Conversion of carbon dioxide into methanol - A potential liquid fuel: Fundamental challenges and opportunities (a review)

Renewable and Sustainable Energy Reviews

Volumn 31, Issue , 2014, Pages 221-257

  Ganesh, Ibram ^a  

^a INTERNATIONAL ADVANCED RESEARCH CENTRE FOR POWDER METALLURGY AND NEW MATERIALS ARCI   (India)

Author keywords

Artificial photosynthesis; Carbon dioxide; Methanol; Molecular catalysts; Renewable and sustainable energy; Stoichiometric reactions

Indexed keywords

ARTIFICIAL PHOTOSYNTHESIS; CARBON DIOXIDE PROCESS; FOSSIL FUELS; FUEL STORAGE; GLOBAL WARMING; LIQUID FUELS; METHANOL; METHANOL FUELS; SOLAR ENERGY;

GLOBAL WARMING PROBLEMS; HIGH ENERGY DENSITIES; MOLECULAR CATALYSTS; PHOTOELECTROCHEMICALS; RESEARCH PRIORITIES; STOICHIOMETRIC REACTION; SUSTAINABLE ENERGY; VALUE-ADDED CHEMICALS;

CARBON DIOXIDE;

EID: 84890493127     PISSN: 13640321     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.rser.2013.11.045     Document Type: Review

References (357)

1. AB Robinson, NE Robinson, and A. Soon Environmental effects of increased atmospheric carbon dioxide J Am Phys Sur 12 2007 79 90
2. David J, Herzog H. The cost of carbon capture. In: Fifth international conference on greenhouse gas control technologies 2001, Cairns, Qld., Australia, 13-16th August 2000. Collingwood, Vic., Australia: CSIRO. p. 985.
3. 2 capture and storage. In: International energy agency and energy technology analysis; 2004. IEA Publications. 〈http://www.iea.org/textbase/nppdf/free/2004/ prospects.pdfâŒ
4. 2 in geological media: criteria and approach for site selection in response to climate change Energy Convers Manage 41 9 2000 953
5. 2 in solution Energy Convers Manage 44 20 2003 3151
6. 2 in deep saline aquifers Environ Sci Technol 36 11 2002 240A
7. 2 sequestration Geol Belgica 7 2004 3 4
8. 2 in aquifers and oil reservoirs Energy Convers Manage 36 6-9 1995 535
9. 2 collection, transport and sequestration. Presented at the third Nordic mini-symposium on carbon dioxide storage, Trondheim, Norway; 3 October 2003.
10. 2-enhanced coal bed methane production Energy 29 2004 1611
11. 2 capture in an FBC environment Chem Eng J 96 3 2003 187
12. 2 reversibly J Am Chem Soc 130 10 2008 2902
13. SK. Ritter What can we do with carbon dioxide? Scientists are trying to find ways to convert the plentiful greenhouse gas into fuels and other value-added products Chem Eng News 85 18 2007 11
14. 2 capture with SOFC. In: Proceedings of the sixth international conference on greenhouse gas control technologies 2003, Kyoto, Japan; 1-4 October 2002. Oxford, UK: Elsevier Science (Pergamon). p. 161.
15. B Dickson, I Yashayaev, J Meincke, B Turrell, S Dye, and J. Holfort Rapid freshening of the deep North Atlantic Ocean over the past four decades Nature 416 6883 2002 832
16. Priddle R. World energy outlook 2002. In: International energy agency and energy technology analysis 2002, IEA/OECD, 2nd ed., Paris, France. 〈http://www.iea.org/textbase/nppdf/free/2000/weo2002. pdfâŒ.
17. Gassner K, Popov A, Pushak N. World electric power-plants database. Utility Data Institute; 2003. Washington, DC: McGraw-Hill.
18. World oil and gas review 2004. ENI 2004, Rome, Italy. 〈http://www.agip.it/âŒ.
19. World Energy Council. 19th survey of world energy resources. 2001, London, UK. 〈http://www.worldenergy.org/wec-geis/ publications/default/launches/ser/ser.aspâŒ.
20. G Moritis EOR continues to unlock oil resources Oil Gas J 12 April 2004 53
21. Agency IE. Key world energy statistics 2009. IEA 2009, Paris, France; 2010.
22. Pehnt M. Fuel cells in the power market: separating the hope from the hype. Presented at CAN Europe meeting, Brussels, Belgium; 27 May 2004. 〈http://www.climnet.org/CTAP/workshop2004/PresentationsWS2. htm/âŒ.
23. NS Lewis, G Crabtree, A Nozik, M Wasielewski, and P. Alivisatos Basic research needs for solar energy utilization 2005 US Department of Energy Washington, DC
24. J. Garcia-Martinez Nanotechnology for the energy challenge 2010 Wiley-VCH Weinheim, Germany
25. TBC Group. Batteries for electric cars: challenges, opportunities, and the outlook to 2020. BCG 2010, Boston, MA, USA [September]. 〈 http://www.bcg.com/documents/file36615.pdfâŒ.
26. Exxon Mobil Algae Biofuels Research and Development Program; 2012, vol. 1, no. (1). 〈http://wwwexxonmobilcom/corporate/files/news- pub-algae-factsheetpdf/âŒ
27. 2 materials for photocurrent and photocatalytic applications. Sci World J 2012.
28. 2 intensive carbon-based energy vectors Energy (Oxford, UK) 41 2012 280 297
29. WM. Budzianowski Negative carbon intensity of renewable energy technologies involving biomass or carbon dioxide as inputs Renew Sustain Energy Rev 16 9 2012 6507 6521
30. 2-based energy vectors for the storage of solar energy Greenhouse Gas Sci Technol 1 2011 21
31. 2 capture technologies and opportunities in Canada. In: First Canadian CC&S technology roadmap workshop; 18 September 2003.
32. M Khoshtinat, NAS Amin, and I. Noshadi A review of methanol production from methane oxidation via non-thermal plasma reactor World Acad Sci Eng Technol 62 2010 354
33. Tans P. Trends in carbon dioxide. NOAA/ESRL; 29 June 2009. 〈 http://www.esrl.noaa.gov/gmd/ccgg/trends/ âŒ
34. 2: from waste to value Tce 813 2009 46
35. M. Aresta Carbon dioxide as chemical feedstock 2010 Wiley-VCH Weinheim
36. 2 as a chemical feedstock: opportunities and challenges Dalton Trans 2007 2975
37. G Centi, and S. Perathoner Opportunities and prospects in the chemical recycling of carbon dioxide to fuels Catal Today 148 3 and 4 2009 191
38. 2 recycling by reaction with renewably-generated hydrogen Int J Greenhouse Gas Control 4 2010 44
39. 2 conversion Catal Today 148 3-4 2009 221
40. YP Patil, PJ Tambade, SR Jagtap, and BM. Bhanage Carbon dioxide: a renewable feedstock for the synthesis of fine and bulk chemicals Front Chem Eng China 4 2 2010 213
41. T Sakakura, J-C Choi, and H. Yasuda Transformation of carbon dioxide Chem Rev 107 6 2007 2365
42. 2 Front Chem Eng China 4 2 2010 172
43. BM Reddy, and G. Thrimurthulu Carbon dioxide-based technologies: converting greenhouse to value added chemicals Chem Ind Digest July 2009 54
44. H Arakawa, M Aresta, JN Armor, MA Barteau, EJ Beckman, and AT Bell Catalysis research of relevance to carbon management: progress, challenges, and opportunities Chem Rev 101 4 2001 953 996
45. A Aruchamy, G Aravamudan, and GVS. Rao Semiconductor based photoelectrochemical cells for solar energy conversion - an overview Bull Mater Sci 4 5 1982 483
