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Volumn 110, Issue , 2013, Pages 772-779

Variable temperature study of electro-reduction of 3-nitrophenolate via cyclic and square wave voltammetry: Molecular insights into electron transfer processes based on the asymmetric Marcus-Hush model

Author keywords

Adiabaticity; Asymmetric Marcus Hush model; Reorganization energy; Variable temperature experiments

Indexed keywords

ADIABATICITY; ASYMMETRIC MARCUS-HUSH MODELS; ELECTROACTIVE SPECIES; ELECTRON TRANSFER PROCESS; REORGANIZATION ENERGIES; SQUARE WAVE VOLTAMMETRY; VARIABLE TEMPERATURE; VARIABLE TEMPERATURE STUDIES;

EID: 84888304648     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2012.12.129     Document Type: Article
Times cited : (11)

References (47)
  • 6
    • 0010884753 scopus 로고
    • On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer
    • R.A. Marcus On the Theory of Oxidation-Reduction Reactions Involving Electron Transfer. I Journal of Chemical Physics 24 1956 966
    • (1956) I Journal of Chemical Physics , vol.24 , pp. 966
    • Marcus, R.A.1
  • 7
    • 36849118773 scopus 로고
    • On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions
    • R.A. Marcus On the Theory of Electron-Transfer Reactions. VI. Unified Treatment for Homogeneous and Electrode Reactions Journal of Chemical Physics 43 1965 679
    • (1965) Journal of Chemical Physics , vol.43 , pp. 679
    • Marcus, R.A.1
  • 8
    • 0026108980 scopus 로고
    • Free energy and temperature dependence of electron transfer at the metal-electrolyte interface
    • C.E.D. Chidsey Free energy and temperature dependence of electron transfer at the metal-electrolyte interface Science 215 1991 919
    • (1991) Science , vol.215 , pp. 919
    • Chidsey, C.E.D.1
  • 9
    • 77953568058 scopus 로고    scopus 로고
    • Implications of Marcus-Hush Theory for Steady-State Heterogeneous Electron Transfer at an Inlaid Disk Electrode
    • S.W. Feldberg Implications of Marcus-Hush Theory for Steady-State Heterogeneous Electron Transfer at an Inlaid Disk Electrode Analytical Chemistry 82 2010 5176
    • (2010) Analytical Chemistry , vol.82 , pp. 5176
    • Feldberg, S.W.1
  • 10
    • 0001148682 scopus 로고
    • The driving-force dependence of electrochemical rate parameters: Origins of anodic-cathodic asymmetries for metal-aquo redox couples
    • J.T. Hupp, and M.J. Weaver The driving-force dependence of electrochemical rate parameters: origins of anodic-cathodic asymmetries for metal-aquo redox couples Journal of Physical Chemistry 88 1984 6128
    • (1984) Journal of Physical Chemistry , vol.88 , pp. 6128
    • Hupp, J.T.1    Weaver, M.J.2
  • 11
    • 1242333135 scopus 로고    scopus 로고
    • Proton-Coupled Electron Transfer of an Osmium Aquo Complex on a Self-Assembled Monolayer on Gold
    • R.M. Haddox, and H.O. Finklea Proton-Coupled Electron Transfer of an Osmium Aquo Complex on a Self-Assembled Monolayer on Gold Journal of Physical Chemistry B 108 2004 1694
    • (2004) Journal of Physical Chemistry B , vol.108 , pp. 1694
    • Haddox, R.M.1    Finklea, H.O.2
  • 12
    • 33846015028 scopus 로고    scopus 로고
    • Potential-, pH-, and Isotope-Dependence of Proton-Coupled Electron Transfer of an Osmium Aquo Complex Attached to an Electrode
    • N. Madhiri, and H.O. Finklea Potential-, pH-, and Isotope-Dependence of Proton-Coupled Electron Transfer of an Osmium Aquo Complex Attached to an Electrode Langmuir 22 2006 10643
