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Volumn 54, Issue 7, 2015, Pages 2095-2099

Influence of ligand architecture on oxidation reactions by high-valent nonheme manganese oxo complexes using water as a source of oxygen

Author keywords

Density functional calculations; Isomers; Manganese; Oxidation; Structure elucidation

Indexed keywords

ATOMS; ISOMERS; LIGANDS; MANGANESE; OXIDATION; SYNTHESIS (CHEMICAL);

EID: 84922324580     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201409476     Document Type: Article
Times cited : (51)

References (62)
  • 1
    • 33747589451 scopus 로고    scopus 로고
    • (Eds.: R. van Eldik, J. Reedijk), Elsevier, San Diego
    • a) S. Tanase, E. Bouwman, Advances in Inorganic Chemistry, Vol. 58 (Eds.: R. van Eldik, J. Reedijk), Elsevier, San Diego, 2006, pp. 29 - 75;
    • (2006) Advances in Inorganic Chemistry , vol.58 , pp. 29-75
    • Tanase, S.1    Bouwman, E.2
  • 26
    • 84896308123 scopus 로고    scopus 로고
    • (Eds.: L. H. Gade, P. Hofmann), Wiley-VCH,Weinheim
    • b) P. Comba in Molecular Catalysis (Eds.: L. H. Gade, P. Hofmann), Wiley-VCH,Weinheim, 2014, pp. 123-145.
    • (2014) Molecular Catalysis , pp. 123-145
    • Comba, P.1
  • 60
    • 84922300043 scopus 로고    scopus 로고
    • We have not completed a computational analysis for the sulfoxidation reaction. From published work on the iron-based systems it emerges, however, that depending on the isomer (oxo group trans to either N3 or N7), the lowest energy transition state (S = 2) has either linear or bent structures,[16b] thus suggesting that in the iron system, there might be changes in structure and concomitantly in reactivity resulting from subtle changes in the steric demand of the substrate
    • We have not completed a computational analysis for the sulfoxidation reaction. From published work on the iron-based systems it emerges, however, that depending on the isomer (oxo group trans to either N3 or N7), the lowest energy transition state (S = 2) has either linear or bent structures,[16b] thus suggesting that in the iron system, there might be changes in structure and concomitantly in reactivity resulting from subtle changes in the steric demand of the substrate.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.