46. LR Sheppard, and J. Nowotny Materials for photoelectrochemical energy conversion Adv Appl Ceram 106 1-2 2007 9
47. 3 electrodes for water splitting Nano Lett 11 2011 35
48. Abbott D. Keeping the energy debate clean: how do we supply the world's energy needs? Proc IEEE 2010;98(1): 42-66.
49. NS Lewis, and DG. Nocera Proc Natl Acad Sci USA 103 2006 15729
50. Conti JJ, Doman LE, Smith KA, Mayne LD, Yucel EM, Barden JL, et al. International energy outlook 2010. The US Energy Information Administration (EIA), US Department of Energy, DOE/EIA-0484(2010), Washington, DC; 2010, no. (1), p. 338.
51. M. Stocker Biofuels and biomass-to-liquid fuels in the biorefinery: catalytic conversion of lignocellulosic biomass using porous materials Angew Chem, Int Ed 47 2008 9200 9211
52. P. Gallezot Catalytic conversion of biomass: challenges and issues ChemSusChem 1 2008 734 737
53. GW Huber, S Iborra, and A. Corma Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering Chem Rev 106 2006 4044 4098
54. 2 ChemSusChem 3 2010 195 208
55. Nozik AJ. Nanoscience and nanostructures for photovoltaics and solar fuels. Nano Lett 2010:2735-2741. 10 [Copyright (C) 2012 American Chemical Society (ACS). All Rights Reserved].
56. SC Roy, OK Varghese, M Paulose, and CA. Grimes Toward solar fuels: photocatalytic conversion of carbon dioxide to hydrocarbons ACS Nano 4 2010 1259 1278
57. H. Tributsch Photovoltaic hydrogen generation Int J Hydrogen Energy 33 2008 5911 5930
58. TL Gibson, and NA. Kelly Optimization of solar powered hydrogen production using photovoltaic electrolysis devices Int J Hydrogen Energy 33 2008 5931 5940
59. S Manisha, and R. Banerjee Comparison of biohydrogen production processes Int J Hydrogen Energy 33 1 2008 279 286
60. SM Kotaya, and D. Das Biohydrogen as a renewable energy resource - prospects and potentials Int J Hydrogen Energy 33 1 2008 258 263
61. T Kodama, and N. Gokon Thermochemical cycles for high-temperature solar hydrogen production Chem Rev 107 2007 4048 4077
62. C Agrafiotis, M Roeb, AG Konstandopoulos, L Nalbandian, VT Zaspalis, and C Sattler Solar water splitting for hydrogen production with monolithic reactors Solar Energy 79 4 2005 409 421
63. M Roeb, JP Säck, P Rietbrock, C Prahl, H Schreiber, and M Neises Test operation of a 100 kW pilot plant for solar hydrogen production from water on a solar tower Solar Energy 85 4 2011 634 644
64. A Kudo, and Y. Miseki Heterogeneous photocatalyst materials for water splitting Chem Soc Rev 38 2009 253 278
65. YRM Navarro, GMC Alvarez, VF del, MJA Villoria dl, and JLG. Fierro Water splitting on semiconductor catalysts under visible-light irradiation ChemSusChem 2 2009 471 485
66. A. Currao Photoelectrochemical water splitting Chimia 61 2007 815819
67. NA Kelly, and TL. Gibson Design and characterization of a robust photoelectrochemical device to generate hydrogen using solar water splitting Int J Hydrogen Energy 31 2006 1658 1673
68. AJ Morris, GJ Meyer, and E. Fujita Molecular approaches to the photocatalytic reduction of carbon dioxide for solar fuels Acc Chem Res 42 2009 1983 1994
69. G Krajacic, R Martins, A Busuttil, N Duic, and GCM. da Hydrogen as an energy vector in the islands' energy supply Int J Hydrogen Energy 33 2008 1091 1103
70. PP Edwards, VL Kuznetsov, and WIF. David Hydrogen energy Philos Trans R Soc, A 365 2007 1043 1056
71. A Sartbaeva, VL Kuznetsov, SA Wells, and PP. Edwards Hydrogen nexus in a sustainable energy future Energy Environ Sci 1 2008 79 85
72. DG Vlachos, and S. Caratzoulas The roles of catalysis and reaction engineering in overcoming the energy and the environment crisis Chem Eng Sci 65 2009 18 29
73. RJ. Farrauto Building the hydrogen economy Hydrocarbon Eng 14 2009 25 30
74. NZ Muradov, and TN. Veziroglu Green path from fossil-based to hydrogen economy: an overview of carbon-neutral technologies Int J Hydrogen Energy 33 2008 6804 6839
75. HW. Cooper Fuel cells, the hydrogen economy and you Chem Eng Prog 103 2007 34 43
76. F Mueller-Langer, E Tzimas, M Kaltschmitt, and S. Peteves Techno-economic assessment of hydrogen production processes for the hydrogen economy for the short and medium term Int J Hydrogen Energy 32 2007 3797 3810
77. D. Strahan Hydrogen's long road to nowhere New Sci 200 2008 40 43
78. JOM Bockris Hydrogen no longer a high cost solution to global warming: new ideas Int J Hydrogen Energy 33 2008 2129 2131
79. GA Olah, A Goeppert, and GKS Prakash Beyond oil and gas: the methanol economy 2006 Wiley-VCH Weinheim
80. I. Taniguchi Electrochemical and photoelectrochemical reduction of carbon dioxide JOM Bockris, RE White, BE Conway, Modern aspects of electrochemistry 20 1989 Plenum Press New York 327
81. KW Frese Jr BP Sullivan, K Krist, HE Guard, Electrochemical and electrocatalytic reactions of carbon dioxide 1993 Elsevier Amsterdam 145
82. 2 reduction catalyzed by metal electrodes W Vielstich, HA Gasteiger, A Lamm, Handbook of fuel cells - fundamentals, technology and applications 2 2003 Wiley West Sussex, England 720 733 (Chapter 48)
83. GA Olah, A Goeppert, and GKS. Prakash Chemical recycling of carbon dioxide to methanol and dimethyl ether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons J Org Chem 74 2009 7487 7498
84. 2 for sustainable development involving energy, catalysis, adsorption and chemical processing Catal Today 115 2006 2 32
85. 2 to hydrocarbons at copper J Electroanal Chem 594 2006 1 19
86. Z Jiang, T Xiao, VL Kuznetsov, and PP. Edwards Turning carbon dioxide into fuel Phil Trans R Soc 368(A) 2010 3343
87. T Seki, and A. Baiker Catalytic oxidations in dense carbon dioxide Chem Rev 109 6 2009 2409 2454
88. 2 conversion and utilization. ACS symposium series. Washington, DC: American Chemical Society; 2010 [Chapter 5].
