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A tentative mechanism for the formation of compound 41 is shown in Scheme S2, and has been calculated by DFT (see the Supporting Information). The present proposal also finds support in the results reported by Austel and colleagues in their synthesis of 3-aminomethyl-5-imino-8-nitro-2,3- dihydroimidazo[1,2-a]pyridines from related intermediates, see:, S. Schmid, D. Schüle, S. Steinberger, Z. Xin, V. Austel, Synthesis 2005, 3107.
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