Activation of white phosphorus by low-valent group 5 complexes: Formation and reactivity of cyclo-P4 inverted sandwich compounds

Journal of the American Chemical Society

Volumn 136, Issue 50, 2014, Pages 17652-17661

  Camp, Clément ^a   Maron, Laurent ^b   Bergman, Robert G ^a   Arnold, John ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITÉ DE TOULOUSE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; PHOSPHORUS; SYNTHESIS (CHEMICAL); ULTRAVIOLET VISIBLE SPECTROSCOPY;

DFT CALCULATION; DIKETIMINATES; LOW-VALENT; MONOCATIONS; SANDWICH COMPLEXES; SIDE PRODUCTS; UV VISIBLE SPECTROSCOPY; WHITE PHOSPHORUS;

NIOBIUM COMPOUNDS;

5 CYCLO TETRAPHOSPHIDE; METAL COMPLEX; NIOBIUM; PHOSPHORUS; TANTALUM; TANTALUM BETA DIKETIMINATE TERT BUTYLIMIDO COMPLEX; UNCLASSIFIED DRUG; COORDINATION COMPOUND;

ARTICLE; DENSITY FUNCTIONAL THEORY; ELECTRON SPIN RESONANCE; HYDROGENATION; HYDROGENOLYSIS; NUCLEOPHILICITY; OXIDATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY; CHEMICAL STRUCTURE; CHEMISTRY; COMPUTER SIMULATION; CYCLIZATION; OXIDATION REDUCTION REACTION;

COMPUTER SIMULATION; COORDINATION COMPLEXES; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PHOSPHORUS;

EID: 84919360332     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja5107282     Document Type: Article

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