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Volumn 54, Issue 4, 2015, Pages 1266-1269

Cationic gold(III) alkyl complexes: Generation, trapping, and insertion of norbornene

Author keywords

Gold; Insertion reactions; Lewis acids; Olefins; Organometallic chemistry

Indexed keywords

CHLORINE COMPOUNDS; GOLD; OLEFINS; ORGANOMETALLICS;

EID: 84921038436     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201409604     Document Type: Article
Times cited : (67)

References (63)
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    • Bis(silyl)gold(III) complexes were isolated as stable crystalline compounds upon coordination of two phosphines, whereas related monophosphine species could only be spectroscopically characterized at low temperature; see references [11a,d]
    • Bis(silyl)gold(III) complexes were isolated as stable crystalline compounds upon coordination of two phosphines, whereas related monophosphine species could only be spectroscopically characterized at low temperature; see references [11a,d].
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    • 13C NMR signals for the methyl groups of lutidine overlap with those of the norbornyl skeleton, in-depth characterization was carried out on the pyridine complex 7
    • 13C NMR signals for the methyl groups of lutidine overlap with those of the norbornyl skeleton, in-depth characterization was carried out on the pyridine complex 7.
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    • A Cambridge database search revealed only two norbornyl gold(III) complexes previously characterized by XRD; see references [3, 7]
    • A Cambridge database search revealed only two norbornyl gold(III) complexes previously characterized by XRD; see references [3, 7].
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    • We recently reported the syn insertion of alkynes into Au-Si bonds of gold(I) silyl complexes; see references [11c,f]
    • We recently reported the syn insertion of alkynes into Au-Si bonds of gold(I) silyl complexes; see references [11c,f].
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    • CCDC 1025240 (4b) and CCDC 1025241 (8) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from via
    • CCDC 1025240 (4b) and CCDC 1025241 (8) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.