Homologation of isocyanates with lithium carbenoids: A straightforward access to α-halomethyl- and α,α-dihalomethylamides

Synthesis (Germany)

Volumn 46, Issue 21, 2014, Pages 2897-2909

  Pace, Vittorio ^a   Castoldi, Laura ^a   Mamuye, Ashenafi Damtew ^a,b   Holzer, Wolfgang ^a  

^a UNIVERSITY OF VIENNA   (Austria)

^b UNIVERSITY OF SASSARI   (Italy)

Author keywords

amides; carbenoids; halides; lithiation; nucleophilic addition

Indexed keywords

ADDITION REACTIONS; AMIDES; HALOGEN COMPOUNDS; KETONES; LITHIUM;

CARBENOIDS; DIHALO COMPOUNDS; HALIDES; HALOGEN EXCHANGE; LITHIATION; NUCLEOPHILIC ADDITIONS; ONE-POT PREPARATIONS; SECONDARY AMIDES;

LITHIUM COMPOUNDS;

ACETAMIDE DERIVATIVE; ALPHA CHLORO KETONE; ALPHA HALOMETHYLAMIDE; ALPHA,ALPHA DIHALOMETHYLAMIDE; AMIDE; CARBENOID; CHLORAMPHENICOL; DIHALOLITHIUM CARBENOID; FLORFENICOL; HALOGEN; HOLOAMIDE; ISOCYANIC ACID DERIVATIVE; KETONE DERIVATIVE; LITHIUM; LITHIUM DERIVATIVE; MONOHALOLITHIUM CARBENOID; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHIRALITY; CONTROLLED STUDY; DEPROTONATION; DRUG STRUCTURE; HOMOLOGATION; NITROGEN NUCLEAR MAGNETIC RESONANCE; ONE POT SYNTHESIS; OPTICS;

EID: 84912143824     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0034-1379209     Document Type: Article

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