Stabilization of the triphosphallyl ligand η3-P 3{P(O)H} at iridium via alkaline activation of P4

Chemistry - An Asian Journal

Volumn 8, Issue 12, 2013, Pages 3177-3184

  Mirabello, Vincenzo ^a,b   Caporali, Maria ^a   Gonsalvi, Luca ^a   Manca, Gabriele ^a   Ienco, Andrea ^a   Peruzzini, Maurizio ^a  

^a CNR   (Italy)

^b University of Bath   (United Kingdom)

Author keywords

1,2 bis(diphenylphosphino)methane; fluxional behavior; iridium; P ligands; phosphorus; triphosphallyl ligand

Indexed keywords

1D AND 2D NMR SPECTROSCOPIES; ALKALINE ACTIVATION; CHEMICAL EXCHANGE; FLUXIONAL BEHAVIOR; P LIGANDS; SELECTIVE FUNCTIONALIZATION; SINGLE CRYSTAL X-RAY STRUCTURES; VARIABLE TEMPERATURE;

ALKALINITY; CHEMICAL BONDS; CRYSTAL STRUCTURE; IRIDIUM; METHANE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHORUS;

LIGANDS;

HYDROXIDE; HYDROXIDE ION; IRIDIUM; LIGAND; ORGANOMETALLIC COMPOUND; ORGANOPHOSPHATE; PHOSPHORUS;

1,2-BIS(DIPHENYLPHOSPHINO)METHANE; ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; FLUXIONAL BEHAVIOR; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; P LIGANDS; PH; QUANTUM THEORY; TRIPHOSPHALLYL LIGAND; X RAY CRYSTALLOGRAPHY;

1,2-BIS(DIPHENYLPHOSPHINO)METHANE; FLUXIONAL BEHAVIOR; IRIDIUM; P LIGANDS; PHOSPHORUS; TRIPHOSPHALLYL LIGAND;

CRYSTALLOGRAPHY, X-RAY; HYDROGEN-ION CONCENTRATION; HYDROXIDES; IRIDIUM; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; ORGANOPHOSPHATES; PHOSPHORUS; QUANTUM THEORY;

EID: 84888366760     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.201300885     Document Type: Article

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