Dualistic nature of the mechanism of the morita-baylis-hillman reaction probed by electrospray ionization mass spectrometry

Journal of Organic Chemistry

Volumn 74, Issue 8, 2009, Pages 3031-3037

  Amarante, Giovanni W ^a   Milagre, Humberto M S ^a   Vaz, Boniek G ^a   Ferreira, Bruno R Vilachã ^a   Eberlin, Marcos N ^a   Coelho, Fernando ^a  

^a UNIVERSITY OF CAMPINAS   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

C-C BONDS; CHEMICAL MANIPULATIONS; ELECTROSPRAY IONIZATION MASS SPECTROMETRIES; EXPERIMENTAL EVIDENCES; FUNCTIONALIZED; GAS-PHASE; KINETIC EXPERIMENTS; MORITA-BAYLIS-HILLMAN REACTIONS; RATE-DETERMINING STEPS; SINGLE STEPS; STRUCTURAL ASSIGNMENTS; THEORETICAL CALCULATIONS;

CHEMICAL BONDS; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; IONIZATION OF GASES; MASS SPECTROMETRY; PROTON TRANSFER; RATE CONSTANTS; SPECTROMETERS;

ELECTROSPRAY IONIZATION;

ACRYLIC ACID METHYL ESTER; BENZALDEHYDE; CARBON; PROTON;

ARTICLE; BAYLIS HILLMAN REACTION; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; ELECTROSPRAY MASS SPECTROMETRY; GAS; ION TRANSPORT; PROTON TRANSPORT; TANDEM MASS SPECTROMETRY;

ACRYLATES; BENZALDEHYDES; CATALYSIS; GASES; KINETICS; MOLECULAR STRUCTURE; PROTONS; SOLUTIONS; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; STEREOISOMERISM; TANDEM MASS SPECTROMETRY;

EID: 65249127674     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo802578t     Document Type: Article

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64. 6. The analogous protonated species of m/z 411 and 423 were intercepted, and their ESI-MS/MS are shown in Figures S4 and S6 (see the Supporting Information).