Formation of cyclo-E42- units (E4=P 4, As4, AsP3) by a Complex with a Cr-Cr Quintuple Bond

Angewandte Chemie - International Edition

Volumn 50, Issue 32, 2011, Pages 7283-7286

  Schwarzmaier, Christoph ^a   Noor, Awal ^b   Glatz, Germund ^b   Zabel, Manfred ^a   Timoshkin, Alexey Y ^c   Cossairt, Brandi M ^d   Cummins, Christopher C ^d   Kempe, Rhett ^b   Scheer, Manfred ^a  

^a UNIVERSITY OF REGENSBURG   (Germany)

^b UNIVERSITY OF BAYREUTH   (Germany)

^c ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

^d MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

arsenic; chromium; phosphorus; quintuple bonds

Indexed keywords

DFT CALCULATION; ONE STEP; QUINTUPLE BONDS; STABLE FORM; WHITE PHOSPHORUS;

ARSENIC; CHROMIUM; PHOSPHORUS;

CHROMIUM COMPOUNDS;

EID: 79960896493     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201102361     Document Type: Article

References (76)

1. M. Morse, Chem. Rev. 1986, 86, 1049-1109.
2. E. P. Kündig, M. Moskovits, G. A. Ozin, Nature 1975, 254, 503-504
3. W. Klotzbücher, G. A. Ozin, Inorg. Chem. 1977, 16, 984-987.
4. Yu. M. Efremov, A. N. Samoilova, L. V. Gurvich, Opt. Spektrosk. 1974, 36, 654-657.
5. V. E. Bondybey, J. H. English, Chem. Phys. Lett. 1983, 94, 443-447.
6. T. Nguyen, A. D. Sutton, M. Brynda, J. C. Fettinger, G. J. Long, P. P. Power, Science 2005, 310, 844-847
7. R. Wolf, C. Ni, T. Nguyen, M. Brynda, G. J. Long, A. D. Sutton, R. C. Fischer, J. C. Fettinger, M. Hellman, L. Pu, P. P. Power, Inorg. Chem. 2007, 46, 11277-11290
8. E. Rivard, P. P. Power, Inorg. Chem. 2007, 46, 10047-10064.
9. K. A. Kreisel, G. P. A. Yap, O. Dmitrenko, C. R. Landis, K. H. Theopold, J. Am. Chem. Soc. 2007, 129, 14162-14163.
10. Y.-C. Tsai, C.-W. Hsu, J.-S. K. Yu, G.-H. Lee, Y. Wang, T.-S. Kuo, Angew. Chem. 2008, 120, 7360-7363
11. Angew. Chem. Int. Ed. 2008, 47, 7250-7253
12. C.-W. Hsu, J.-S. K. Yu, C.-H. Yen, G.-H. Lee, Y. Wang, Y.-C. Tsai, Angew. Chem. 2008, 120, 10081-10084
13. Angew. Chem. Int. Ed. 2008, 47, 9933-9936
14. Y.-C. Tsai, H.-Z. Chen, C.-C. Chang, J.-S. K. Yu, G.-H. Lee, Y. Wang, T.-S. Kuo, J. Am. Chem. Soc. 2009, 131, 12534-12535.
15. A. Noor, F. R. Wagner, R. Kempe, Angew. Chem. 2008, 120, 7356-7359
16. Angew. Chem. Int. Ed. 2008, 47, 7246-7249
17. A. Noor, G. Glatz, R. Müller, M. Kaupp, S. Demeshko, R. Kempe, Z. Anorg. Allg. Chem. 2009, 635, 1149-1152.
18. L. Gagliardi, B. O. Roos, Nature 2005, 433, 848-851
19. G. Frenking, R. Tonner, Nature 2007, 446, 276-277
20. G. Merino, K. J. Donald, J. S. D'Acchioli, R. Hoffmann, J. Am. Chem. Soc. 2007, 129, 15295-15302
21. U. Radius, F. Breher, Angew. Chem. 2006, 118, 3072-3077
22. Angew. Chem. Int. Ed. 2006, 45, 3006-3010
23. G. Frenking, Science 2005, 310, 796-397
24. M. Brynda, L. Gagliardi, P. O. Widmark, P. P. Power, B. O. Roos, Angew. Chem. 2006, 118, 3888-3891
25. Angew. Chem. Int. Ed. 2006, 45, 3804-3807
26. G. La Macchia, M. Brynda, L. Gagliardi, Angew. Chem. 2006, 118, 6356-6359
27. Angew. Chem. Int. Ed. 2006, 45, 6210-6213
28. J. Huang, Q. Li, H. Ren, H. Su, J. Yang, J. Chem. Phys. 2006, 125, 184713
29. B. O. Roos, P. A. Malmqvist, L. Gagliardi, J. Am. Chem. Soc. 2006, 128, 17000-17006
30. F. Weinhold, C. R. Landis, Science 2007, 316, 61-63
31. G. La Macchia, L. Gagliardi, P. P. Power, M. Brynda, J. Am. Chem. Soc. 2008, 130, 5104-5114
32. G. La Macchia, F. Aquilante, V. Veryazov, B. O. Ross, L. Gagliardi, Inorg. Chem. 2008, 47, 11455-11457
33. B. Xu, Q.-S. Li. Y. Xie, H. F. Shaefer III, J. Chem. Theory Comput. 2010, 6, 735-746
34. M. Brynda, L. Gagliardi, B. O. Roos, Chem. Phys. Lett. 2009, 471, 1-10
