Endohedral metallofullerenes based on spherical i h-C 80 cage: Molecular structures and paramagnetic properties

Accounts of Chemical Research

Volumn 47, Issue 2, 2014, Pages 450-458

  Wang, Taishan ^a   Wang, Chunru ^a  

^a INSTITUTE OF CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84894277249     PISSN: 00014842     EISSN: 15204898     Source Type: Journal    
DOI: 10.1021/ar400156z     Document Type: Article

References (60)

1. Fowler, P. W., Manolopoulos, D. E. An Atlas of Fullerenes; Clarendon Press: Oxford, U.K., 1995.
2. Hirsch, A., Brettreich, M. Fullerenes: Chemistry and Reactions; Wiley-VCH Verlag GmbH & Co. KGaA: Weinheim, Germany, 2005.
3. 80 fullerene IPR isomers Fullerenes, Nanotubes, Carbon Nanostruct. 2011, 19, 599-604
4. 80: Are there still more isomers? J. Chem. Phys. 2001, 114, 10362-10367
5. 80 Angew. Chem., Int. Ed. 1996, 35, 1732-1734
6. Shinohara, H. Endohedral metallofullerenes Rep. Prog. Phys. 2000, 63, 843-892
7. Rodriguez-Fortea, A.; Balch, A. L.; Poblet, J. M. Endohedral metallofullerenes: A unique host-guest association Chem. Soc. Rev. 2011, 40, 3551-3563
8. Lu, X.; Akasaka, T.; Nagase, S. Chemistry of endohedral metallofullerenes: The role of metals Chem. Commun. 2011, 47, 5942-5957
9. Dunsch, L.; Yang, S. F. Endohedral clusterfullerenes: Playing with cluster and cage sizes Phys. Chem. Chem. Phys. 2007, 9, 3067-3081
10. Chaur, M. N.; Melin, F.; Ortiz, A. L.; Echegoyen, L. Chemical, electrochemical, and structural properties of endohedral metallofullerenes Angew. Chem., Int. Ed. 2009, 48, 7514-7538
11. Yamada, M.; Akasaka, T.; Nagase, S. Endohedral metal atoms in pristine and functionalized fullerene cages Acc. Chem. Res. 2010, 43, 92-102
12. Lu, X.; Akasaka, T.; Nagase, S. Carbide cluster metallofullerenes: Structure, properties, and possible origin Acc. Chem. Res. 2013, 46, 1627-1635
13. Zhang, J.; Stevenson, S.; Dorn, H. C. Trimetallic nitride template endohedral metallofullerenes: Discovery, structural characterization, reactivity, and applications Acc. Chem. Res. 2013, 46, 1548-1557
14. Popov, A. A.; Yang, S.; Dunsch, L. Endohedral fullerenes Chem. Rev. 2013, 113, 5989-6113
15. Garcia-Borràs, M.; Osuna, S.; Swart, M.; Luis, J. M.; Solà, M. Maximum aromaticity as a guiding principle for the most suitable hosting cages in endohedral metallofullerenes Angew. Chem., Int. Ed. 2013, 52, 9275-9278
16. Bethune, D. S.; Johnson, R. D.; Salem, J. R.; Devries, M. S.; Yannoni, C. S. Atoms in carbon cages: The structure and properties of endohedral fullerenes Nature 1993, 366, 123-128
17. 80 Angew. Chem., Int. Ed. 1995, 34, 1094-1096
18. 80: First evidence for circular motion of metal atoms in endohedral dimetallofullerenes Angew. Chem., Int. Ed. 1997, 36, 1643-1645
19. Stevenson, S.; Rice, G.; Glass, T.; Harich, K.; Cromer, F.; Jordan, M. R.; Craft, J.; Hadju, E.; Bible, R.; Olmstead, M. M.; Maitra, K.; Fisher, A. J.; Balch, A. L.; Dorn, H. C. Small-band gap endohedral metallofullerenes in high yield and purity Nature 1999, 401, 55-57
20. 84 Angew. Chem., Int. Ed. 2001, 40, 397-399 (Pubitemid 32114885)
21. 82 revisited: A surprising finding J. Am. Chem. Soc. 2005, 127, 12500-12501 (Pubitemid 41292163)
22. 80 J. Am. Chem. Soc. 2008, 130, 11844-11845
