Coupling of sterically hindered trisubstituted olefins and benzocyclobutenones by C-C activation: Total synthesis and structural revision of cycloinumakiol

Angewandte Chemie - International Edition

Volumn 53, Issue 40, 2014, Pages 10733-10736

  Xu, Tao ^a   Dong, Guangbin ^a  

^a University of Texas at Austin   (United States)

Author keywords

C C activation; cycloinumakiol; Rh catalysis; structure elucidation; total synthesis

Indexed keywords

CATALYSIS; CHEMICAL INDUSTRY; OLEFINS; RHODIUM; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

C-C ACTIVATIONS; CYCLOINUMAKIOL; NATURAL COMPOUNDS; NATURAL PRODUCT SYNTHESIS; RHODIUM CATALYSIS; STRUCTURE ELUCIDATION; SYNTHETIC PRODUCTS; TOTAL SYNTHESIS;

CHEMICAL ACTIVATION;

11,10-OXYMETHYLENECYCLOPENT-14-ISOPROPYL-8,11,13-PODOCARPATRIENE; ALKENE; CYCLOBUTANE DERIVATIVE; CYCLOBUTENONE; DITERPENE; RHODIUM;

CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; PINACEAE; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKENES; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; CYCLOBUTANES; DITERPENES; MODELS, MOLECULAR; PINACEAE; RHODIUM;

EID: 84923642408     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201404802     Document Type: Article

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