35. R. Ponec, F. Feixas, J. Chem. Phys. A 2009, 113, 8394-8400
36. D. B. Donald, J. Phys. Chem. A 2009, 113, 1559-1563
37. G. La Macchia, G. Li Manni, T. K. Todorova, F. Aquilante, B. O. Roos, L. Gagliardi, Inorg. Chem. 2010, 49, 5216-5222.
38. F. Wagner, A. Noor, R. Kempe, Nat. Chem. 2009, 1, 529-536.
39. A. Noor, G. Glatz, R. Müller, M. Kaupp, S. Demeshko, R. Kempe, Nat. Chem. 2009, 1, 322-325
40. C. Ni, B. D. Ellis, G. J. Long, P. P. Power, Chem. Commun. 2009, 2332-2334
41. A. Noor, E. S. Tamne, S. Qayyum, T. Bauer, R. Kempe, Chem. Eur. J. 2011, 17, 6900-6903.
42. M. Scheer, G. Balàzs, A. Seitz, Chem. Rev. 2010, 110, 4236-4256.
43. B. M. Crossairt, N. A. Piro, C. C. Cummins, Chem. Rev. 2010, 110, 4161-4177
44. M. Caporali, L. Gonsalvi, A. Rossin, M. Peruzzini, Chem. Rev. 2010, 110, 4178-4235
45. M. Peruzzini, L. Gonsalvi, A. Romerosa, Chem. Soc. Rev. 2005, 34, 1038-1047.
46. M. Peruzzini, M. Marvelli, A. Romerosa, R. Rossi, F. Vizza, F. Zanobini, Eur. J. Inorg. Chem. 1999, 931-933
47. M. Di Vaira, P. Frediani, S. Seniori Costantini, M. Peruzzini, P. Stoppioni, Acta Crystallogr. Sect. A 2005, 61, c 298
48. P. Barbaro, M. Di Vaira, M. Peruzzini, S. Seniori Costantini, P. Stoppioni, Chem. Eur. J. 2007, 13, 6682-6690
49. M. Caporali, M. Di Vaira, M. Peruzzini, S. Seniori Costantini, P. Stoppioni, F. Zanobini, Eur. J. Inorg. Chem. 2010, 152-158
50. D. Yakhvarov, P. Barbaro, L. Gonsalvi, S. M. Carpio, S. Midollini, A. Orlandini, M. Peruzzini, O. Sinyashin, F. Zanobini, Angew. Chem. 2006, 118, 4288-4291
51. Angew. Chem. Int. Ed. 2006, 45, 4182-4185.
52. O. J. Scherer, G. Schwarz, G. Wolmershäuser, Z. Anorg. Allg. Chem. 1996, 622, 951-957
53. O. J. Scherer, T. Hilt, G. Wolmershäuser, Organometallics 1998, 17, 4110-4112.
54. W. W. Seidel, O. T. Summerscales, B. U. Patrick, M. D. Fryzuk, Angew. Chem. 2009, 121, 121-123
55. Angew. Chem. Int. Ed. 2009, 48, 115-117.
56. F. Kraus, J. C. Aschenbrenner, N. Korber, Angew. Chem. 2003, 115, 4162-4165
57. Angew. Chem. Int. Ed. 2003, 42, 4030-4033
58. F. Kraus, N. Korber, Chem. Eur. J. 2005, 11, 5945-5959.
59. N. Korber, M. Reil, Chem. Commun. 2002, 84-85
60. F. Kraus, T. Hanauer, N. Korber, Inorg. Chem. 2006, 45, 1117-1123.
61. O. J. Scherer, J. Vondung, G. Wolmershäuser, Angew. Chem. 1989, 101, 1395-1397
62. Angew. Chem. Int. Ed. Engl. 1989, 28, 1355-1357
63. O. J. Scherer, J. Vondung, G. Wolmershäuser, J. Organomet. Chem. 1989, 376, C 35 -C 38
64. O. J. Scherer, R. Winter, G. Wolmershäuser, Z. Anorg. Allg. Chem. 1993, 619, 827-835.
65. B. M. Cossairt, C. C. Cummins, J. Am. Chem. Soc. 2009, 131, 15501-15511
66. B. M. Cossairt, C. C. Cummins, Chem. Eur. J. 2010, 16, 12603-12608.
67. L. R. Maxwell, S. B. Hendrichs, V. M. Mosley, J. Chem. Phys. 1995, 103, 699; see also reference [12].
68. Y. Morino, T. Ukaji, T. Ito, Bull. Chem. Soc. Jpn. 1966, 39, 64-71
69. H. A. Spinney, N. A. Piro, C. C. Cummins, J. Am. Chem. Soc. 2009, 131, 16233-16243.
70. See the Supporting Information for details for the X-ray structure analyses and the DFT calculations. CCDC-816510 (2 a), CCDC-816511 (2 b), CCDC-816512 (2 c), and CCDC-816513 (3 a) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
71. 5thf]:, M. Scheer, J. Müller, M. Häser, Angew. Chem. 1996, 108, 2637-2641
72. Angew. Chem. Int. Ed. Engl. 1996, 35, 2492-2496.
73. A. D. Becke, J. Chem. Phys. 1993, 98, 5648
74. C. Lee, W. Yang, R. G. Parr, Phys. Rev. B 1988, 37, 785.
75. F. Weigend, R. Ahlrichs, Phys. Chem. Chem. Phys. 2005, 7, 3297
76. D. Andrae, U. Haeussermann, M. Dolg, H. Stoll, H. Preuss, Theor. Chim. Acta 1990, 77, 123.