23. h J. Am. Chem. Soc. 2010, 132, 16362-16364
24. 79N: Isolation, characterization, and monoadduct formation of a very stable heterofullerene with a magnetic spin state of S = 15/2 J. Am. Chem. Soc. 2011, 133, 9741-9750
25. 79N (M = Y, Tb): Isolation and characterization of stable endohedral metallofullerenes exhibiting M-M bonding interactions inside aza[80]fullerene cages J. Am. Chem. Soc. 2008, 130, 12992-12997
26. 80 Chem. Commun. 2010, 46, 279-281
27. 80 with nitrogen substituted by a pseudoatom ACS Nano 2010, 4, 795-802
28. 80: Encapsulation of three metal atoms in a cage without a nonmetallic mediator J. Am. Chem. Soc. 2013, 135, 4187-4190
29. 80: Synthesis, isolation, and effect of the group-III metal Inorg. Chem. 2012, 51, 3039-3045
30. 80: Preference for [5,6]-bonds, and not pyracylenic bonds Chem. Commun. 2012, 48, 2486-2488
31. h isomer and the influence of the metal cluster Chem. -Eur. J. 2012, 18, 8944-8956
32. 80 Endohedral Metallofullerenes Chem.-Eur. J. 2013, 19, 14931-14940
33. Osuna, S.; Swart, M.; Sola, M. The reactivity of endohedral fullerenes. What can be learnt from computational studies? Phys. Chem. Chem. Phys. 2011, 13, 3585-3603
34. 80 J. Phys. Chem. B 2006, 110, 13322-13325 (Pubitemid 44115568)
35. 80: A density functional theory investigation J. Phys. Chem. A 2006, 110, 1171-1176
36. 80 metallofullerene by third generation synchrotron radiation X-ray powder diffraction J. Phys. Chem. B 2006, 110, 19215-19219 (Pubitemid 44626390)
37. 80 ChemPhysChem 2007, 8, 537-540
38. 80 J. Am. Chem. Soc. 2009, 131, 16646-16647
39. 80 J. Phys. Chem. B 2006, 110, 11098-11102
40. 80 (n = 2, 3) Inorg. Chem. 2009, 48, 5957-5961
41. 2 n (2 n = 68, 78, and 80) Phys. Chem. Chem. Phys. 2010, 12, 12442-12449
42. Feng, Y. Q.; Wang, T. S.; Wu, J. Y.; Ma, Y. H.; Zhang, Z. X.; Jiang, L.; Ge, C. H.; Shu, C. Y.; Wang, C. R. Spin-active metallofullerene stabilized by the core of an NC moiety Chem. Commun. 2013, 49, 2148-2150
43. 2 J. Phys. Chem. C 2011, 115, 23755-23759
44. 82 Sci. Rep. 2013, 3, 1487
45. 2 Science 1995, 269, 1554-1556
46. 79N J. Am. Chem. Soc. 2009, 131, 17780-17782
47. 80) from the 6,6 to the 5,6 regioisomer Angew. Chem., Int. Ed. 2006, 45, 8176-8180 (Pubitemid 44974156)
48. 80 (x = 0-3) J. Phys. Chem. C 2007, 111, 11823-11828 (Pubitemid 47325757)
49. 80 (x = 0-3) Org. Lett. 2007, 9, 2011-2013
50. 80 (M = Er, Dy, Gd, Nd) J. Phys. Chem. C 2009, 113, 7616-7623
51. Yang, S. F.; Popov, A. A.; Dunsch, L. Carbon pyramidalization in fullerene cages induced by the endohedral cluster: Non-scandium mixed metal nitride clusterfullerenes Angew. Chem., Int. Ed. 2008, 47, 8196-8200
52. 80 fullerene cage: An electron paramagnetic resonance and photoluminescence excitation study Phys. Rev. Lett. 2008, 101 (1 013002
53. 80 J. Phys. Chem. Lett. 2012, 3, 3291-3296
54. h fullerene cage Chem. Commun. 2009, 42, 6391-6393
55. 80 bisfulleroid derivative J. Am. Chem. Soc. 2012, 134, 4092-4095
56. 80 fulleropyrrolidine Angew. Chem., Int. Ed. 2010, 49, 1786-1789
57. 80 bis-addition fulleropyrrolidines Dalton Trans. 2012, 41, 2567-2570
58. 79N Chem. Commun. 2012, 48, 11570-11572
59. 80 radical anions J. Am. Chem. Soc. 2001, 123, 8854-8855 (Pubitemid 32852689)
60. 80 and its ion radicals J. Am. Chem. Soc. 2012, 134, 19607-19618