Comparison of the catalytic activity of [(η5-C 5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(η5-C5H5)Ru(6,6′-diamino-2,2′- bipyridine)(L)]OTf (L = labile ligand) in the hydrogenation of cyclohexanone. Evidence for the presence of a metal-ligand bifunctional mechanism under acidic conditions

Organometallics

Volumn 32, Issue 21, 2013, Pages 6541-6554

  Dimondo, Domenico ^a   Thibault, Michelle E ^a   Britten, James ^b   Schlaf, Marcel ^a  

^a UNIVERSITY OF GUELPH   (Canada)

^b MCMASTER UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDIC CONDITIONS; ACIDIC MEDIUMS; BI-FUNCTIONAL MECHANISMS; DIMERIC COMPLEXES; PROTON SHUTTLE; RELATIVE REACTIVITIES; SINGLE CRYSTAL X-RAY CRYSTALLOGRAPHY; STRUCTURAL COMPARISON;

CATALYST ACTIVITY; HYDROGENATION; RUTHENIUM COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

LIGANDS;

EID: 84887681545     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om400871v     Document Type: Article

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