Reactivity studies of a masked three-coordinate vanadium(II) complex

Angewandte Chemie - International Edition

Volumn 49, Issue 51, 2010, Pages 9871-9875

  Tran, Ba L ^a   Singhal, Madhavi ^a   Park, Hyunsoo ^a   Lam, Oanh P ^b   Pink, Maren ^a   Krzystek, J ^c   Ozarowski, Andrew ^c   Telser, Joshua ^d   Meyer, Karsten ^b   Mindiola, Daniel J ^a  

^a INDIANA UNIVERSITY   (United States)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^c FLORIDA STATE UNIVERSITY   (United States)

^d ROOSEVELT UNIVERSITY   (United States)

Author keywords

EPR spectroscopy; nitrides; phosphorus; reduction; vanadium

Indexed keywords

ARENE INTERACTIONS; CYCLOPROPENES; EPR SPECTROSCOPY; FACILE ACCESS; LOW-VALENT; SMALL MOLECULES; TERMINAL LIGANDS;

ELECTRON SPIN RESONANCE SPECTROSCOPY; LIGANDS; NITRIDES; PARAMAGNETIC RESONANCE; PHOSPHORUS; PROPYLENE; VANADIUM; VANADIUM ALLOYS;

VANADIUM COMPOUNDS;

EID: 78650259893     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201005029     Document Type: Article

References (68)

