A graphene hybrid material functionalized with POSS: Synthesis and applications in low-dielectric epoxy composites

Composites Science and Technology

Volumn 92, Issue , 2014, Pages 112-119

  Yu, Wenqi ^a   Fu, Jifang ^a   Dong, Xing ^a   Chen, Liya ^a   Shi, Liyi ^a  

^a SHANGHAI UNIVERSITY   (China)

Author keywords

A. Nano composites; A. Polymer matrix composites (PMCs); B. Electrical properties; B. Thermal properties

Indexed keywords

EPOXY COMPOSITE MATERIALS; EPOXY STRUCTURES; FUNCTIONALIZED GRAPHENE; NEW APPLICATIONS; POLYHEDRAL OLIGOMERIC SILSESQUIOXANES; POLYMER MATRIX COMPOSITES (PMCS); THERMAL DECOMPOSITION TEMPERATURE; THERMAL GRAVIMETRIC ANALYSES (TGA);

DECOMPOSITION; DIELECTRIC DEVICES; DIELECTRIC LOSSES; ELECTRIC PROPERTIES; GRAPHENE; THERMOGRAVIMETRIC ANALYSIS;

HYBRID MATERIALS;

EID: 84892458690     PISSN: 02663538     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.compscitech.2013.12.016     Document Type: Article

References (40)

