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Volumn 44, Issue 42, 2005, Pages 6892-6895

Reactions of gold(III) oxo complexes with cyclic alkenes

Author keywords

Alkene ligands; Gold; Oxidation; Oxo ligands

Indexed keywords

GOLD; OLEFINS; OXIDATION;

EID: 27544460203     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200501754     Document Type: Article
Times cited : (110)

References (63)
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    • For full experimental data on the synthesis, spectroscopy, and elemental analysis of complexes 2a-2c, 3a-3d, 4a-4c and for spectroscopic characterization of organic compounds 6-11 see Supporting Information.
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    • max = 26°. Structure solved by direct methods and refined by full-matrix least squares. The program used to refine the structure was Personal SDP. CCDC-272640 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_ request/cif.
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    • [15]
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    • 2O.3) Under the same nb/1a ratio and time conditions higher 4a yields are obtained from concentrated solutions; the overall yield (3a + 4a) was slightly lower than that from dilute solutions.
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    • 3CN) as they overlapped with those of 1c, 3c, and 4c.
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    • 3): 7: 9.64 (d, 2.0 Hz; 2H); 8 or 9: 9.63 (d, 2.4 Hz; 1 H); 9 or 8: 9.62 ppm (d, 2.4 Hz; 1 H). Intensities: 7 ≥ (8 + 9); 7 ≤ 6 (molar ratio based on CHH-7 of the epoxide at δ = 0.70 ppm).
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    • note
    • 2O to 4a; in this case small amounts of diols 10 and 11 are formed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.