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Volumn 18, Issue 10, 2014, Pages 1192-1210

Preparation, properties, and safe handling of commercial organolithiums: Alkyllithiums, lithium sec-organoamides, and lithium alkoxides

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLLITHIUMS; LITHIUM ALKOXIDES; ORGANOLITHIUMS;

EID: 84907997827     PISSN: 10836160     EISSN: 1520586X     Source Type: Journal    
DOI: 10.1021/op500161b     Document Type: Review
Times cited : (80)

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    • Butane evolution is most often experienced during the higher temperatures of the workup procedures
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    • A second equivalent of n-BuLi (Scheme 10b) is required to decompose n-butyl iodide byproduct generated in the first step (Scheme 10a). Also, butene and butane are possible decomposition products but were not reported
    • A second equivalent of n-BuLi (Scheme 10b) is required to decompose n-butyl iodide byproduct generated in the first step (Scheme 10a). Also, butene and butane are possible decomposition products but were not reported.
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    • One brand of flame-resistant fabric is Nomex. A variety of Nomex clothing styles, including lab coats, coveralls, shirts, and pants, is commercially available. Flame-resistant clothing is available from a number of laboratory supply vendors, including Fisher Scientific, Sigma-Aldrich, and VWR
    • One brand of flame-resistant fabric is Nomex. A variety of Nomex clothing styles, including lab coats, coveralls, shirts, and pants, is commercially available. Flame-resistant clothing is available from a number of laboratory supply vendors, including Fisher Scientific, Sigma-Aldrich, and VWR.
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    • One pair of Viton gloves, size 9, is listed in the VWR catalog for $236.54. https://us.vwr.com/store/catalog/product.jsp?catalog-number=89236-764 (accessed May 16, 2014).
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    • A variety of bottle tote safety carriers are commercially available from laboratory supply houses, in multiple sizes. One set of such carriers can be found at: https://www.spectrumchemical.com/OA-HTML/lab-supplies-products-Bottle-Tote-Safety-Carrier-301205.jsp?section=12095 (accessed May 16, 2014).
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    • Ansul Purple-K is one popular brand of dry chemical fire extinguisher. Other dry chemical extinguishers effective for organolithium fires include Plus Fifty B and Monnex
    • Ansul Purple-K is one popular brand of dry chemical fire extinguisher. Other dry chemical extinguishers effective for organolithium fires include Plus Fifty B and Monnex.
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    • Butyllithium , pp. 33
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    • A variety of bubbler designs are commercially available from laboratory glassware suppliers. A versatile bubbler design is Chemglass catalog number AF-0513-20. accessed May 16, 2014
    • A variety of bubbler designs are commercially available from laboratory glassware suppliers. A versatile bubbler design is Chemglass catalog number AF-0513-20. http://www.chemglass.com/product-view.asp?pnr=AF-0513 (accessed May 16, 2014).
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    • op. cit.
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    • Butyllithium , pp. 7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.