The use of differential pulse voltammetries to discriminate between the Butler-Volmer and the simple Marcus-Hush models for heterogeneous electron transfer: The electro-reduction of europium (III) in aqueous solution

Journal of Electroanalytical Chemistry

Volumn 668, Issue , 2012, Pages 7-12

  Wang, Yijun ^a   Laborda, Eduardo ^a   Henstridge, Martin C ^a   Martinez Ortiz, Francisco ^b   Molina, Angela ^b   Compton, Richard G ^a  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b UNIVERSITY OF MURCIA   (Spain)

Author keywords

Butler Volmer theory; Differential multipulse voltammetry; Eu(II) Eu(III); Marcus Hush theory; Square wave voltammetry

Indexed keywords

ELECTRON TRANSITIONS; KINETICS; MERCURY (METAL); MICROELECTRODES; RATE CONSTANTS; SOLUTIONS; VOLTAMMETRY;

BUTLER-VOLMER; CHARGING CURRENT; CONSISTENT VALUES; DIFFERENTIAL PULSE; DIFFERENTIAL PULSE VOLTAMMETRY; ELECTRO REDUCTION; ELECTRODE KINETICS; EXPERIMENTAL DATA; HALF-REACTIONS; HETEROGENEOUS ELECTRON TRANSFER; HETEROGENEOUS RATE CONSTANT; KINETIC ANALYSIS; KINETIC APPROACH; KINETIC FORMALISM; MARCUS-HUSH; MULTIPULSES; PEAK HEIGHT; REDOX COUPLE; SCAN MODE; SQUARE WAVE VOLTAMMETRY; TRANSFER COEFFICIENT; VOLTAMMOGRAMS;

EUROPIUM;

EID: 84862776583     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2011.12.023     Document Type: Article

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