First total synthesis and assignment of the stereochemistry of crispatenine

Journal of Organic Chemistry

Volumn 72, Issue 10, 2007, Pages 3770-3775

  Bourdron, Julien ^a   Commeiras, Laurent ^a   Audran, Gérard ^b   Vanthuyne, Nicolas ^c   Hubaud, J C ^c   Parrain, Jean Luc ^a  

^a CNRS   (France)

^b AIX MARSEILLE UNIVERSITY   (France)

^c DIPTA (SA)   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CRISPATENINE 1; RELATIVE CONFIGURATIONS;

ENANTIOSELECTIVITY; STEREOCHEMISTRY; STRUCTURE (COMPOSITION); SYNTHESIS (CHEMICAL);

HYDROCARBONS;

2 [(E) 2 METHOXY VINYL] 1,1 DIMETHYL 3 METHYLENE CYCLOHEXANE; 2 [(Z) 2 METHOXY VINYL] 1,1 DIMETHYL 3 METHYLENE CYCLOHEXANE; 2 [2 (TERT BUTYL DIMETHYL SILANYLOXY) ETHYLIDENE] 4 (2,2 DIMETHYL 6 METHYLENE CYCLOHEXYL) BUTANE 1,3 DIOL; 3 [(E) 2 METHOXY VINYL] 2,2 DIMETHYL 4 METHYLENE CYCLOHEXANOL; 3 [(Z) 2 METHOXY VINYL] 2,2 DIMETHYL 4 METHYLENE CYCLOHEXANOL; ACETIC ACID 2 ACETOXYMETHYL 1 (2,2 DIMETHYL 6 METHYLENE CYCLOHEXYLMETHYL) 4 HYDROXY BUT 2 ENYL ESTER; ACETIC ACID 2 ACETOXYMETHYL 1 (2,2 DIMETHYL 6 METHYLENE CYCLOHEXYLMETHYL) 4 OXO BUT 2 ENYL ESTER; ACETIC ACID 2 ACETOXYMETHYL 4 (TERT BUTYL DIMETHYL SILANYLOXY) 1 (2,2 DIMETHYL 6 METHYLENE CYCLOHEXYLMETHYL) BUT 2 ENYL ESTER; CRISPATENINE; CYCLOHEXANE DERIVATIVE; ESTER DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; STEREOCHEMISTRY; SYNTHESIS;

BIOLOGICAL PRODUCTS; BUTADIENES; CRYSTALLOGRAPHY, X-RAY; CYCLOHEXANES; MOLECULAR STRUCTURE; ORGANIC CHEMICALS; STEREOISOMERISM;

EID: 34248587433     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo070045j     Document Type: Article

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