89. 2 reduction Chem Soc Rev 42 2013 2253 2261
90. DC. Webster Cyclic carbonate functional polymers and their applications Prog Org Coatings 47 1 2003 77 86
91. DJ. Darensbourg Chemistry of carbon dioxide relevant to its utilization: a personal perspective Inorg Chem 49 23 2010 10765
92. M Jitaru, DA Lowy, M Toma, BC Toma, and L. Oniciu Electrochemical reduction of carbon dioxide on flat metallic cathodes J Appl Electrochem 27 8 1997 875 889
93. J-P Collin, and J-P. Sauvage Electrochemical reduction of carbon dioxide mediated by molecular catalysts Coordination Chem Rev 93 1989 245
94. 2 utilizing room temperature ionic liquids. A thesis submitted to Chemical Engineering in the Graduate College, University of Illinois at Urbana-Champaign, Urbana, IL, USA; 2010.
95. 2 to methanol. A thesis submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College, Chemical Engineering, Louisiana State University, Baton Rouge, LA, USA; 2011.
96. D Chaturvedi, and S. Ray Versatile use of carbon dioxide in the synthesis of carbamates Monatsh Chem 137 2006 127 145
97. I. Ganesh Conversion of carbon dioxide to methanol using solar energy - a brief review Mater Sci Appl 2 2011 1407 1415
98. W Wang, S Wang, X Ma, and J. Gong Recent advances in catalytic hydrogenation of carbon dioxide Chem Soc Rev 40 7 2011 3703 3727
99. I. Omae Aspects of carbon dioxide utilization Catal Today 115 1-4 2006 33 52
100. 2 Green Chem 12 2010 1514 1539
101. I. Ganesh Conversion of carbon dioxide into several potential chemical commodities following different pathways - a review Mater Sci Forum 764 2013 1 82
102. J Nowotny, and LR. Sheppard Solar-hydrogen Int J Hydrogen Energy 32 2007 2607 2608
103. GA Olah, A Geoppert, and GKS. Prakash Chemical recycling of carbon dioxide to methanol and dimethylether: from greenhouse gas to renewable, environmentally carbon neutral fuels and synthetic hydrocarbons J Org Chem 74 2009 487
104. GA. Olah Beyond oil and gas: the methanol economy Angew Chem, Int Ed 44 2005 2636 2639
105. l6/Al system J Am Chem Soc 124 2002 11379 11391
106. F Joo, G Laurenczy, P Karady, J Elek, L Nadasdi, and R. Roulet Homogeneous hydrogenation of aqueous hydrogen carbonate to formate under mild conditions with water soluble rhodium(I)- and ruthenium(II)-phosphine catalysts Appl Organomet Chem 14 2000 857 859
107. 2 Angew Chem, Int Ed Engl 34 1995 2207 2221
108. 2 to methanol using hydroboranes J Am Chem Soc 135 25 2013 9326 9329
109. 2 to methanol by Al-based frustrated Lewis pairs and ammonia borane J Am Chem Soc 132 6 2010 1796 1797
110. 3: at the boundary of classical and frustrated Lewis pair reactivity J Am Chem Soc 131 2009 3476 3477
111. 3OH Angew Chem, Int Ed 48 2009 9839 9843
112. T Matsuo, and H. Kawaguchi From carbon dioxide to methane: homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes J Am Chem Soc 128 2006 12362 12363
113. SN Riduan, Y Zhang, and JY. Ying Conversion of carbon dioxide into methanol with silanes over N-heterocyclic carbene catalysts Angew Chem, Int Ed 48 2009 3322 3325
114. D Enders, O Niemeier, and A. Henseler Organocatalysis by N-heterocyclic carbenes Chem Rev 107 2007 5606 5655
115. N Marion, S Diez-Gonzalez, and SP. Nolan N-heterocyclic carbenes as organocatalysts Angew Chem, Int Ed 46 2007 2988 3000
116. K. Zeitler Extending mechanistic routes in heterazolium catalysis - promising concepts for versatile synthetic methods Angew Chem, Int Ed 44 2005 7506 7510
117. J Seayad, PK Patra, Y Zhang, and JY. Ying Organocatalytic synthesis of N-phenylisoxazolidin-5-ones and a one-pot synthesis of β-amino acid esters Org Lett 10 2008 953 956
118. FT Wong, PK Patra, J Seayad, Y Zhang, and JY. Ying N-heterocyclic carbene (NHC)-catalyzed direct amidation of aldehydes with nitroso compounds Org Lett 10 2008 2333 2336
119. Y Zhang, SN Riduan, and JY. Ying Microporous polyisocyanurate and its application in heterogeneous catalysis Chem-Eur J 15 2009 1077 1081
120. G Yong, Y Zhang, and J. Ying Efficient catalytic system for the selective production of 5-hydroxymethylfurfural from glucose and fructose Angew Chem, Int Ed 47 2008 9345 9348
121. HA Duong, TN Tekavec, AM Arif, and J. Louie Reversible carboxylation of N-heterocyclic carbenes Chem Commun 2004 112 113
122. AM Voutchkova, M Feliz, E Clot, O Eisenstein, and RH. Crabtree Imidazolium carboxylates as versatile and selective N-heterocyclic carbene transfer agents: synthesis, mechanism, and applications J Am Chem Soc 129 2007 12834 12846
123. +: application in the synthesis of carboxylates, monomethyl carbonate anions and halogen-free ionic liquids Tetrahedron Lett 46 2005 2141 2145
124. 2 reduction Inorg Chem 49 19 2010 8724 8728
125. J-H Jeoung, and H. Dobbek Carbon dioxide activation at the Ni, Fe-cluster of anaerobic carbon monoxide dehydrogenase Science 318 2007 1461 1464
126. 2/CO interconversions by carboxydothermus hydrogenoformans CO dehydrogenase I on an electrode J Am Chem Soc 129 2007 10328 10329
127. PM Zimmerman, A Paul, Z Zhang, and CB. Musgrave The role of free N-heterocyclic carbene (NHC) in the catalytic dehydrogenation of ammonia borane in the nickel NHC system Angew Chem, Int Ed 48 2009 2201 2205
128. PM Zimmerman, A Paul, and CB. Musgrave Catalytic dehydrogenation of ammonia borane at Ni monocarbene and dicarbene catalysts Inorg Chem 48 2009 5418 5433
129. R Obert, and BC. Dave Enzymatic conversion of carbon dioxide to methanol: enhanced methanol production in silica sol-gel matrices J AM Chem Soc 121 51 2009 12192 12193
130. LM Ellerby, CR Nishida, F Nishida, SA Yamanaka, B Dunn, and JS Valentine Encapsulation of proteins in transparent porous silicate glasses prepared by the sol-gel method Science 255 1992 1113 1115
131. 2) hybrid gel Ind Eng Chem Res 45 2006 4567 4573
132. HJ Freund, and MW. Roberts Surface chemistry of carbon dioxide Surf Sci Reports 25 8 1996 225 273
133. G Centi, and S. Perathoner The role of nanostructure in improving the performance of electrodes for energy storage and conversion Eur J Inorg Chem 2009 26 2009 3851 3878
134. X Pan, Z Fan, W Chen, Y Ding, H Luo, and X. Bao Enhanced ethanol production inside carbon-nanotube reactors containing catalytic particles Nat Mater 6 7 2007 507 511
135. 2/CO ratios Catal Today 98 4 2004 463 484
136. Bell AT. Basic research needs: catalysis for energy. Report from the US Department of Energy, basic energy sciences workshop; 2007. p. 69.
