α,β-unsaturated diazoketones as platforms in the asymmetric synthesis of hydroxylated alkaloids. Total synthesis of 1-deoxy-8,8a- diepicastanospermine and 1,6-dideoxyepicastanospermine and formal synthesis of pumiliotoxin 251D

Journal of Organic Chemistry

Volumn 77, Issue 21, 2012, Pages 9926-9931

  Bernardim, Barbara ^a   Pinho, Vagner D ^a   Burtoloso, Antonio C B ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC SYNTHESIS; DIAZOKETONES; FORMAL SYNTHESIS; INDOLIZIDINES; STEREOSELECTIVE DIHYDROXYLATION; STEREOSELECTIVE SYNTHESIS; TOTAL SYNTHESIS; WOLFF REARRANGEMENT;

HYDROXYLATION; METABOLITES; STEREOCHEMISTRY; STEREOSELECTIVITY;

NITROGEN COMPOUNDS;

1 DEOXY 8,8A DIEPICASTANOSPERMINE; 1,6 DIDEOXYEPICASTANOSPERMINE; ALKALOID; ALPHA,BETA UNSATURATED DIAZOKETONE; CASTANOSPERMINE DERIVATIVE; INDOLIZIDINE ALKALOID; KETONE DERIVATIVE; PUMILIOTOXIN; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; STEREOCHEMISTRY;

ALKALOIDS; DIAZONIUM COMPOUNDS; HYDROXYLATION; INDOLIZIDINES; INDOLIZINES; MOLECULAR STRUCTURE; STEREOISOMERISM;

EID: 84868361017     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo301967w     Document Type: Article

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