    • (2006) Langmuir , vol.22 , pp. 10643
    • Madhiri, N.1    Finklea, H.O.2
  • 13
    • 33644683036 scopus 로고    scopus 로고
    • Evaluation of electron transfer rates in peptide films: Simplified calculation and theory
    • G.A. Orlowski, and H.-B. Kraatz Evaluation of electron transfer rates in peptide films: Simplified calculation and theory Electrochimica Acta 51 2006 2934
    • (2006) Electrochimica Acta , vol.51 , pp. 2934
    • Orlowski, G.A.1    Kraatz, H.-B.2
  • 14
    • 37249087568 scopus 로고    scopus 로고
    • Reorganization Energies of Ferrocene-Peptide Monolayers
    • G.A. Orlowski, S. Chowdhury, and H.-B. Kraatz Reorganization Energies of Ferrocene-Peptide Monolayers Langmuir 23 2007 12765
    • (2007) Langmuir , vol.23 , pp. 12765
    • Orlowski, G.A.1    Chowdhury, S.2    Kraatz, H.-B.3
  • 15
    • 77149156959 scopus 로고    scopus 로고
    • Kinetic Dispersion in Redox-Active Dithiocarbamate Monolayers
    • A.L. Eckermann, J.A. Shaw, and T.J. Meade Kinetic Dispersion in Redox-Active Dithiocarbamate Monolayers Langmuir 26 2010 2904
    • (2010) Langmuir , vol.26 , pp. 2904
    • Eckermann, A.L.1    Shaw, J.A.2    Meade, T.J.3
  • 16
    • 79961077055 scopus 로고    scopus 로고
    • Experimental Comparison of the Marcus-Hush and Butler-Volmer Descriptions of Electrode Kinetics.The One-Electron Oxidation of 9,10-Diphenylanthracene and One-Electron Reduction of 2-Nitropropane Studied at High-Speed Channel Microband Electrodes
    • D. Suwatchara, M.C. Henstridge, N.V. Rees, and R.G. Compton Experimental Comparison of the Marcus-Hush and Butler-Volmer Descriptions of Electrode Kinetics. The One-Electron Oxidation of 9,10-Diphenylanthracene and One-Electron Reduction of 2-Nitropropane Studied at High-Speed Channel Microband Electrodes Journal of Physical Chemistry C 115 2011 14876
    • (2011) Journal of Physical Chemistry C , vol.115 , pp. 14876
    • Suwatchara, D.1    Henstridge, M.C.2    Rees, N.V.3    Compton, R.G.4
  • 17
    • 81855204928 scopus 로고    scopus 로고
    • An experimental comparison of the Marcus-Hush and Butler-Volmer descriptions of electrode kinetics applied to cyclic voltammetry.The one electron reductions of europium (III) and 2-methyl-2-nitropropane studied at a mercury microhemisphere electrode
    • M.C. Henstridge, Y. Wang, J.G. Limon-Petersen, E. Laborda, and R.G. Compton An experimental comparison of the Marcus-Hush and Butler-Volmer descriptions of electrode kinetics applied to cyclic voltammetry. The one electron reductions of europium (III) and 2-methyl-2-nitropropane studied at a mercury microhemisphere electrode Chemical Physics Letters 517 2011 29
    • (2011) Chemical Physics Letters , vol.517 , pp. 29
    • Henstridge, M.C.1    Wang, Y.2    Limon-Petersen, J.G.3    Laborda, E.4    Compton, R.G.5
  • 18
    • 80051471928 scopus 로고    scopus 로고
    • Quantitative weaknesses of the Marcus-Hush theory of electrode kinetics revealed by Reverse Scan Square Wave Voltammetry: The reduction of 2-methyl-2-nitropropane at mercury microelectrodes
    • E. Laborda, Y. Wang, M. Henstridge, F. Martinez-Ortiz, A. Molina, and R.G. Compton Quantitative weaknesses of the Marcus-Hush theory of electrode kinetics revealed by Reverse Scan Square Wave Voltammetry: The reduction of 2-methyl-2-nitropropane at mercury microelectrodes Chemical Physics Letters 512 2011 133
    • (2011) Chemical Physics Letters , vol.512 , pp. 133
