A cobalt-catalyzed alkene hydroboration with pinacolborane

Angewandte Chemie - International Edition

Volumn 53, Issue 10, 2014, Pages 2696-2700

  Zhang, Lei ^a   Zuo, Ziqing ^a   Leng, Xuebing ^a   Huang, Zheng ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

alkenes; cobalt; cross coupling; hydroboration; synthetic methods

Indexed keywords

CHEMO-SELECTIVITY; COBALT CATALYST; COBALT COMPLEXES; CROSS-COUPLINGS; HYDROBORATION; SYNTHETIC METHODS; SYSTEM DISPLAYS; TURNOVER NUMBER;

CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COBALT; OLEFINS;

COBALT COMPOUNDS;

EID: 84897594218     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201310096     Document Type: Article

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63. 1H NMR analysis) and its isomer (≈7 %) arising from the hydroboration of the gem-disubstituted alkene in 7 o and subsequent coupling. Notably, a product (≈5 %) resulting from the hydroboration of both monosubstituted alkene and gem-disubstituted alkene and subsequent coupling with two aryl chlorides was also detected by GC/MS and GC analysis.