-
1
-
-
84883642375
-
-
0value exceeds +3.0 V vs. NHE
-
0value exceeds +3.0 V vs. NHE.
-
-
-
-
3
-
-
84883650235
-
-
0values for the highest oxidation states of Pu (VII, VI) in acidic environment are not available; also, it is not unreasonable that Pu(VIII)O4 could exist
-
0values for the highest oxidation states of Pu (VII, VI) in acidic environment are not available; also, it is not unreasonable that Pu(VIII)O4 could exist.
-
-
-
-
4
-
-
0035820568
-
-
In disagreement with the values listed here, some experiments suggest that at certain conditions NiF3 + is a stronger oxidizer than PtF6 but whether its oxidizing strength exceeds that of KrF+ remains unclear: T. Schroer, K. O. Christe, Inorg. Chem. 2001, 40, 2415-2419.
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Inorg. Chem.
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-
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Schroer, T.1
Christe, K.O.2
-
5
-
-
0001410535
-
-
3+ (solv): G. Lucier, C. Shen, W. J. Casteel, Jr., L. Chacón, N. Bartlett, J. Fluor. Chem. 1995, 72, 157-163.
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J. Fluor. Chem.
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Lucier, G.1
Shen, C.2
Casteel Jr., W.J.3
Chacón, L.4
Bartlett, N.5
-
8
-
-
22544454069
-
-
0value for Xe-F2/Xe pair; see S. R. Gunn, J. Phys. Chem. 1967, 71, 2934-2937
-
(1967)
J. Phys. Chem.
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Gunn, S.R.1
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9
-
-
0011025471
-
-
G. K. Johnson, J. G. Malm, W. N. Hubbard, J. Chem. Thermod. 1972, 4, 879-891.
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J. Chem. Thermod.
, vol.4
, pp. 879-891
-
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Johnson, G.K.1
Malm, J.G.2
Hubbard, W.N.3
-
11
-
-
84883650657
-
-
Western Oregon University data, accessed on Apr 12, 2012
-
Western Oregon University data; http://www.wou.edu/las/physci/ch412/ redox.htm accessed on Apr 12, 2012.
-
-
-
-
12
-
-
0011614278
-
-
Marcel Dekker, New York, USA
-
Values from www.webelements.com accessed on May 12, 2012, usually taken from A. J. Bard, R. Parsons, J. Jordan, Standard Potentials in Aqueous Solutions, IUPAC. Marcel Dekker, New York, USA, 1985.
-
(1985)
Standard Potentials in Aqueous Solutions, IUPAC
-
-
Bard, A.J.1
Parsons, R.2
Jordan, J.3
-
13
-
-
0000189636
-
-
It is intriguing that the salts of this acid are remarkably thermally stable, for example K3MnO4 decomposes only above 700 °C: R. Olazcuaga, J. M. Reau, G. LeFlem, P. Hagenmüller, Z. Anorg. Allg. Chem., 1975, 412, 271-280.
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(1975)
Z. Anorg. Allg. Chem.
, vol.412
, pp. 271-280
-
-
Olazcuaga, R.1
Reau, J.M.2
Leflem, G.3
Hagenmüller, P.4
-
14
-
-
77958609518
-
-
T. Szuppa, A. Stolle, B. Ondruschka, W. Hopfe, ChemSus-Chem 2010, 3, 1181-1191.
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(2010)
ChemSus-Chem
, vol.3
, pp. 1181-1191
-
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Szuppa, T.1
Stolle, A.2
Ondruschka, B.3
Hopfe, W.4
-
17
-
-
84881100083
-
-
in press, doi: 10.1039/c3cc43072c
-
The value of +1.98 V is frequently given in textbooks. Our recent study shows that the formal redox potential, E0', may reach up to +2.9 V vs. NHE for Ag(II) dissolved in 33% oleum: P. Połczyński, R. Jurczakowski, W. Grochala, Chem. Commun., in press 2013, doi: 10.1039/c3cc43072c.
-
(2013)
Chem. Commun.
-
-
Połczyński, P.1
Jurczakowski, R.2
Grochala, W.3
-
18
-
-
0000160287
-
-
B. Žemva, K. Lutar, L. Chacon, M. Fele-Beuermann, J. Allman, C. Shen, N. Bartlett, J. Am. Chem. Soc., 1995, 117, 10025-10034.
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J. Am. Chem. Soc.
, vol.117
, pp. 10025-10034
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-
Žemva, B.1
Lutar, K.2
Chacon, L.3
Fele-Beuermann, M.4
Allman, J.5
Shen, C.6
Bartlett, N.7
-
20
-
-
0011053497
-
-
B. Žemva, K. Lutar, A. Jesih, W. J. Casteel Jr., A. P. Wilkinson, D. E. Cox, R. B. Von Dreele, H. Borrmann, N. Bartlett, J. Am. Chem. Soc., 1991, 113, 4192-4198.
