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9644297523
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-
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143
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9644310890
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note
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9a
-
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147
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9644293562
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note
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In the case of palladium enolates, the chirality is carried by the ligands of palladium [(R)-BINAP]. The chiral palladium enolate, catalytically generated from a trimethylsilyl enolether is protonated by an achiral agent, water
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0343375910
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H. Matsushita, Y. Tsujino, M. Noguchi, M. Saburi, and S. Yoshikawa Bull. Chem. Soc. Jpn. 51 1978 862 865
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169
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9644298266
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note
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(b) For the four models shown in Schemes 12 and 13, the attack by H-A* can occur on the same face of the paper, either above as depicted in Schemes 12 and 13 or behind. Obviously, the attack can also occur above (or behind) for the E- and Z-models of the RSC reaction (Scheme 12) and behind (or above) for the E- and Z-models of the NSC reaction (Schemes 13)
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-
-
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170
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0025895518
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An example of this reaction type is reported in the hydrogenation of methyl 3-acetamido-2-butenoate by the Ru-BINAP system: the Z-isomer gave 96% ee while the E-isomer gave only 5% ee with an opposite configuration: W.D. Lubell, M. Kitamura, and R. Noyori Tetrahedron: Asymmetry 2 1991 543 554
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Lubell, W.D.1
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Noyori, R.3
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172
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9644298267
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note
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7w,7y
-
-
-
-
173
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9644285735
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note
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10f
-
-
-
-
174
-
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84985611103
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-
See for example: R. Schmierer, G. Grotemeier, G. Helmchen, and A. Selim Angew. Chem., Int. Ed. Engl. 20 1981 207 208
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Schmierer, R.1
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Selim, A.4
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0029118411
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P. Angibaud, J.L. Chaumette, J.R. Desmurs, L. Duhamel, G. Plé, J.Y. Valnot, and P. Duhamel Tetrahedron: Asymmetry 6 1995 1919 1932
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Angibaud, P.1
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178
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0000189242
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P.L. Hall, J.H. Gilhrist, A.T. Harrisson, D.J. Fuller, and D.B. Collum J. Am. Chem. Soc. 113 1991 9575 9585
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185
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0025780257
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H. Buschmann, H.D. Scharf, N. Hoffmann, and P. Esser Angew. Chem., Int. Ed. Engl. 30 1991 477 515
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186
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9644286459
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note
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2e,2g
-
-
-
-
187
-
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9644299042
-
-
note
-
This type of reaction is sometimes considered as a diastereoselective protonation
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