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27544492000
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2O; this diol converts almost completely into methylbenzylketone after a prolonged reaction time.
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26
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27544496416
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27544440771
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note
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For full experimental data on the synthesis, spectroscopy, and elemental analysis of complexes 2a-2c, 3a-3d, 4a-4c and for spectroscopic characterization of organic compounds 6-11 see Supporting Information.
-
-
-
-
50
-
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27544457988
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-
note
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3.
-
-
-
-
51
-
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27544443082
-
-
max = 26°. Structure solved by direct methods and refined by full-matrix least squares. The program used to refine the structure was Personal SDP. CCDC-272640 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_ request/cif.
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52
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56
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27544501561
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note
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[15]
-
-
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57
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27544463600
-
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note
-
2O.3) Under the same nb/1a ratio and time conditions higher 4a yields are obtained from concentrated solutions; the overall yield (3a + 4a) was slightly lower than that from dilute solutions.
-
-
-
-
58
-
-
27544441888
-
-
note
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3CN) as they overlapped with those of 1c, 3c, and 4c.
-
-
-
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59
-
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27544490938
-
-
note
-
3): 7: 9.64 (d, 2.0 Hz; 2H); 8 or 9: 9.63 (d, 2.4 Hz; 1 H); 9 or 8: 9.62 ppm (d, 2.4 Hz; 1 H). Intensities: 7 ≥ (8 + 9); 7 ≤ 6 (molar ratio based on CHH-7 of the epoxide at δ = 0.70 ppm).
-
-
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60
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0343294003
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1H NMR and GC-MS spectra were compared to those of an authentic sample prepared according to: S. Göksu, R. Altundas, Y. Sütbeyaz, Synth. Commun. 2000, 30, 1615-1621.
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Göksu, S.1
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62
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27544485580
-
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note
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2O to 4a; in this case small amounts of diols 10 and 11 are formed.
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