1. S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini, J. Am. Chem. Soc. 1982, 104, 1918
2. G. Fachinetti, S. D. Nero, C. Floriani, J. Chem. Soc. Dalton Trans. 1976, 1046
3. R. M. Kowaleski, F. Basolo, W. C. Trogler, R. D. Ernst, J. Am. Chem. Soc. 1986, 108, 6046
4. M. Pasquali, S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini, Inorg. Chem. 1981, 20, 165
5. J. L. Petersen, L. Griffith, Inorg. Chem. 1980, 19, 1852
6. R. Prins, P. Biloen, J. D. W. vana Voorst, J. Chem. Phys. 1967, 46, 1216
7. R. M. Kowaleski, A. L. Rheingold, W. C. Trogler, F. Basolo, J. Am. Chem. Soc. 1986, 108, 2460.
8. S. Gambarotta, C. Floriani, A. Chiesi-Villa, C. Guastini, Inorg. Chem. 1984, 23, 1739
9. R. M. Kowaleski, F. Basolo, J. H. Osborne, W. C. Trogler, Organometallics 1988, 7, 1425.
10. J. J. H. Edema, W. Stauthamer, F. Vana Bolhuis, S. Gambarotta, W. J. J. Smeets, A. L. Spek, Inorg. Chem. 1990, 29, 1302
11. G. S. Girolami, G. Wilkinson, A. M. R. Galas, M. Thornton-Pett, M. B. Hursthouse, Dalton Trans. 1985, 1339.
12. B. Hessen, J. H. Teuben, T. H. Lemmen, J. C. Huffman, K. G. Caulton, Organometallics 1985, 4, 946
13. B. Hessen, T. H. Lemmen, H. J. G. Luttikhedde, J. H. Teuben, J. L. Petersen, J. C. Huffman, S. Jagner, K. G. Caulton, Organometallics 1987, 6, 2354
14. A. Shinohara, J. McBee, R. Waterman, T. D. Tilley, Organometallics 2008, 27, 5717.
15. M. A. Lockwood, P. E. Fanwick, I. P. Rothwell, Polyhedron 1995, 14, 3363
16. M. A. Lockwood, P. E. Fanwick, O. Eisenstein, I. P. Rothwell, J. Am. Chem. Soc. 1996, 118, 2762
17. M. A. Lockwood, P. E. Fanwick, I. P. Rothwell, Chem. Commun. 1996, 2013
18. M. R. Lentz, J. S. Vilardo, M. A. Lockwood, P. E. Fanwick, I. P. Rothwell, Organometallics 2004, 23, 329.
19. P. L. Diaconescu, C. C. Cummins, J. Am. Chem. Soc. 2002, 124, 7660
20. X. Dai, P. Kapoor, T. H. Warren, J. Am. Chem. Soc. 2004, 126, 4798
21. W. J. Evans, S. A. Kozimor, J. W. Ziller, N. Kaltsoyannis, J. Am. Chem. Soc. 2004, 126, 14533
22. G. Bai, P. Wie, D. W. Stephan, Organometallics 2005, 24, 5901
23. Y. M. Badiei, A. Krishnaswamy, M. M. Melzer, T. H. Warren, J. Am. Chem. Soc. 2006, 128, 15056
24. Y.-C. Tsai, P.-Y. Wang, K.-M. Lin, S.-A. Chen, J.-M. Chen, Chem. Commun. 2008, 205
25. G. Bai, D. W. Stephan, Angew. Chem. 2007, 119, 1888
26. Angew. Chem. Int. Ed. 2007, 46, 1856
27. T. Watanabe, Y. Ishida, T. Matsuo, H. Kawaguchi, Dalton Trans. 2010, 484
28. Y.-C. Tsai, P.-Y. Wang, S.-A. Chen, J.-M. Chen, J. Am. Chem. Soc. 2007, 129, 8066
29. W. H. Monillas, G. P. A. Yap, K. H. Theopold, Angew. Chem. 2007, 119, 6812
30. Angew. Chem. Int. Ed. 2007, 46, 6692.
31. F. Basuli, U. J. Kilgore, D. Brown, J. C. Huffman, D. J. Mindiola, Organometallics 2004, 23, 6166
32. G. Bai, P. Wei, D. W. Stephan, Organometallics 2006, 25, 2649
33. H. Hamaki, N. Takeda, N. Tokitoh, Organometallics 2006, 25, 2457
34. F. Basuli, J. C. Huffman, D. J. Mindiola, Inorg. Chim. Acta 2007, 360, 246.
35. B. L. Tran, M. Pink, X. Gao, H. Park, D. J. Mindiola, J. Am. Chem. Soc. 2010, 132, 1458.
36. F. Basuli, U. J. Kilgore, X. Hu, K. Meyer, M. Pink, J. C. Huffman, D. J. Mindiola, Angew. Chem. 2004, 116, 3218
37. Angew. Chem. Int. Ed. 2004, 43, 3156.
38. See the Supporting Information. CCDCa 787159-787162 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via.)
39. P. W. Wanandi, W. M. Davis, C. C. Cummins, J. Am. Chem. Soc. 1995, 117, 2110
40. K. B. P. Ruppa, N. Desmangles, S. Gambarotta, G. Yap, A. L. Rheingold, Inorg. Chem. 1997, 36, 1194
41. A. L. Odom, P. L. Arnold, C. C. Cummins, J. Am. Chem. Soc. 1998, 120, 5836.
42. III) were also observed, which is inevitable given the sensitivity of 2
43. C. J. H. Jacobsen, E. Pedersen, J. Villadsen, H. Weihe, Inorg. Chem. 1993, 32, 1216
44. N. Laurance, J. Lambe, Phys. Rev. 1963, 132, 1029
45. K. K. Chan, L. Shields, J. Chem. Soc. A 1970, 2700.
46. G. S. Girolami, G. Wilkinson, A. M. R. Galas, M. Thornton-Pett, M. B. Hursthouse, J. Chem. Soc. Dalton Trans. 1985, 1339
47. M. J. Scott, W. C. A. Wilisch, W. H. Armstrong, J. Am. Chem. Soc. 1990, 112, 2430
48. II complexes at the Xa band (Ref.[13a] and [13b]).
49. E. A. Maatta, Inorg. Chem. 1984, 23, 2560
50. D. D. Devore, J. D. Lichtenhan, F. Takusagawa, E. A. Maatta, J. Am. Chem. Soc. 1987, 109, 7408
51. M. G. Fickes, W. M. Davis, C. C. Cummins, J. Am. Chem. Soc. 1995, 117, 6384
52. W. Zhang, J. Yamada, K. Nomura, Organometallics 2008, 27, 5353
53. J.-I. Song, S. Gambarotta, Chem. Eur. J. 1996, 2, 1258.
54. H.-T. Chiu, Y.-P. Chen, S.-H. Chuang, J.-S. Jen, G.-H. Lee, S.-M. Peng, Chem. Commun. 1996, 139.
55. L. K. Woo, J. G. Goll, D. J. Czapla, J. A. Hays, J. Am. Chem. Soc. 1991, 113, 8478
56. L. K. Woo, Chem. Rev. 1993, 93, 1125
57. L. K. Woo, J. G. Goll, J. Am. Chem. Soc. 1989, 111, 3755
58. F. L. Neely, L. A. Bottomley, Inorg. Chem. 1997, 36, 5432
59. C. E. Laplaza, A. R. Johnson, C. C. Cummins, J. Am. Chem. Soc. 1996, 118, 709
60. C. J. Chang, D. W. Low, H. B. Gray, Inorg. Chem. 1997, 36, 270
61. Y.-C. Tsai, M. J. A. Johnson, D. J. Mindiola, W. T. Klooster, T. F. Koetzle, C. C. Cummins, J. Am. Chem. Soc. 1999, 121, 10426
62. T. Birk, J. Bendix, Inorg. Chem. 2003, 42, 7608.
63. 3:, B. M. Cossairt, M.-C. Diawara, C. C. Cummins, Science 2009, 323, 602.
64. B. M. Cossairt, N. A. Piro, C. C. Cummins, Chem. Rev. 2010, 110, 4164.
65. 2 (60a atm)
66. P. Berno, S. Gambarotta, Angew. Chem. 1995, 107, 871
67. Angew. Chem. Int. Ed. Engl. 1995, 34, 822.
68. S. Ye, F. Neese, A. Ozarowski, D. Smirnov, J. Krzystek, J. Telser, J.-H. Liao, C.-H. Hung, W.-C. Chu, Y.-F. Tsai, R.-C. Wang, K.-Y. Chen, H.-F. Hsu, Inorg. Chem. 2010, 49, 977.