Chiral primary-amine-catalyzed conjugate addition to α-substituted vinyl ketones/aldehydes: Divergent stereocontrol modes on enamine protonation

Chemistry - A European Journal

Volumn 19, Issue 46, 2013, Pages 15669-15681

  Fu, Niankai ^a   Zhang, Long ^a   Luo, Sanzhong ^a   Cheng, Jin Pei ^a  

^a INSTITUTE OF CHEMISTRY   (China)

Author keywords

alkylation; amines; asymmetric catalysis; ketones; protonation

Indexed keywords

ASYMMETRIC CATALYSIS; CONJUGATE ADDITION; DFT CALCULATION; ENAMINE INTERMEDIATES; ENANTIOSELECTIVE; HIGH ENANTIOSELECTIVITY; MECHANISTIC STUDIES; TRIFLUOROMETHANE SULFONIC ACID;

ADDITION REACTIONS; ALDEHYDES; ALKYLATION; AMINES; CATALYSIS; ENANTIOSELECTIVITY; FRIEDEL-CRAFTS REACTION; HERBICIDES; KETONES; STEREOSELECTIVITY;

PROTONATION;

EID: 84887017605     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201302056     Document Type: Article

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