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Volumn 136, Issue 16, 2014, Pages 5832-5835

A general approach to mechanism in multiproduct reactions: Product-specific intermolecular kinetic isotope effects

Author keywords

[No Author keywords available]

Indexed keywords

ISOTOPES;

EID: 84899527924     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja412827c     Document Type: Article
Times cited : (9)

References (35)
  • 18
    • 45749090574 scopus 로고    scopus 로고
    • It should be noted that the bulk fractional conversion, F, may only be used as shown in eq 1 when the isotopic label is present at only trace levels. When substantial amounts of labeled material are used in competitively measured KIE experiments, fractional conversion for competing isotopomers or isotopologues must be considered explicitly. A full derivation is given in the following - 7817
    • It should be noted that the bulk fractional conversion, F, may only be used as shown in eq 1 when the isotopic label is present at only trace levels. When substantial amounts of labeled material are used in competitively measured KIE experiments, fractional conversion for competing isotopomers or isotopologues must be considered explicitly. A full derivation is given in the following: West, J. D.; Meyer, M. P. J. Am. Chem. Soc. 2008, 130, 7816-7817
    • (2008) J. Am. Chem. Soc. , vol.130 , pp. 7816
    • West, J.D.1    Meyer, M.P.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.