    • Laborda, E.1    Wang, Y.2    Henstridge, M.3    Martinez-Ortiz, F.4    Molina, A.5    Compton, R.G.6
  • 19
    • 84855204809 scopus 로고    scopus 로고
    • Experimental comparison of the Butler-Volmer and Marcus-Hush-Chidsey formalisms of electrode kinetics: The reduction of cyclooctatetraene at mercury hemispherical electrodes via cyclic and square wave voltammetries
    • D. Suwatchara, N.V. Rees, M.C. Henstridge, E. Laborda, and R.G. Compton Experimental comparison of the Butler-Volmer and Marcus-Hush-Chidsey formalisms of electrode kinetics: The reduction of cyclooctatetraene at mercury hemispherical electrodes via cyclic and square wave voltammetries Journal of Electroanalytical Chemistry 665 2012 38
    • (2012) Journal of Electroanalytical Chemistry , vol.665 , pp. 38
    • Suwatchara, D.1    Rees, N.V.2    Henstridge, M.C.3    Laborda, E.4    Compton, R.G.5
  • 20
    • 83155180242 scopus 로고    scopus 로고
    • Redox systems obeying Marcus-Hush-Chidsey electrode kinetics do not obey the Randles-Sevcik equation for linear sweep voltammetry
    • M.C. Henstridge, E. Laborda, E.J.F. Dickinson, and R.G. Compton Redox systems obeying Marcus-Hush-Chidsey electrode kinetics do not obey the Randles-Sevcik equation for linear sweep voltammetry Journal of Electroanalytical Chemistry 664 2012 73
    • (2012) Journal of Electroanalytical Chemistry , vol.664 , pp. 73
    • Henstridge, M.C.1    Laborda, E.2    Dickinson, E.J.F.3    Compton, R.G.4
  • 21
    • 84862776583 scopus 로고    scopus 로고
    • The use of differential pulse voltammetries to discriminate between the Butler-Volmer and the simple Marcus-Hush models for heterogeneous electron transfer: The electro-reduction of europium (III) in aqueous solution
    • Y. Wang, E. Laborda, M. Henstridge, F. Martinez-Ortiz, A. Molina, and R.G. Compton The use of differential pulse voltammetries to discriminate between the Butler-Volmer and the simple Marcus-Hush models for heterogeneous electron transfer: The electro-reduction of europium (III) in aqueous solution Journal of Electroanalytical Chemistry 668 2012 7
    • (2012) Journal of Electroanalytical Chemistry , vol.668 , pp. 7
    • Wang, Y.1    Laborda, E.2    Henstridge, M.3    Martinez-Ortiz, F.4    Molina, A.5    Compton, R.G.6
  • 22
    • 84869083344 scopus 로고    scopus 로고
    • Marcus-Hush-Chidsey theory of electron transfer applied to voltammetry: A review
    • M.C. Henstridge, E. Laborda, N.V. Rees, and R.G. Compton Marcus-Hush-Chidsey theory of electron transfer applied to voltammetry: A review Electrochimica Acta 84 2012 12
    • (2012) Electrochimica Acta , vol.84 , pp. 12
    • Henstridge, M.C.1    Laborda, E.2    Rees, N.V.3    Compton, R.G.4
  • 24
    • 84859642041 scopus 로고    scopus 로고
    • Giving physical insight into the Butler-Volmer model of electrode kinetics: Application of asymmetric Marcus-Hush theory to the study of the electroreductions of 2-methyl-2-nitropropane, cyclooctatetraene and europium(III) on mercury microelectrodes
    • M.C. Henstridge, E. Laborda, Y. Wang, D. Suwatchara, N. Rees, A. Molina, F. Martínez-Ortiz, and R.G. Compton Giving physical insight into the Butler-Volmer model of electrode kinetics: Application of asymmetric Marcus-Hush theory to the study of the electroreductions of 2-methyl-2-nitropropane, cyclooctatetraene and europium(III) on mercury microelectrodes Journal of Electroanalytical Chemistry 672 2012 45