137. KW Frese Jr B.P. Sullivan, K. Krist, H.E. Guard, Electrochemical and electrocatalytic reactions of carbon dioxide 1993 Elsevier Amsterdam 145
138. 2 reduction on metal electrodes. Modern aspects of electrochemistry 2008 Springer New York 89 189
139. 2 to liquid fuels Chem Soc Rev 38 2009 89 99
140. WM. Latimer Oxidation potentials 1952 Prentice-Hall Englewood Cliffs, NJ
141. FR Keene, C Creutz, and N. Sutin Reduction of carbon dioxide by tris(2,2'-bipyridine)cobalt(I) Coord Chem Rev 64 1985 247 260
142. J Lilie, G Beck, and A. Henglein Pulse radiolysis and polarography. Halfwave potentials for the oxidation and reduction of short-lived organic radicals at the mercury electrode Ber Bunsenges Phys Chem 75 1971 458 465
143. S Gambarotta, F Arena, C Floriani, and PF. Zanazzi Carbon dioxide fixation: bifunctional complexes containing acidic and basic sites working as reversible carriers J Am Chem Soc 104 1982 5082 5092
144. A Yamamoto, S Kitazume, LS Pu, and S. Ikeda Synthesis and properties of hydridodinitrogentris(triphenylphosphine)cobalt(I) and the related phosphine-cobalt complexes J Am Chem Soc 93 1971 371 380
145. DA Palmer, and ER. Van The chemistry of metal carbonato and carbon dioxide complexes Chem Rev 83 1983 651 731
146. 2 to methanol over supported and promoted copper-based catalysts: influence of support and promoter Appl Catal B 29 2001 207 215
147. 2 conversion to methanol of gallium-promoted copper-based catalysts: influence of metallic precursors Appl Catal B 34 2001 255 266
148. 2 to methanol reaction Appl Catal A 218 2001 113 119
149. X-M Liu, GQ Lu, and Z-F. Yan Nanocrystalline zirconia as catalyst support in methanol synthesis Appl Catal A 279 2005 241 245
150. 2 Appl Catal A 310 2006 127 137
151. 2 Top Catal 45 2007 57 60
152. 2 catalysts for the hydrogenation of carbon dioxide to methanol Catal Commun 10 2009 1661 1664
153. 2 to methanol Appl Catal A 278 2004 11 23
154. 2 hydrogenation J Catal 271 2010 178 185
155. 2 hydrogenation to methanol catalyst Catal Lett 118 2007 264 269
156. 2 to methanol Appl Catal B 88 2009 315 322
157. 2 Catal Lett 103 2005 83 88
158. 3 catalyst Catal Commun 10 2009 2000 2003
159. GC Chinchen, KC Waugh, and DA. Whan The activity and state of the copper surface in methanol synthesis catalysts Appl Catal 25 1 and 2 1986 101 107
160. GC Chinchen, MS Spencer, KC Waugh, and DA. Whan Promotion of methanol synthesis and the water-gas shift reactions by adsorbed oxygen on supported copper catalysts J Chem Soc Faraday Trans 1: Phys Chem Condens Phases 83 7 1987 2193 2212
161. O-S Joo, K-D Jung, I Moon, AY Rozovskii, GI Lin, and S-H Han Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE Process) Ind Eng Chem Res 38 5 1999 1808 1812
162. 2-rich feed and from a CO-rich feed Appl Catal A: Gen 218 1-2 2001 235 240
163. M Saito, and K. Murata Development of high performance Cu/ZnO-based catalysts for methanol synthesis and the water-gas shift reaction Catal Surv Asia 8 4 2004 285 294
164. JCJ Bart, and RPA. Sneeden Copper-zinc oxide-alumina methanol catalysts revisited Catal Today 2 1987 1 124
165. GC Chinchen, PJ Denny, JR Jennings, MS Spencer, and KC. Waugh Synthesis of methanol. Part 1. Catalysts and kinetics Appl Catal 36 1988 1 65
166. GJ Millar, CH Rochester, and KC. Waugh An in situ high pressure FT-IR study of carbon dioxide/hydrogen interactions with model zinc oxide/silica, copper/silica and copper/zinc oxide/silica methanol synthesis catalysts Catal Lett 14 1992 289 295
167. 2 Ind Eng Chem Res 42 25 2003 6518 6530
168. WX Pan, R Cao, DL Roberts, and GL. Griffin Methanol synthesis activity of copper/zinc oxide catalysts J Catal 114 1988 440 446
169. 2 Catal Lett 26 3 1994 373 381
170. 2 on Cu(100) Surf Sci 318 3 1994 267 280
171. TS Askgaard, JK Norskov, CV Ovesen, and P. Stoltze A kinetic model of methanol synthesis J Catal 156 2 1995 229 242
172. 2. Comparison of various preparation methods Appl Catal A: Gen 139 1 1996 75 85
173. 3 catalysts J Catal 56 3 1979 407 429
174. J Szanyi, and DW. Goodman Methanol synthesis on a copper(100) catalyst Catal Lett 1991 383 390
175. S Bailey, GF Froment, JW Snoeck, and KC Waugh A DRIFTS study of the morphology and surface adsorbate composition of an operating methanol synthesis catalyst Catal Lett 30 1 1994 99 111
176. 2: IV. The effects of carbon dioxide J Catal 74 2 1982 343 360
177. J Nakamura, Y Choi, and T. Fujitani On the issue of the active site and the role of ZnO in Cu/ZnO methanol synthesis catalysts Top Catal 22 3 2003 277 285
178. Y Choi, K Futagami, T Fujitani, and J. Nakamura The role of ZnO in Cu/ZnO methanol synthesis catalysts - morphology effect or active site model? Appl Catal A: Gen 208 1and 2 2001 163 167
179. MV Twigg, and MS. Spencer Deactivation of supported copper metal catalysts for hydrogenation reactions Appl Catal A: Gen 212 1 and 2 2001 161 174
180. 2-based methanol plant. Chem Week; March 2010.
