Giving physical insight into the Butler-Volmer model of electrode kinetics: Application of asymmetric Marcus-Hush theory to the study of the electroreductions of 2-methyl-2-nitropropane, cyclooctatetraene and europium(III) on mercury microelectrodes

Journal of Electroanalytical Chemistry

Volumn 672, Issue , 2012, Pages 45-52

  Henstridge, Martin C ^a   Laborda, Eduardo ^a   Wang, Yijun ^a   Suwatchara, Danu ^a   Rees, Neil ^a   Molina, Ángela ^b   Martinez Ortiz F ^b   Compton, Richard G ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b UNIVERSITY OF MURCIA   (Spain)

Author keywords

2 Methyl 2 nitropropane electroreduction; Asymmetric Marcus Hush theory; Cyclooctatetraene electroreduction; Europium(III) electroreduction; Force constant differences

Indexed keywords

ACETONITRILE; ELECTROLYTIC REDUCTION; EUROPIUM; KINETIC THEORY; MERCURY (METAL); MICROELECTRODES;

ASYMMETRIC MODELS; BUTLER-VOLMER; BUTLER-VOLMER MODELS; CYCLOOCTATETRAENE; ELECTRO REDUCTION; ELECTROACTIVE SPECIES; ELECTRODE KINETICS; FORCE CONSTANTS; KINETIC MODELS; KINETIC STUDY; MARCUS-HUSH; MERCURY MICROELECTRODE; PHYSICAL INTERPRETATION; REDOX COUPLE; REDUCTIVE PROCESS; REORGANIZATION ENERGIES; SQUARE WAVE VOLTAMMETRY; TRANSFER COEFFICIENT; VOLTAMMOGRAMS; WORKING ELECTRODE;

KINETICS;

EID: 84859642041     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2012.02.028     Document Type: Article

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