1. Novoselov K.S., Geim A.K., Morozov S.V., Jiang D., Zhang Y., Dubonos S.V., et al. Electric field effect in atomically thin carbon films. Science 2004, 306:666-669.
2. Roy-Mayhew J.D., Boschloo G., Hagfeldt A., Aksay I.A. Functionalized graphene sheets as a versatile replacement for platinum in dye-sensitized solar cells. ACS Appl Mater Interfaces 2012, 4:2794-2800.
3. Qu L., Liu Y., Baek J.-B., Dai L. Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells. Acs Nano 2010, 4:1321-1326.
4. Yu D., Dai L. Self-assembled graphene/carbon nanotube hybrid films for supercapacitors. J Phys Chem Lett 2010, 1:467-470.
5. Liu Y., Yu D., Zeng C., Miao Z., Dai L. Biocompatible graphene oxide-based glucose biosensors. Langmuir 2010, 26:6158-6160.
6. Wang X., Yang H.Y., Song L., Hu Y., Xing W.Y., Lu H.D. Morphology, mechanical and thermal properties of graphene-reinforced poly(butylene succinate) nanocomposites. Compos Sci Technol 2011, 72:1-6.
7. Fina A., Tabuani D., Peijs T., Camino G. POSS grafting on PPgMA by one-step reactive blending. Polymer 2009, 50:218-226.
8. Zhang W., Fang B., Walther A., Mueller A.H.E. Synthesis via RAFT polymerization of tadpole-shaped organic/inorganic hybrid poly(acrylic acid) containing polyhedral oligomeric silsesquioxane (POSS) and their self-assembly in water. Macromolecules 2009, 42:2563-2569.
9. Moon J.H., Seo J.S., Xu Y., Yang S. Direct fabrication of 3D silica-like microstructures from epoxy-functionalized polyhedral oligomeric silsesquioxane (POSS). J Mater Chem 2009, 19:4687-4691.
10. Valentini L., Bon S.B., Cardinali M., Monticelli O., Kenny J.M. POSS vapor grafting on graphene oxide film. Chem Phys Lett 2012, 537:84-87.
11. Xue Y., Liu Y., Lu F., Qu J., Chen H., Dai L. Functionalization of graphene oxide with polyhedral oligomeric silsesquioxane (POSS) for multifunctional applications. J Phys Chem Lett 2012, 3:1607-1612.
12. Lerf A., He H.Y., Forster M., Klinowski J. Structure of graphite oxide revisited. J Phys Chem B 1998, 102:4477-4482.
13. Lee B.D., Park Y.H., Hwang Y.T., Oh W., Yoon J., Ree M. Ultralow-k nanoporous organosilicate dielectric films imprinted with dendritic spheres. Nat Mater 2005, 4:147-151.
14. Sebastian M.T., Jantunen H. Low loss dielectric materials for LTCC applications: a review. Int Mater Rev 2008, 53:57-90.
15. Wang X., Xing W.Y., Zhang P., Song L., Yang H.Y., Hu Y. Covalent functionalization of graphene with organosilane and its use as a reinforcement in epoxy composites. Compos Sci Technol 2012, 72:737-743.
16. Volksen W., Miller R.D., Dubois G. Low dielectric constant materials. Chem Rev 2010, 110:56-110.
17. Wang W., Grozea D., Kim A., Perovic D.D., Ozin G.A. Vacuum-assisted aerosol deposition of a low-dielectric-constant periodic mesoporous organosilica film. Adv Mater 2010, 22:99-102.
18. Ni Y., Zheng S.X. A novel photocrosslinkable polyhedral oligomeric silsesquioxane and its nanocomposites with poly(vinyl cinnamate). Chem Mater 2004, 16:5141-5148.
19. Marcano D.C., Kosynkin D.V., Berlin J.M., Sinitskii A., Sun Z., Slesarev A., et al. Improved synthesis of graphene oxide. Acs Nano 2010, 4:4806-4814.
20. McNally T., Potschke P., Halley P., Murphy M., Martin D., Bell S.E.J., et al. Polyethylene multiwalled carbon nanotube composites. Polymer 2005, 46:8222-8232.
21. Rao C.N.R., Sood A.K., Subrahmanyam K.S., Govindaraj A. Graphene: the new two-dimensional nanomaterial. Angew Chem Int Edit 2009, 48:7752-7777.
22. Paredes J.I., Villar-Rodil S., Martinez-Alonso A., Tascon J.M.D. Graphene oxide dispersions in organic solvents. Langmuir 2008, 24:10560-10564.
23. Xu Y., Liu Z., Zhang X., Wang Y., Tian J., Huang Y., et al. A graphene hybrid material covalently functionalized with porphyrin: synthesis and optical limiting property. Adv Mater 2009, 21:1275-1279.
24. Allen M.J., Tung V.C., Kaner R.B. Honeycomb carbon: a review of graphene. Chem Rev 2010, 110:132-145.
25. Li D., Mueller M.B., Gilje S., Kaner R.B., Wallace G.G. Processable aqueous dispersions of graphene nanosheets. Nat Nanotechnol 2008, 3:101-105.
26. Paci J.T., Belytschko T., Schatz G.C. Computational studies of the structure, behavior upon heating, and mechanical properties of graphite oxide. J Phys Chem C 2007, 111:18099-18111.
27. Xu Z., Gao C. In situ Polymerization approach to graphene-reinforced nylon-6 composites. Macromolecules 2010, 43:6716-6723.
28. Zhang B., Chen Y., Zhuang X., Liu G., Yu B., Kang E.-T., et al. Poly(N-vinylcarbazole) chemically modified graphene oxide. J Polym Sci, Part A: Polym Chem 2010, 48:2642-2649.
29. Yuan C., Jin K.K., Li K., Diao S., Tong J.W., Fang Q. Non-porous low-k dielectric films based on a new structural amorphous fluoropolymer. Adv Mater 2013, 25:4875-4878.
30. Maex K., Baklanov M.R., Shamiryan D., Iacopi F., Brongersma S.H., Yanovitskaya Z.S. Low dielectric constant materials for microelectronics. J Appl Phys 2003, 93:8793-8841.
31. Livi A., Levita G., Rolla P.A. Dielectric behavior at microwave-frequencies of an epoxy-resin during cross-linking. J Appl Polym Sci 1993, 50:1583-1590.
32. Eloundou J.P. Dipolar relaxations in an epoxy-amine system. Eur Polym J 2002, 38:431-438.
33. Tsagaropoulos G., Eisenberg A. Dynamic mechanical study of the factors affecting the two glass transition behavior of filled polymers. Similarities and differences with random ionomers. Macromolecules 1995, 28:6067-6077.
34. Dang Z.M., Wang L., Yin Y., Zhang Q., Lei Q.Q. Giant dielectric permittivities in functionalized carbon-nanotube/electroactive-polymer nanocomposites. Adv Mater 2007, 19:852-857.
35. Singha S., Thomas M.J. Dielectric properties of epoxy nanocomposites. IEEE Trans Dieletric Electr Insul 2008, 15:12-23.
36. Wang D., Bao Y., Zha J.-W., Zhao J., Dang Z.-M., Hu G.-H. Improved dielectric properties of nanocomposites based on poly(vinylidene fluoride) and poly(vinyl alcohol)-functionalized graphene. ACS Appl Mater Interfaces 2012, 4:6273-6279.
37. Stankovich S., Dikin D.A., Dommett G.H.B., Kohlhaas K.M., Zimney E.J., Stach E.A., et al. Graphene-based composite materials. Nature 2006, 442:282-286.
38. Liao L., Duan X. Graphene-dielectric integration for graphene transistors. Mater Sci Eng R: Rep 2010, 70:354-370.
39. Zhen D., Tang G.S., Zhang H.-B., et al. In situ thermal reduction of graphene oxide for high electrical conductivity and low percolation threshold in polyamide 6 nanocomposites. Compos Sci Technol 2011, 72:284-289.
40. Dreyer D.R., Park S., Bielawski C.W., Ruoff R.S. The chemistry of graphene oxide. Chem Soc Rev 2010, 39:228-240.