181. P Braunstein, D Matt, and D. Nobel Reactions of carbon dioxide with carbon-carbon bond formation catalyzed by transition-metal complexes Chem Rev 88 1988 747 764
182. 2 Electrochem Commun 3 2001 762 766
183. 2 anion-radical in organic carboxylations Tetrahedron Lett 47 2006 2171 2173
184. M Tokuda, T Kabuki, Y Katoh, and H. Suginome Regioselective synthesis of β,γ-unsaturated acids by the electrochemical carboxylation of allylic bromides using a reactive-metal anode Tetrahedron Lett 36 1995 3345 3348
185. H Kamekawa, H Senboku, and M. Tokuda Facile synthesis of aryl-substituted 2-alkenoic acids by electroreductive carboxylation of vinylic bromides using a magnesium anode Electrochim Acta 42 1997 2117 2123
186. H Senboku, Y Fujimura, H Kamekawa, and M. Tokuda Divergent electrochemical carboxylation of vinyl triflates: new electrochemical synthesis of phenyl-substituted α,β-unsaturated carboxylic acids and aliphatic β-keto carboxylic acids Electrochim Acta 45 2000 2995 3003
187. G Silvestri, S Gambino, and G. Filardo Use of sacrificial anodes in synthetic electrochemistry. Processes involving carbon dioxide Acta Chem Scand 45 1991 987 992
188. VG Koshechko, VE Titov, and VA. Lopushanskaya Electrochemical carboxylation of benzoyl bromide as effective phenylglyoxylic acid synthesis route Electrochem Commun 4 2002 655 658
189. RR Ramesh, MS Krishna, and RS. Jayarama Electroorganic synthesis of 6-aminonicotinic acid from 2-amino-5-chloropyridine Tetrahedron Lett 44 2003 4133 4135
190. 1-synthon Appl Organomet Chem 15 2001 135 140
191. 2 into terminal alkynes and diynes Eur J Org Chem 2001 2507 2511
192. H Yang, Y Gu, Y Deng, and F. Shi Electrochemical activation of carbon dioxide in ionic liquids: synthesis of cyclic carbonates under mild reaction conditions Chem Commun 2002 274 275
193. S Lee Methanol-to-gasoline vs. DME-to-gasoline. II. Process comparison and analysis Fuel Energy Abst 36 6 1995 414
194. M Jayamurthy, and S. Vasudevan Methanol-to-gasoline(MTG)conversion over ZSM-5. A temperature programmed surface reaction study Catal Lett 36 1 and 2 1996 111 114
195. AJ. Dean Lange's handbook of chemistry 13th ed. 6-2 1985 McGraw-Hill New York 9 4-9-107
196. 2 reduction on metal electrodes. Modern aspects of electrochemistry 2008 Springer New York 89 189
197. A Murata, and Y. Hori Electrochemical reduction of carbon dioxide to carbon monoxide at nickel electrodes modified with cadmium Chem Lett 1991 181 184
198. Y Hori, A Murata, and S. Ito Enhanced evolution of carbon monoxide and suppressed formation of hydrocarbons in electroreduction of carbon dioxide at a copper electrode modified with cadmium Chem Lett 1990 1231 1234
199. Y Hori, A Murata, SY Ito, Y Yoshinami, and O. Koga Nickel and iron modified copper electrode for electroreduction of carbon dioxide by in-situ electrodeposition Chem Lett 1989 1567 1570
200. Y Hori, K Kikuchi, A Murata, and S. Suzuki Production of methane and ethylene in electrochemical reduction of carbon dioxide at copper electrode in aqueous hydrogen carbonate solution Chem Lett 1986 897 898
201. Y Hori, K Kikuchi, and S. Suzuki Production of carbon monoxide and methane in electrochemical reduction of carbon dioxide at metal electrodes in aqueous hydrogen carbonate solution Chem Lett 1985 1695 1698
202. 2 reduction J Electrochem Soc 138 11 1991 3382 3389
203. 2 reduction J Electrochem Soc 141 8 1994 2054 2058
204. RL Cook, RC MacDuff, and AF. Sammells On the electrochemical reduction of carbon dioxide at in situ electrodeposited copper J Electrochem Soc 135 6 1988 1320 1326
205. Lynch FE, Marmaro RW. Special purpose blends of hydrogen and natural gas; 1992. USA: Hydrogen Consultants, Inc. 30 pp.
206. Lynch FE. Metal hydrides: the missing link in automotive hydrogen technology. In: 1975 NTIS; 1975. p. 408-421.
207. MN Mahmood, D Masheder, and CJ. Harty Use of gas-diffusion electrodes for high-rate electrochemical reduction of carbon dioxide. I. Reduction at lead, indium- and tin-impregnated electrodes J Appl Electrochem 17 1987 1159 1170
208. S Kapusta, and N. Hackerman The electroreduction of carbon dioxide and formic acid on tin and indium electrodes J Electrochem Soc 130 3 1983 607 613
209. K Hara, A Kudo, and T. Sakata Electrochemical reduction of carbon dioxide under high pressure on various electrodes in an aqueous electrolyte J Electroanal Chem 391 1 and 2 1995 141 147
210. 2 reduction at gas-diffusion electrodes J Electroanal Chem 431 1 1997 39 41
211. Frese KW Jr, Leach SC, Summers DP. Electrochemical reduction of aqueous carbon dioxide to methanol. US patent no. 4,609,441; 2 September 1986.
212. Hussain ST, Muhammad MM, Rehman HU. Novel process and catalyst for carbon dioxide conversion to energy generating products. US patent 2007. Application number: 11/751,026 (May 20): Publication number: US 2008/0287555 A0287551.
213. A Coehn, and S. Jahn Electrolytic reduction of carbon dioxide Ber Dtsch Chem Ges 1904 37
214. F Fischer, and O. Prziza Electrolytic reduction of carbon oxides dissolved under pressure Ber Dtsch Chem Ges 1914 47
215. TE Teeter, and PV. Rysselberghe Reduction of carbon dioxide on mercury cathodes J Chem Phys 1954 22
216. W Paik, TN Andersen, and H. Eyring Kinetic studies of electrolytic reduction of carbon dioxide on mercury electrode Electrochim Acta 14 12 1969 1217 1232
217. KS Udupa, GS Subramanian, and HVK. Udupa Electrolytic reduction of carbon dioxide to formic acid Electrochim Acta 16 9 1971 1593
218. PG Russell, N Kovac, S Srinivasan, and M. Steinberg Electrochemical reduction of carbon dioxide, formic acid, and formaldehyde J Electrochem Soc 124 9 1977 1329 1338
219. D Canfield, and KW Frese Jr Reduction of carbon dioxide to methanol on n-GaAs and p-GaAs and p-InP. Effect of crystal face, electrolyte and current density J Electrochem Soc 130 8 1983 1772 1773
220. KW Frese, and S Leach Jr Electrochemical reduction of carbon dioxide to methane, methanol, and CO on Ru electrodes J Electrochem Soc 132 1 1985 259 260
221. DP Summers, S Leach, and KW Frese Jr The electrochemical reduction of aqueous carbon dioxide to methanol at molybdenum electrodes with low overpotentials J Electroanal Chem 205 1 and 2 1986 219 232
222. Y Hori, and S Suzuki Electrolytic reduction of carbon dioxide at mercury electrode in aqueous solution Bull Chem Soc Jpn 55 1982 660 665
223. Y Hori, and A Murata Electrochemical evidence of intermediate formation of adsorbed carbon monoxide in cathodic reduction of carbon dioxide at a nickel electrode Electrochim Acta 35 1990 1777 1780
224. 2 formation on Pt single crystal electrodes in sulfuric acid solution Electrochim Acta 39 17 1994 2533 2537
225. 2 at metal electrodes in aqueous media Electrochim Acta 39 11 and 12 1994 1833 18339
226. 3 media J Electrochem Soc 137 6 1990 1772 1778
227. H Kita, and T. Kurisu Electrocatalysis by d- and sp-metals J Res Inst Catal, Hokkaido Univ 21 3 1973 200 246
228. 2 in a gas-diffusion electrode-based electrolytic cell Electrochim Acta 47 2002 3327 3334
229. 2 production/oxidation Acc Chem Res 42 12 2009 1974 1982
230. 2 to fuel. In: Proceedings of the fourth international conference on greenhouse gas control technology, Interlaken, Switzerland; 30 August-2 September 1998.