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J. Am. Chem. Soc.
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Žemva, B.1
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Wilkinson, A.P.5
Cox, D.E.6
Von Dreele, R.B.7
Borrmann, H.8
Bartlett, N.9
-
21
-
-
0003929366
-
-
N. Bartlett, G. Lucier, C. Shen, W. J. Casteel Jr., L. Chacon, J. Munzenberg, B. Žemva, J. Fluor. Chem., 1995, 71, 163-164.
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Bartlett, N.1
Lucier, G.2
Shen, C.3
Casteel Jr., W.J.4
Chacon, L.5
Munzenberg, J.6
Žemva, B.7
-
22
-
-
84883631690
-
-
2nd Ed., G. Brauer, Academic Press New York
-
Preparative chemistry textbooks contain warning that PbCl4 could spontaneously explode and preparation of larger amounts of this compound is not advisable. It should be stored at temperatures below -80 °C and protected from sunlight. See for example: Handbook of Preparative Inorganic Chemistry, Vol. 1, 2nd Ed., G. Brauer, Academic Press New York 1963, p.751.
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(1963)
Handbook of Preparative Inorganic Chemistry
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26
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0031072478
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Y. Yamamoto, S. Arai, T. Matsuda, M. Satoh, T. Inoue, Jpn. J. Appl. Phys. 1997, 36, L133-L135.
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Yamamoto, Y.1
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28
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-
34250278211
-
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and references therein
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V. V. Aleksandrov, V. V. Boldyrev, V. V. Marusin, V. G. Morozov, V. S. Solovjev, T. M. Rozhentseva, J. Therm. Anal. 1978, 13, 205-212 and references therein.
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Aleksandrov, V.V.1
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reference [3] therein
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W. K. Jóźwiak, W. Ignaczak, D. Dominiak, T. P. Maniecki, Appl. Cat. A 2004, 258, 33-45
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Appl. Cat. A
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0036339950
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Data for Li0.04NiO2: H. Arai, M. Tsuda, K. Saito, M. Hayashi, K. Takei, Y. Sakurai, J. Solid State Chem., 2002, 163, 340-349.
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J. Solid State Chem.
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Arai, H.1
Tsuda, M.2
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Sakurai, Y.6
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37
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0026156620
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The value of 390 °C is probably wrong: M. Afzal, P. K. Butt, H. Ahmad, J. Therm. Anal. 1991, 37, 1015-1023.
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Afzal, M.1
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Ahmad, H.3
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2142639491
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The data for pure related CoO2 are missing, specimen containing water have been studied: C. B. Wang, H. K. Lin, C. W. Tang, Cat. Lett., 2004, 94, 69-74.
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Cat. Lett.
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Wang, C.B.1
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3rd ed. Wiley, New York
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F. Cotton, G. Wilkinson, Inorganic Chemistry, 3rd ed., Wiley, New York, 1972, p. 994.
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Inorganic Chemistry
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Cotton, F.1
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42
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0006285615
-
-
These authors feel that possibility of its facile collapse to U(VI)(O22-) has not been sufficiently addressed
-
Unusual U(XII)O6 has been postulated: P. Pyykkö, N. Runeberg, M. Straka, K. G. Dyall, Chem. Phys. Lett., 2000, 328, 415-419. These authors feel that possibility of its facile collapse to U(VI)(O22-) has not been sufficiently addressed.
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Chem. Phys. Lett.
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Pyykkö, P.1
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43
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0006476614
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1st Ed. Elsevier
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Advanced Inorganic Fluorides: Synthesis, Characterization and Applications, T. Nakajima, B. Žemva, A. Tressaud (Eds.), 1st Ed., Elsevier 2000.
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(2000)
Advanced Inorganic Fluorides: Synthesis, Characterization and Applications
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Nakajima, T.1
Žemva, B.2
Tressaud, A.3
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46
-
-
0001116165
-
-
Interestingly, atomic fluorine (radical) is generated in large amounts during thermal decomposition of TbF4 at temperatures exceeding 600 K and of CoF3 at T > 700 K: N. S. Chilingarov, J. V. Rau, L.N. Sidorov, L. Bencze, A. Popovic, V.F. Sukhoverkhov, J. Fluor. Chem. 2000, 104, 291-295
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Chilingarov, N.S.1
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Bencze, L.4
Popovic, A.5
Sukhoverkhov, V.F.6
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47
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44649154973
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M. S. Leskiv, N. S. Chilingarov, J. V. Rau, D. Ferro, S. V. Abramov, F. M. Spiridonov, L. N. Sidorov, J. Fluor. Chem. 2008, 129, 529-534.
