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Volumn 47, Issue 23, 2011, Pages 6593-6595

On the mechanism of the aza-Morita-Baylis-Hillman reaction: ESI-MS interception of a unique new intermediate

Author keywords

[No Author keywords available]

Indexed keywords

SULFONAMIDE;

EID: 79957985387     PISSN: 13597345     EISSN: 1364548X     Source Type: Journal    
DOI: 10.1039/c1cc10678c     Document Type: Article
Times cited : (44)

References (43)
  • 14
  • 35
    • 77955469206 scopus 로고    scopus 로고
    • No change in the ESI(+)-MS profile of this reaction was observed when we performed experiments in different concentrations of reagents. A similar intermediate has been proposed by M. Shi to explain an anomalous behaviour of an aza-MBH reaction with propiolates, see:
    • B. Temelli D. I. Tasgin C. Unaleroglu Tetrahedron 2010 66 6765
    • (2010) Tetrahedron , vol.66 , pp. 6765
    • Temelli, B.1    Tasgin, D.I.2    Unaleroglu, C.3
  • 43
    • 0037423248 scopus 로고    scopus 로고
    • The ESI-MS interception of no aza analog of dioxanone does not eliminate the possibility of its existence. However the low nucleophilicity of an anionic sulfonylated nitrogen atom would tend to hamper its formation
    • V. K. Aggarwal I. Emme S. Y. Fulford J. Org. Chem. 2003 68 692
    • (2003) J. Org. Chem. , vol.68 , pp. 692
    • Aggarwal, V.K.1    Emme, I.2    Fulford, S.Y.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.