231. M. Halmann Photoelectrochemical reduction of aqueous carbon-dioxide on p-type gallium-phosphide in liquid junction solar-cells Nature 275 1978 115
232. BR Eggins, EM Brown, EA McNeill, and J. Grimshaw Carbon dioxide fixation by electrochemical reduction in water to oxalate and glyoxylate Tetrahedron Lett 29 8 1988 945 948
233. Bell AT. Basic research needs: catalysis for energy. Report from the US Department of Energy. Basic energy sciences workshop; 2007. p. 69.
234. 2O reduction at room temperature J Electrochem Soc 155 2007 B42 B49
235. A. Bandi Electrochemical reduction of carbon dioxide on conductive metallic oxides J Electrochem Soc 137 7 1990 2157 2160
236. 3 J Electroanal Chem 421 1997 105 110
237. N Spataru, K Tokuhiro, C Terashima, TN Rao, and A. Fujishima Electrochemical reduction of carbon dioxide at ruthenium dioxide deposited on boron-doped diamond J Appl Electrochem 33 2003 1205 1210
238. 2 nanotubes composite modified Pt electrode Electrochim Acta 50 2005 3576 3580
239. 2 at intentionally oxidized copper electrodes J Electrochem Soc 138 11 1991 3338 3344
240. JJ Kim, DP Summers, and KW Frese Jr Reduction of carbon dioxide and carbon monoxide to methane on copper foil electrodes J Electroanal Chem Interfacial Electrochem 245 1988 223 244
241. O Koga, K Nakama, A Murata, and Y. Hori Effects of surface state of copper electrode on the selectivity of electrochemical reduction of carbon dioxide Denki Kagaku Oyobi Kogyo Butsuri Kagaku 57 1989 1137 1140
242. G Kyriacou, and A. Anagnostopoulos Electroreduction of carbon dioxide on differently prepared copper electrodes. The influence of electrode treatment on the current efficiencies J Electroanal Chem Interfacial Electrochem 322 1992 233 246
243. 2 reduction by adsorption of sulfide ion on metal electrodes J Electroanal Chem 434 1997 239 243
244. 2 reduction on a glassy carbon electrode under high pressure J Electroanal Chem 421 1997 1 4
245. BRW Pinsent, L Pearson, and FJW Roughton The kinetics of combination of carbon dioxide with hydroxide ions Trans Faraday Soc 52 1956 1512 1520
246. K Ogura, and M. Fujita Electrocatalytic reduction of carbon dioxide to methanol. Part 7. With quinone derivatives immobilized on platinum and stainless steel J Mol Catal 41 1987 303 311
247. K Ogura, and K. Takamagari Electrocatalytic reduction of carbon dioxide to methanol. Part 2. Effects of metal complex and primary alcohol J Chem Soc, Dalton Trans 8 1986 1519 1523
248. K Ogura, and S. Yamasaki Conversion of carbon monoxide into methanol at room temperature and atmospheric pressure J Chem Soc, Faraday Trans 1 81 1985 267 271
249. VD. Neff Electrochemical oxidation and reduction of thin films of Prussian blue J Electrochem Soc 125 1978 886 887
250. K Ogura, and K. Takamagari Electrocatalytic reduction of carbon dioxide to methanol. Part 2. Effects of metal complex and primary alcohol J Chem Soc, Dalton Trans 1986 1519 1523
251. 2 electrochemical reduction via adsorbed halide anions JOM 63 2011 35 38
252. K. Ogura Carbon dioxide fixation and catalysts Hyomen 29 1991 945 954
253. K. Ogura Fixation of carbon dioxide by electrolytic reduction Kagaku (Kyoto) 46 1991 307 309
254. K Ogura, and I. Yoshida Electrocatalytic reduction of carbon dioxide to methanol. Part 9. Mediation with metal porphyrins J Mol Catal 47 1988 51 57
255. K Ogura, and I. Yoshida Electrocatalytic reduction of carbon dioxide to methanol - VI. Use of a solar cell and comparison with that of carbon monoxide Electrochim Acta 32 1987 1191 1195
256. Ogura K, Yamasaki S. Selective conversion of carbon monoxide into methanol at ordinary temperature. Part 4. Activation by iron (II), iron (III), and chromium (III) complexes. J Chem Soc, Dalton Trans 1985: 2499-504.
257. K Ogura, and H. Uchida Electrocatalytic reduction of carbon dioxide to methanol. Part VIII. Photoassisted electrolysis and electrochemical photocell with n-titanium dioxide anode J Electroanal Chem Interfacial Electrochem 220 1987 333 337
258. K Ogura, and H. Uchida Electrocatalytic reduction of carbon dioxide to methanol. Part 5. Relationship between the ability of metal complexes to engage in homogeneous catalysis and their coordination chemistry. J Chem Soc, Dalton Trans 1987 1377 1380
259. Ogura K, Takagi M. Electrocatalytic reduction of carbon monoxide with a photocell. J Electroanal Chem Interfacial Electrochem 1985;195(2):357-62.