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Leskiv, M.S.1
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Sidorov, L.N.7
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48
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-
85013708611
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Elsevier, Amsterdam, chapter 6.11.2 and references therein
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See: L. Piela, Ideas of quantum chemistry, Elsevier, Amsterdam 2007, chapter 6.11.2 and references therein.
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Ideas of Quantum Chemistry
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Piela, L.1
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50
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-
84881819908
-
-
Physics & Chemistry at low temperatures, ed. by L. Khriachtchev, Pan Stanford Publishing
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For a recent review of oxidizers containing noble gas atoms see: W. Grochala, L. Khriachtchev, M. Räsänen, Noble Gas Chemistry, in: Physics & Chemistry at low temperatures, ed. by L. Khriachtchev, Pan Stanford Publishing 2011, 421-448.
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Noble Gas Chemistry
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Grochala, W.1
Khriachtchev, L.2
Räsänen, M.3
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C. R. Bieler, K. E. Spence, K. C. Janda, J. Phys. Chem., 1991, 95, 5058-5064.
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Bieler, C.R.1
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55
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43149085778
-
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See for example: S. Riedel, M. Kaupp, P. Pyykkö, Inorg. Chem. 2008, 47, 3379-3383.
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Riedel, S.1
Kaupp, M.2
Pyykkö, P.3
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56
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-
84883644822
-
-
To our disappointment, we have not found any previous case of the inversion of metal-ligand states which would be well documented via quantum mechanical calculations and quantitative analysis of atomic contributions to the density o states, F4 (see Ref. 65) thus seems to be the first of the kind
-
To our disappointment, we have not found any previous case of the inversion of metal-ligand states which would be well documented via quantum mechanical calculations and quantitative analysis of atomic contributions to the density o states. The case of KAg(III)F4 (see Ref. 65) thus seems to be the first of the kind.
-
The Case of KAg(III)
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4243761984
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J. Zaanen, G. A. Sawatzky, J. W. Allen, Phys. Rev. Lett. 1985, 55, 418-421
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Zaanen, J.1
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0001054988
-
-
Not many genuine "p metals" have in fact been demonstrated so far. CuS and CuSe have been suggested as such. The case of CuS is very interesting as it contains alternating (Cu(II)S) and (Cu(I)2S2) units, which indicates that the partial redox reaction between Cu(II) and S2- has occurred. Nevertheless, theoretical calculations suggest that the states at the Fermi level are substantially predominated by Cu(3d) states with much smaller contribution from sulphur: Z. Kurmaev, J. van Ek, D. L. Ederer, L. Zhou, T. A. Callcott, R. C. C. Perera, V. M. Cherkashenko, S. N. Shamin, V. A. Trofimova, S. Bartkowski, M. Neumann, A. Fujimori, V. P. Moloshag, J. Phys.: Condens. Matter 1998, 10, 1687-1697
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Kurmaev, Z.1
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Perera, R.C.C.6
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Shamin, S.N.8
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Bartkowski, S.10
Neumann, M.11
Fujimori, A.12
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N. S. Pavlova, V. A. Galkina, I. A. Nekrasov, E. Z. Kurmaev, Physics Sol. State, 2009, 51, 2207-2210.
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Pavlova, N.S.1
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61
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0001343315
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-
The crossing of electronic states was postulated to be the reason for so called "bond stretch isomerism" but the original explanation did not involve the genuine redox process. See or example: Y. Jean, A. Lledos, J. K. Burdett, R. Hoffmann, J. Am. Chem. Soc. 1988, 110, 4506-4516
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84989535309
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G. Parkin, R. Hoffmann, Angew. Chem. Int. Ed. Engl., 1994, 33, 1462-1462, and references therein. The experimental findings which inspired the discussion on bond stretch isomerism later proved incorrect, nevertheless the theoretical arguments are valid and a real case of bond stretch isomerism might be found in the future.
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27844452029
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One example of how one may systematically play the metalligand redox equilibrium and use it as a base for molecular memory is given in: A. Sokołowski, W. Grochala, J. Mol. Model. 2005, 11, 278-287.
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115141-1 to -14
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For atomic DOS analysis of higher silver oxides, AgO i.e. Ag(I))Ag(III)O2, and Ag(III)2O3 cf.: J. P. Allen, D. O. Scanlon, G. W. Watson, Phys. Rev. B 2011, 84, 115141-1 to -14.
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This simple tool was first introduced in the comparative study of CaCuO2 and hypothetical flat-layer AgF2 and it served to emphasize similarities between both compounds: W. Grochala, Scripta Mater., 2006, 55, 811-814.
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