    • (2012) Journal of Electroanalytical Chemistry , vol.672 , pp. 45
    • Henstridge, M.C.1    Laborda, E.2    Wang, Y.3    Suwatchara, D.4    Rees, N.5    Molina, A.6    Martínez-Ortiz, F.7    Compton, R.G.8
  • 25
    • 84863004132 scopus 로고    scopus 로고
    • Comparative evaluation of the symmetric and asymmetric Marcus-Hush formalisms of electrode kinetics - The one-electron oxidation of tetraphenylethylene in dichloromethane on platinum microdisk electrodes
    • D. Suwatchara, M.C. Henstridge, N.V. Rees, E. Laborda, and R.G. Compton Comparative evaluation of the symmetric and asymmetric Marcus-Hush formalisms of electrode kinetics - The one-electron oxidation of tetraphenylethylene in dichloromethane on platinum microdisk electrodes Journal of Electroanalytical Chemistry 677 2012 120
    • (2012) Journal of Electroanalytical Chemistry , vol.677 , pp. 120
    • Suwatchara, D.1    Henstridge, M.C.2    Rees, N.V.3    Laborda, E.4    Compton, R.G.5
  • 26
    • 84866857721 scopus 로고    scopus 로고
    • Molecular insights into electron transfer processes via variable temperature cyclic voltammetry. Application of the asymmetric Marcus-Hush model
    • D. Suwatchara, N.V. Rees, M.C. Henstridge, E. Laborda, and R.G. Compton Molecular insights into electron transfer processes via variable temperature cyclic voltammetry. Application of the asymmetric Marcus-Hush model Journal of Electroanalytical Chemistry 685 2012 53
    • (2012) Journal of Electroanalytical Chemistry , vol.685 , pp. 53
    • Suwatchara, D.1    Rees, N.V.2    Henstridge, M.C.3    Laborda, E.4    Compton, R.G.5
  • 27
    • 3242828101 scopus 로고
    • Electron Transfer Reactions. III.The Application of Derivative Cyclic Voltammetry for the Determination of Rate Constants and alpha Values for Heterogeneous Electron Transfer Processes: The Reduction of Organic Anions
    • H. Wang, and O. Hammerich Electron Transfer Reactions. III. The Application of Derivative Cyclic Voltammetry for the Determination of Rate Constants and alpha Values for Heterogeneous Electron Transfer Processes: the Reduction of Organic Anions Acta Chemica Scandinavica 46 1992 563
    • (1992) Acta Chemica Scandinavica , vol.46 , pp. 563
    • Wang, H.1    Hammerich, O.2
  • 28
    • 0033723207 scopus 로고    scopus 로고
    • Ohmic drop compensation in cyclic voltammetry at scan rates in the megavolt per second range: Access to nanometric diffusion layers via transient electrochemistry
    • C. Amatore, E. Maisonhaute, and G. Simonneau Ohmic drop compensation in cyclic voltammetry at scan rates in the megavolt per second range: access to nanometric diffusion layers via transient electrochemistry Journal of Electroanalytical Chemistry 486 2000 141
    • (2000) Journal of Electroanalytical Chemistry , vol.486 , pp. 141
    • Amatore, C.1    Maisonhaute, E.2    Simonneau, G.3
  • 32
    • 0038779725 scopus 로고    scopus 로고
    • A computational and experimental study of the cyclic voltammetry response of partially blocked electrodes. Part II: Randomly distributed and overlapping blocking systems
    • T.J. Davies, B.A. Brookes, A.C. Fisher, K. Yunus, S.J. Wilkins, P.R. Greene, J.D. Wadhawan, and R.G. Compton A computational and experimental study of the cyclic voltammetry response of partially blocked electrodes. Part II: Randomly distributed and overlapping blocking systems Journal of Physical Chemistry B 107 2003 6431
    • (2003) Journal of Physical Chemistry , vol.107 B , pp. 6431
