties of Transition Metal Oxides for Oxygen Evolution Reaction Mater. Chem. Phys. 1986, 14, 397-426
25. Raabe, S.; Mierwaldt, D.; Ciston, J.; Uijttewaal, M.; Stein, H.; Hoffmann, J.; Zhu, Y.; Blöchl, P.; Jooss, C. In Situ Electrochemical Electron Microscopy Study of Oxygen Evolution Activity of Doped Manganite Perovskites Adv. Funct. Mater. 2012, 22, 3378-3388
26. Grenier, J. C.; Pouchard, M.; Wattiaux, A. Electrochemical Synthesis: Oxygen Intercalation Curr. Opin. Solid State Mater. Sci. 1996, 1, 233-240
27. Samet, L.; Imhoff, D.; Maurice, J.-L.; Contour, J.-P.; Gloter, A.; Manoubi, T.; Fert, A.; Colliex, C. EELS Study of Interfaces in Magnetoresistive LSMO/STO/LSMO Tunnel Junctions Eur. Phys. J. B 2003, 34, 179-192
28. Varela, M.; Oxley, M. P.; Luo, W.; Tao, J.; Watanabe, M.; Lupini, A. R.; Pantelides, S. T.; Pennycook, S. J. Atomic-Resolution Imaging of Oxidation States in Manganites Phys. Rev. B 2009, 79, 085117
29. Riedl, T.; Gemming, T.; Wetzig, K. Extraction of EELS White-Line Intensities of Manganese Compounds: Methods, Accuracy, and Valence Sensitivity Ultramicroscopy 2006, 106, 284-291
30. Mierwaldt, D.; Mildner, S.; Arrigo, R.; Knop-Gericke, A.; Franke, E.; Blumenstein, A.; Hoffmann, J.; Jooss, C. In Situ XANES/XPS Investigation of Doped Manganese Perovskite Catalysts Catalysts 2014, 4, 129-145
31. Toth, M.; Phillips, M. R.; Craven, J. P.; Thiel, B. L.; Donald, A. M. Electric Fields Produced by Electron Irradiation of Insulators in a Low Vacuum Environment J. Appl. Phys. 2002, 91, 4492-4499
32. Chung, M. S.; Everhart, T. E. Simple Calculation of Energy Distribution of Low-Energy Secondary Electrons Emitted from Metals under Electron Bombardment J. Appl. Phys. 1974, 45, 707-709
33. Cazaux, J. Material contrast in SEM: Fermi Energy and Work Function Effects Ultramicroscopy 2010, 110, 242-253
34. Henke, B. L.; Liesegang, J.; Smith, S. D. Soft-X-ray-Induced Secondary-Electron Emission From Semiconductors and Insulators: Models and Measurements Phys. Rev. B 1979, 19, 3004-3021
35. Kathrein, H.; Freund, F. Electrical Conductivity of Magnesium Oxide Single Crystal below 1200 K J. Phys. Chem. Solids 1983, 44, 177-186
36. http://dbshino.nifs.ac.jp.
37. 3 Using ELNES in the (S)TEM Micron 2007, 38, 224-230
38. 2.5+x Chem. Mater. 1996, 8, 2232-2238
39. Bakardjieva, S.; Bezdička, P.; Grygar, T.; Vorm, P. Reductive Dissolution of Microparticulate Manganese Oxides J. Solid State Electrochem. 2000, 4, 306-313
40. Kim, J.; Manthiram, A. A Manganese Oxyiodide Cathode for Rechargeable Lithium Batteries Nature 1997, 390, 265-267
41. Donald, A. M. The Use of Environmental Scanning Electron Microscopy for Imaging Wet and Insulating Materials Nat. Mater. 2003, 2, 511-516
42. Wight, S. A. Experimental Data and Model Simulations of Beam Spread in the Environmental Scanning Electron Microscope Scanning 2001, 23, 320-327