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Volumn 12, Issue 14, 2014, Pages 2176-2179

The mechanism of the NHC catalyzed aza-Morita-Baylis-Hillman reaction: Insights into a new substrate-catalyzed bimolecular pathway

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTENONES; MECHANISTIC STUDIES;

EID: 84903367746     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/c3ob42273a     Document Type: Article
Times cited : (29)

References (46)
  • 1
    • 38349142750 scopus 로고    scopus 로고
    • Chem. Rev., 2007, 107 12, 5413 5883
    • (2007) Chem. Rev. , vol.107 , Issue.12 , pp. 5413-5883
  • 39
    • 75749083809 scopus 로고    scopus 로고
    • Gaussian, Inc, Wallingford, CT,. See ESI for full computational methods and citations. The mPW1K functional has been successfully employed in the study of the reaction mechanism of the MBH reaction, see
    • M. J. Frisch, et al., Gaussian 09 Revision A.02, Gaussian, Inc, Wallingford, CT, 2009
    • (2009) Gaussian 09 Revision A.02
    • Frisch, M.J.1
  • 41
    • 80755155947 scopus 로고    scopus 로고
    • -1 as compared to the bimolecular pathway It is of importance here to note that intermediate 9 could as well expel NHC to give an aminal intermediate, which could further dissociate to form the product. However, this possibility is found to be of higher energy (see ESI for details)
    • S. Schenker C. Schneider S. B. Tsogoeva T. Clark J. Chem. Theory Comput. 2011 7 3586
    • (2011) J. Chem. Theory Comput. , vol.7 , pp. 3586
    • Schenker, S.1    Schneider, C.2    Tsogoeva, S.B.3    Clark, T.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.