260. K. Ogura Catalytic conversion of carbon monoxide and carbon dioxide into methanol with an electrochemical photocell and a solar cell Proc - Electrochem Soc 86 and 87 1986 591 605
261. K Ogura, and M. Takagi Electrocatalytic reduction of carbon dioxide to methanol. Part IV. Assessment of the current-potential curves leading to reduction J Electroanal Chem Interfacial Electrochem 206 1986 209 216
262. K Ogura, and M. Takagi Electrocatalytic reduction of carbon dioxide to methanol. Part III. Use of an electrochemical photocell J Electroanal Chem Interfacial Electrochem 201 1986 359 365
263. K Ogura, and I. Yoshida Electrocatalytic reduction of carbon dioxide to methanol in the presence of (1,2-dihydroxybenzene-3,5-disulfonato)ferrate(III) and ethanol J Mol Catal 34 1986 67 72
264. G Seshadri, C Lin, and AB. Bocarsly A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential J Electroanal Chem 372 1 and 2 1994 145 150
265. R Raghavan, and RT Iwamoto Characterization of the dimeric one-electron electrolytic reduction products of 1-alkylpyridinium ions in acetonitrile J Electroanal Chem Interfacial Electrochem 92 1978 101 114
266. H Baumgartel, and KJ. Retzlav Encyclopedia of electrochemistry of the elements A.J. Bard, H. Lund, Derivatives of ammonia, heteroaromatic compounds 12 1984 Dekker New York 168
267. K Yasukouchi, I Taniguchi, H Yamaguchi, and M. Shiraishi Cathodic reduction of pyridinium ion in acetonitrile J Electroanal Chem Interfacial Electrochem 105 1979 403 408
268. A Bandi, and HM. Kühne Electrochemical reduction of carbon dioxide in water: analysis of reaction mechanism on ruthenium-titanium-oxide J Electrochem Soc 139 6 1992 1605 1610
269. M Schwartz, RL Cook, VM Kehoe, RC MacDuff, J Patel, and AF. Sammells Carbon dioxide reduction to alcohols using perovskite-type electrocatalysts J Electrochem Soc 140 1993 614 618
270. BA Parkinson, and PF. Weaver Photoelectrochemical pumping of enzymic carbon dioxide reduction Nature 309 1984 148 149
271. AM Klibanov, BN Alberti, and SE. Zale Enzymic synthesis of formic acid from hydrogen and carbon dioxide and production of hydrogen from formic acid Biotechnol Bioeng 24 1982 25 36
272. CJ Stalder, S Chao, and MS. Wrighton Electrochemical reduction of aqueous bicarbonate to formate with high current efficiency near the thermodynamic potential at chemically derivatized electrodes J Am Chem Soc 106 1984 3673 3675
273. TR O'Toole, BP Sullivan, MRM Bruce, LD Margerum, RW Murray, and TJ. Meyer Electrocatalytic reduction of carbon dioxide by a complex of rhenium in thin polymeric films J Electroanal Chem Interfacial Electrochem 259 1989 217 239
274. BP. Sullivan Reduction of carbon dioxide with platinum metals electrocatalysts. A potentially important route for the future production of fuels and chemicals Platinum Met Rev 33 1989 2 9
275. BP Sullivan, CM Bolinger, D Conrad, WJ Vining, and TJ. Meyer One- and two-electron pathways in the electrocatalytic reduction of carbon dioxide by fac-(2,2'-bipyridine)tricarbonylchlororhenium J Chem Soc, Chem Commun 1985 1414 1416
276. CM Bolinger, BP Sullivan, D Conrad, JA Gilbert, N Story, and TJ. Meyer Electrocatalytic reduction of carbon dioxide based on polypyridyl complexes of rhodium and ruthenium J Chem Soc, Chem Commun 1985 796 797
277. B Beden, A Bewick, M Razaq, and J. Weber On the nature of reduced carbon dioxide an IR spectroscopic investigation J Electroanal Chem Interfacial Electrochem 139 1982 203 206
278. 2 radical anion and methyl radical Faraday Discuss Chem Soc 56 1973 75 95
279. Frank AJ. Organic conductive films for semiconductor electrodes; 1984. USA: United States Department of Energy. 31 pp. Avail. NTIS order no. PAT-APPL-36-465 418.
280. Williams RM, Rembaum A. Photoelectrochemical electrodes. USA: United States National Aeronautics and Space Administration; 1983. 29 pp. Avail. NTIS order no. PAT-APPL-26-376 306.
281. Jensen RJ, Lyman JL, King JD, Guettler RD. Solar reduction of carbon dioxide, USA; 2000. 11 pp.
282. K Ohashi, J McCann, and JO. Bockris Stable photoelectrochemical cells for the splitting of water Nature 266 1977 610 611
283. R Bhardwaj, RL Pan, and EL. Gross Solar energy conversion by chloroplast photoelectrochemical cells Nature 289 1981 396 398
284. AJ. Nozik Energetics of photoelectrolysis Proc - Electrochem Soc 77-3 1977 272 289
285. Nozik AJ. Photoelectrolysis cell for manufacturing hydrogen using solar energy; 1978. USA: Allied Chemical Corp.; 34 pp. Addn. to Ger. Offen. 32,650,267.
286. F Williams, and AJ. Nozik Irreversibilities in the mechanism of photoelectrolysis Nature 271 1978 137 139
287. AJ. Nozik Electrode materials for photoelectrochemical devices J Cryst Growth 39 1977 200 209
288. AJ. Nozik Photochemical diodes Appl Phys Lett 30 1977 567 569
289. Nozik AJ. Hydrogen generation by the photoelectrolysis of water, vol. 5B. University of Miami; 1976. p. 31-54.
290. Nozik AJ. Energy conversion via photoelectrolysis. In: Proceedings of the Intersociety Energy Conversion Engineering Conference, vol. 11, no. (1); 1976. p. 43-50.
291. Nozik AJ. Photoelectrolysis of water by solar radiation. USA: Allied Chemical Corp.; 1977. 10 pp.
292. AJ. Nozik p-n Photoelectrolysis cells Appl Phys Lett 29 1976 150 153
293. AJ. Nozik Photoelectrolysis of water using semiconducting titanium dioxide crystals Nature 257 1975 383 386
294. AJ Esswein, and DG. Nocera Hydrogen production by molecular photocatalysis Chem Rev 107 10 2007 4022 4047
295. 2 pellets Catal Today 115 1-4 2006 269 273
296. M Tomkiewicz, and JM. Woodall Photoassisted electrolysis of water by visible irradiation of a p-type gallium phosphide electrode Science 196 1977 990 991
297. H. Gerischer Electrochemical photo and solar cells principles and some experiments J Electroanal Chem Interfacial Electrochem 58 1 1975 263 274
298. KW Frese Jr, and D. Canfield Reduction of carbon dioxide on n-gallium arsenide electrodes and selective methanol synthesis J Electrochem Soc 131 1984 2518 2522
299. AJ Bard, and MS. Wrighton Thermodynamic potential for the anodic dissolution of n-type semiconductors. A crucial factor controlling durability and efficiency in photoelectrochemical cells and an important criterion in the selection of new electrode/electrolyte systems J Electrochem Soc 124 1977 1706 1710
300. T Inoue, A Fujishima, S Konishi, and K. Honda Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders Nature 277 5698 1979 637 638
301. 2 by photoreduction on cadmium sulphide J Chem Soc Chem Commun 1988 1123 1124
302. 3OH medium at p-type semiconductor electrodes J Phys Chem B 102 1998 9834 9843
303. B Aurian-Blajeni, M Halmann, and J. Manassen Electrochemical measurements on the photoelectrochemical reduction of aqueous carbon dioxide on p-gallium phosphide and p-gallium arsenide semiconductor electrodes Sol Energy Mater 8 1983 425 440