    • Davies, T.J.1    Brookes, B.A.2    Fisher, A.C.3    Yunus, K.4    Wilkins, S.J.5    Greene, P.R.6    Wadhawan, J.D.7    Compton, R.G.8
  • 34
    • 79551490502 scopus 로고    scopus 로고
    • Measurement of the diffusion coefficients of RuNH363+ and RuNH362+ in aqueous solution using microelectrode double potential step chronoamperometry
    • Y. Wang, J.G. Limon-Petersen, and R.G. Compton Measurement of the diffusion coefficients of RuNH363+ and RuNH362+ in aqueous solution using microelectrode double potential step chronoamperometry Journal of Electroanalytical Chemistry 652 2011 13
    • (2011) Journal of Electroanalytical Chemistry , vol.652 , pp. 13
    • Wang, Y.1    Limon-Petersen, J.G.2    Compton, R.G.3
  • 35
    • 4444312864 scopus 로고    scopus 로고
    • Double potential step chronoamperometry at microdisk electrodes: Simulating the case of unequal diffusion coefficients
    • O.V. Klymenko, R.G. Evans, C. Hardacre, I.B. Svir, and R.G. Compton Double potential step chronoamperometry at microdisk electrodes: simulating the case of unequal diffusion coefficients Journal of Electroanalytical Chemistry 571 2004 211
    • (2004) Journal of Electroanalytical Chemistry , vol.571 , pp. 211
    • Klymenko, O.V.1    Evans, R.G.2    Hardacre, C.3    Svir, I.B.4    Compton, R.G.5
  • 36
    • 33846435693 scopus 로고    scopus 로고
    • Coulometry on the voltammetric timescale: Microdisk potential-step chronoamperometry in aprotic solvents reliably measures the number of electrons transferred in an electrode process simultaneously with the diffusion coefficients of the electroactive species
    • C.A. Paddon, D.S. Silvester, F.L. Bhatti, T.J. Donohoe, and R.G. Compton Coulometry on the voltammetric timescale: Microdisk potential-step chronoamperometry in aprotic solvents reliably measures the number of electrons transferred in an electrode process simultaneously with the diffusion coefficients of the electroactive species Electroanalysis 19 2007 11
    • (2007) Electroanalysis , vol.19 , pp. 11
    • Paddon, C.A.1    Silvester, D.S.2    Bhatti, F.L.3    Donohoe, T.J.4    Compton, R.G.5
  • 39
    • 67650747667 scopus 로고    scopus 로고
    • How Much Supporting Electrolyte Is Required to Make a Cyclic Voltammetry Experiment Quantitatively "diffusional"? A Theoretical and Experimental Investigation
    • E.J.F. Dickinson, J.G. Limon-Petersen, N.V. Rees, and R.G. Compton How Much Supporting Electrolyte Is Required to Make a Cyclic Voltammetry Experiment Quantitatively "Diffusional"? A Theoretical and Experimental Investigation Journal of Physical Chemistry C 113 2009 11157
    • (2009) Journal of Physical Chemistry C , vol.113 , pp. 11157
    • Dickinson, E.J.F.1    Limon-Petersen, J.G.2    Rees, N.V.3    Compton, R.G.4
  • 40
    • 84856012429 scopus 로고    scopus 로고
    • Reorganization energy and pre-exponential factor from temperature-dependent experiments in electron transfer reactions. A typical example: The reduction of tert-nitrobutane
    • C. Costentin, C. Louault, M. Robert, V. Rogé, and J.M. Savéant Reorganization energy and pre-exponential factor from temperature-dependent experiments in electron transfer reactions. A typical example: the reduction of tert-nitrobutane Physical Chemistry Chemical Physics 14 2012 1581
    • (2012) Physical Chemistry Chemical Physics , vol.14 , pp. 1581
    • Costentin, C.1    Louault, C.2    Robert, M.3    Rogé, V.4    Savéant, J.M.5
