Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of β-diketiminato ligands involving nitrene transfer

Journal of the American Chemical Society

Volumn 136, Issue 8, 2014, Pages 2994-2997

  Obenhuber, Andreas H ^a   Gianetti, Thomas L ^a   Berrebi, Xavier ^a   Bergman, Robert G ^a   Arnold, John ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIETHYL ETHERS; MECHANISTIC STUDIES; METAL CENTERS; NIOBIUM COMPLEXES; NIOBIUM SPECIES; NITRENES; ORGANIC AZIDES; TRIMETHYLSILYL;

NIOBIUM COMPOUNDS; REACTION INTERMEDIATES;

LIGANDS;

(BISIMIDO)NIOBIUM(V) COMPLEX; AZIDE; LIGAND; METAL COMPLEX; NIOBIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CRYSTAL STRUCTURE; CRYSTALLIZATION; CYCLOADDITION; PROTON NUCLEAR MAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

EID: 84896884958     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja413194z     Document Type: Article

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