SPE HG-AAS method for the determination of inorganic arsenic in rice - Results from method validation studies and a survey on rice products

Analytical and Bioanalytical Chemistry

Volumn 405, Issue 24, 2013, Pages 7851-7857

  Rasmussen, Rie R ^a   Qian, Yiting ^a   Sloth, Jens J ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Food control; Inorganic arsenic; Rice samples; SPE HG AAS; Speciation; Water bath extraction

Indexed keywords

FOOD CONTROL; INORGANIC ARSENIC; RICE SAMPLES; SPE HG-AAS; SPECIATION; WATER BATHS;

ARSENIC; ARSENIC COMPOUNDS; ATOMIC ABSORPTION SPECTROMETRY; FOOD SUPPLY; HEATING; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; MASS SPECTROMETERS;

EXTRACTION;

EID: 84884281922     PISSN: 16182642     EISSN: 16182650     Source Type: Journal    
DOI: 10.1007/s00216-013-6936-8     Document Type: Review

References (29)

1. Rasmussen RR, Hedegaard RV, Larsen EH, Sloth JJ (2012) Development and validation of an SPE HG-AAS method for determination of inorganic arsenic in samples of marine origin. Anal Bioanal Chem 403:2825-2834
2. Schoof R, Yost L, Eickhoff J, Crecelius E, Cragin D, Meacher D, Menzel D (1999) A market basket survey of inorganic arsenic in food. Food and Chem Toxicol 37:839-846
3. Pizarro I, Gómez M, Palacios MA, Cámara C (2003) Evaluation of stability of arsenic species in rice. Anal Bioanal Chem 376:102-109
4. Williams P, Price A, Raab A, Hossain S, Feldmann J, Meharg A (2005) Variation in arsenic speciation and concentration in paddy rice related to dietary exposure. Environ Sci Technol 39:5531-5540
5. Abedin MJ, Cresser MS, Meharg AA, Feldmann J, Cotter-Howells J (2002) Arsenic accumulation and metabolism in rice (Oryza sativa L.). Environ Sci Technol 36:962-968
6. IARC (International Agency for Research on Cancer) (1987) IARC monographs on the evaluation of the carcinogenic risks to humans. Suppl. 7. Overall evaluations of carcinogenicity: an updating of IARC monographs, vol 1-42
7. EFSA (European Food Safety Authority) (2009) Scientific opinion on arsenic in food. EFSA Panel on Contaminants in the Food Chain (CONTAM). EFSA J 7(10):1351, 1-199
8. Codex (2012) Proposed draft maximum levels for arsenic in rice (at step 3). http://usriceproducers.com/files/362-2012.01-WHO.maximumlevelsforarsenic. pdf. Accessed 4 Feb 2013
9. Sun GX, Williams PN, Carey AM, Zhu YG, Deacon C, Raab A, Feldmann J, Islam RM, Meharg AA (2008) Inorganic arsenic in rice bran and its products are an order of magnitude higher than in bulk grain. Environ Sci Technol 42:7542-7546
10. Heitkemper DT, Vela NP, Stewart KR, Westphal CS (2001) Determination of total and speciated arsenicin rice by ion chromatography and inductively coupled plasma mass spectrometry. J Anal At Spectrom 16:299-306
11. Commission EC (2006) Commission regulation (EC) no. 1881/2006 of 19 December 2006 setting maximum levels for certain contaminants in foodstuffs. Off J Eur Commun L364:5-24
12. WHO (World Health Organization) (2011) < br />Evaluation of certain contaminants in food: seventy-second meeting of the Joint FAO/WHO Expert Committee on Food Additives. WHO Technical Report Series 959
13. European Standard (EN 15517:2008) Determination of trace elements - determination of inorganic As in seaweed by hydride generation atomic absorption spectrometry (HG-AAS) after acid digestion
14. European Standard (EN 16278:2012) Animal feeding stuffs - determination of inorganic arsenic by hydride generation atomic absorption spectrometry (HG-AAS) after microwave extraction and separation by solid phase extraction (SPE)
15. GB/T5009.11-2003. Determination of total arsenic and abio-arsenic in foods.
16. Francesconi KA, Kuehnelt D (2004) Determination of arsenic species: a critical review of methods and applications, 2000-2003. Analyst 129:373-395
17. de la Calle MB, Emteborg H, Linsinger TPJ, Montoro R, Sloth JJ, Rubio R, Baxter MJ, Feldmann J, Vermaercke P, Raber G (2011) Does the determination of inorganic arsenic in rice depend on the method? TrAC 30:641-651
18. Raber G, Stock N, Hanel P, Murko M, Navratilova J, Francesconi KA (2012) An improved HPLC-ICPMS method for determining inorganic arsenic in food: application to rice, wheat and tuna fish. Food Chem 134(1):524-532
19. de la Calle MB, Linsinger T, Emteborg H, Charaud-Got J, Verbist I (2010) Report of the Seventh interlaboratory comparison organized by the European Union-Reference Laboratory for Heavy Metals in Feed and Food, IMEP-107: total and inorganic As in rice. JRC-IRMM, Geel, Belgium EUR 24314 EN
20. Raab A, Baskaran C, Feldmann J, Meharg AA (2009) Cooking rice in a high water to rice ratio reduces inorganic arsenic content. J Environ Monit 11:41-44
21. ISO (2005) 13528: statistical methods for use in proficiency testing by interlaboratory comparisons. ISO, Geneva
22. ISO (1994) 5725-2: accuracy (trueness and precision) of measurement methods and results. Part 2: basic method for the determination of repeatability and reproducibility of a standard measurement method. ISO, Geneva
23. NMKL (Nordic Committee on Food Analysis) (2009) Validation of chemical analytical methods. NMKL procedure 4:ed. 3
24. de la Calle M, Baer I, Robouch P, Cordeiro F, Emteborg H, Baxter M, Brereton N, Raber G, Velez D, Devesa V (2012) Is it possible to agree on a value for inorganic arsenic in food? The outcome of IMEP-112. Anal Bioanal Chem 404(8):2475-2488
25. Commission EC (2002) Commission decision of 12 August 2002 implementing Council Directive 96/23/EC concerning the performance of analytical methods and the interpretation of results. Off J Eur Commun L221:8-36
26. Horwitz W (1982) Evaluation of analytical methods used for regulation. J Assoc Off Anal Chem 65:525-530
27. Commission EC (2007) Commission regulation (EC) no 333/2007 of 28 March 2007 laying down the methods of sampling and analysis for the official control of the levels of lead, cadmium, mercury, inorganic tin, 3-MCPD and benzo(a)pyrene in foodstuffs. Off J Eur Commun L88:29-38
28. Williams P, Islam M, Adomako E, Raab A, Hossain S, Zhu Y, Feldmann J, Meharg A (2006) Increase in rice grain arsenic for regions of Bangladesh irrigating paddies with elevated arsenic in groundwaters. Environ Sci Technol 40:4903-4908
29. Jorhem L, Åstrand C, Sundström B, Baxter M, Stokes P, Lewis J, Grawé KP (2008) Elements in rice from the Swedish market: 1. Cadmium, lead and arsenic (total and inorganic). Food Addit Contam 25:284-292