  • 41
    • 0013366757 scopus 로고
    • Dependence of electrode kinetics on molecular structure nitro-compounds in dimethylformamide
    • M.E. Peover, and J.S. Powell Dependence of electrode kinetics on molecular structure nitro-compounds in dimethylformamide Journal of Electroanalytical Chemistry 20 1969 427
    • (1969) Journal of Electroanalytical Chemistry , vol.20 , pp. 427
    • Peover, M.E.1    Powell, J.S.2
  • 42
    • 0037130677 scopus 로고    scopus 로고
    • Density Functional Theory Study of Redox Pairs: 2. Influence of Solvation and Ion-Pair Formation on the Redox Behavior of Cyclooctatetraene and Nitrobenzene
    • M.H. Baik, C.K. Schauer, and T. Ziegler Density Functional Theory Study of Redox Pairs: 2. Influence of Solvation and Ion-Pair Formation on the Redox Behavior of Cyclooctatetraene and Nitrobenzene Journal of the American Chemical Society 124 2002 11167
    • (2002) Journal of the American Chemical Society , vol.124 , pp. 11167
    • Baik, M.H.1    Schauer, C.K.2    Ziegler, T.3
  • 43
    • 0348218642 scopus 로고
    • Estimation of the free energy of activation for electron transfer reactions involving dipolar reactants and products
    • W.R. Fawcett, and Y.I. Kharkats Estimation of the free energy of activation for electron transfer reactions involving dipolar reactants and products Journal of Electroanalytical Chemistry 47 1973 413
    • (1973) Journal of Electroanalytical Chemistry , vol.47 , pp. 413
    • Fawcett, W.R.1    Kharkats, Y.I.2
  • 44
    • 1042281156 scopus 로고    scopus 로고
    • Revisiting the heterogeneous electron-transfer kinetics of nitro compounds
    • C. Kraiya, P. Singh, and D.H. Evans Revisiting the heterogeneous electron-transfer kinetics of nitro compounds Journal of Electroanalytical Chemistry 563 2004 203
    • (2004) Journal of Electroanalytical Chemistry , vol.563 , pp. 203
    • Kraiya, C.1    Singh, P.2    Evans, D.H.3
  • 45
    • 33646254381 scopus 로고    scopus 로고
    • Distance dependence of heterogeneous electron transfer through the nonadiabatic and adiabatic regimes
    • S.W. Feldberg, and N. Sutin Distance dependence of heterogeneous electron transfer through the nonadiabatic and adiabatic regimes Chemical Physics 324 2006 216
    • (2006) Chemical Physics , vol.324 , pp. 216
    • Feldberg, S.W.1    Sutin, N.2
  • 46
    • 33244469516 scopus 로고    scopus 로고
    • Electroreduction of a Series of Alkylcobalamins: Mechanism of Stepwise Reductive Cleavage of the CoC Bond
    • R.L. Birke, Q. Huang, T. Spataru, and D.K. Gosser Electroreduction of a Series of Alkylcobalamins: Mechanism of Stepwise Reductive Cleavage of the CoC Bond Journal of the American Chemical Society 128 2006 1922
    • (2006) Journal of the American Chemical Society , vol.128 , pp. 1922
    • Birke, R.L.1    Huang, Q.2    Spataru, T.3    Gosser, D.K.4
  • 47
    • 4644336559 scopus 로고
    • The solvent effect on the electro-oxidation of 1,4-phenylenediamine. the influence of the solvent reorientation dynamics on the one-electron transfer rate
    • M. Opallo The solvent effect on the electro-oxidation of 1,4-phenylenediamine. The influence of the solvent reorientation dynamics on the one-electron transfer rate Journal of the Chemical Society, Faraday Transactions 82 1986 339
    • (1986) Journal of the Chemical Society, Faraday Transactions , vol.82 , pp. 339
    • Opallo, M.1


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