304. 2 evolution in the presence of ruthenium and osmium colloids: strategies to design selectivity of products distribution J Am Chem Soc 109 1987 6080 6086
305. 4 in aqueous solutions using visible light J Am Chem Soc 108 1986 8100 8101
306. JM Lehn, and R. Ziessel Photochemical generation of carbon monoxide and hydrogen by reduction of carbon dioxide and water under visible light irradiation Proc Natl Acad Sci USA 79 2 1982 701 704
307. 2 to methanol using a catalyzed p-GaP based photoelectrochemical cell J Am Chem Soc 130 2008 6342 6344
308. 2 to methanol: kinetic, mechanistic, and structural insights J Am Chem Soc 132 33 2010 11539 11551
309. WM. Grant Colorimetric microdetermination of formic acid based on reduction to formaldehyde Anal Chem 20 1948 267 269
310. 2 materials for solar light induced current and photocatalytic applications Mater Chem Phys 135 1 2012 220 234
311. I. Ganesh Conversion of carbon dioxide to methanol using solar energy Curr Sci 101 6 2011 731 733
312. 2 powders for solar light response and photocatalytic applications Process Appl Ceram 6 2012 21 36
313. I Ganesh, PSC Sekhar, G Padmanabham, and G. Sundararajan Influence of Li-doping on structural characteristics and photocatalytic activity of ZnO nano-powder formed in a novel solution pyro-hydrolysis route Appl Surf Sci 259 2012 524 537
314. 2 suspension mixed with copper powder J Photochem Photobiol A: Chem 64 2 1992 255 258
315. 2 (111) crystal face to form methane Cheml Phys Lett 57 1 1978 100 104
316. 2 using sol-gel derived titania and titania-supported copper catalysts Appl Catal B: Environ 37 1 2002 37 48
317. 2 to methanol using optical-fiber photoreactor Appl Catal A: Gen 296 2 2005 194 200
318. H Nakatsuji, and ZM. Hu Mechanism of methanol synthesis on Cu(100) and Zn/Cu(100) surfaces: Comparative dipped adcluster model study Int J Quant Chem 77 1 2010 341 349
319. Nasution HW Slamet, E Purnama, K Riyani, and J. Gunlazuardi Effect of copper species in a photocatalytic synthesis of methanol from carbon dioxide over copper-doped titania catalysts World Appl Sci J 6 2009 1
320. T Fujitani, and J. Nakamura The chemical modification seen in the Cu/ZnO methanol synthesis catalysts Appl Catal A: Gen 191 1 and 2 2000 111 129
321. 2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(000(1)over-bar) Phys Chem Chem Phys 12 33 2010 9909 9917
322. 2 to useful chemicals by room temperature photoelectrocatalysis Catal Today 27 1996 271 277
323. S Sakka, K Kamiya, K Makita, and Y. Yamamoto Formation of sheets and coating films from alkoxide solutions J Non-Crystal Solids 63 1 and 2 1984 223 235
324. 2 on copper electrodes J Electrochem Soc 140 1993 3479 3482
325. 2 to fuel: first prototype results Ind Eng Chem Res 41 8 2002 1935 1939
326. 2 photocatalyst Int J Photoenergy 7 2005 115 119
327. 2 reduction Int J Hydrogen Energy 37 13 2012 9967 9976
328. 2 reduction mediated by a supramolecular electrode of packed Co II (tetrabenzoporphyrin) Inorg Chim Acta 362 2009 5 10
329. 2 towards methanol. In: IOP conference series: materials science and engineering; 2011. p. 19: 012010/012011-012010/012017.
330. 2 into renewable hydrocarbon fuel J Am Chem Soc 132 2010 14385 14387
331. 2 by modification with small metal particles J Phys Chem B 102 1998 974 980
332. 2 with semiconductor colloids J Photochem Photobiol A: Chem 118 1998 31 40
333. AWB Aylmer-Kelly, A Bewick, PR Cantrill, and AM. Tuxford Studies of electrochemically generated reaction intermediates using modulated specular reflectance spectroscopy Faraday Discuss Chem Soc 56 1973 96 107
334. E Lamy, L Nadjo, and JM. Saveant Standard potential and kinetic parameters of the electrochemical reduction of carbon dioxide in dimethylformamide J Electroanal Chem Interfacial Electrochem 78 1977 403 407
335. DA Tyssee, JH Wagenknecht, MM Baizer, and JL. Chruma Cathodic organic syntheses involving carbon dioxide Tetrahedron Lett 1972 4809 4812
336. EM Bennett, BR Eggins, J McNeill, and EA. McMullan Recycling carbon dioxide from fossil fuel combustion Anal Proc (Lond) 17 1980 356 358
337. BR Eggins, EM Brown, EA McNeill, and J. Grimshaw Carbon dioxide fixation by electrochemical reduction in water to oxalate and glyoxylate Tetrahedron Lett 29 1988 945 948
338. A Bewick, and GP. Greener Electroreduction of carbon dioxide to malate on a mercury cathode Tetrahedron Lett 1969 4623 4626
339. BR Eggins, C Ennis, R McConnell, and M. Spence Improved yields of oxalate, glyoxylate and glycolate from the electrochemical reduction of carbon dioxide in methanol J Appl Electrochem 27 1997 706 712
340. A Bewick, and GP. Greener Electroreduction of carbon dioxide to glycollate on a lead cathode Tetrahedron Lett 1970 391 394
341. BR Eggins, EM Bennett, and EA. McMullan Voltammetry of carbon dioxide. Part 2. Voltammetry in aqueous solutions on glassy carbon J Electroanal Chem 1996 165 171
342. 2O vapor to hydrocarbon fuels Nano Lett 9 2 2009 731 737
343. 2 nanotube arrays to 134 μm in length J Phys Chem B 110 33 2006 16179 16184
344. J. Barber Biological solar energy Philos Trans A Math Phys Eng Sci 365 1853 2007 1007 1023
345. T Bak, J Nowotny, M Rekas, and CC Sorrell Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects Int J Hydrogen Energy 27 2002 991 1022
346. X Chen, S Shen, L Guo, and SS. Mao Semiconductor-based photocatalytic hydrogen generation Chem Rev 110 11 2010 6503 6570
347. K. Rajeshwar Hydrogen generation at irradiated oxide semiconductor- solution interfaces J Appl Electrochem 37 7 2007 765 787
348. J Nowotny, T Bak, MK Nowotny, and LR. Sheppard Titanium dioxide for solar-hydrogen I. Functional properties Int J Hydrogen Energy 32 14 2007 2609 2629
349. A. Steinfeld Solar thermochemical production of hydrogen - a review Solar Energy 78 5 2005 603 615
350. T Kodama, and N. Gokon Thermochemical cycles for high-temperature solar hydrogen production ChemInform 38 2007 51
351. S Somasundaram, C Raman Nair Chenthamarakshan, NR de Tacconi, and K. Rajeshwar Photocatalytic production of hydrogen from electrodeposited film and sacrificial electron donors Int J Hydrogen Energy 32 18 2007 4661 4669
352. 2 in the presence of sacrificial reagents Energy Fuels 19 3 2005 1143 1147
353. NA Kelly, and TL. Gibson Solar energy concentrating reactors for hydrogen production by photoelectrochemical water splitting Int J Hydrogen Energy 33 22 2008 6420 6431
354. MG Walter, EL Warren, JR McKone, SW Boettcher, Q Mi, and EA Santori Solar water splitting cells Chem Rev 110 11 2010 6446 6473
355. H Lv, YV Geletii, C Zhao, JW Vickers, G Zhu, and Z Luo Polyoxometalate water oxidation catalysts and the production of green fuel Chem Soc Rev 41 2012 7572 7589
356. JJ Concepcion, JW Jurss, MK Brennaman, PG Hoertz, Patrocinio AOvT, and NY Murakami Iha Making oxygen with ruthenium complexes Acc Chem Res 42 12 2009 1954 1965
357. BRW Pinsent, L Pearson, and FJW. Roughton The kinetics of combination of carbon dioxide with hydroxide ions Trans Faraday Soc 52 1956 1512 1520