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Volumn , Issue 16, 2011, Pages 2499-2507

Silver(II) fluorosulfate: A thermally fragile ferromagnetic derivative of divalent silver in an oxa-ligand environment

Author keywords

Density functional calculations; Fluorosulfate; Oxidation; Silver

Indexed keywords

ATOMS; CHEMICAL BONDS; CRYSTAL ATOMIC STRUCTURE; ELECTRON SPIN RESONANCE SPECTROSCOPY; ENERGY GAP; FERROMAGNETIC MATERIALS; FERROMAGNETISM; MAGNETIC MOMENTS; SILVER COMPOUNDS; THERMOGRAVIMETRIC ANALYSIS;

EID: 79956334702     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201100077     Document Type: Article
Times cited : (23)

References (37)
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    • 15944382970 scopus 로고    scopus 로고
    • manuscript submitted
    • P. J. Malinowski, Z. Mazej, M. Derzsi, Z. JagličiĆ, J. Szydłowska, T. Gilewski, W. Grochala, CrystEngComm, manuscript submitted.
    • CrystEngComm
    • Malinowski, P.J.1
  • 15
    • 85153324574 scopus 로고    scopus 로고
    • note
    • 6). The angles were restrained at 113 (O-S-O) and 105° (O-S-F), whereas the distances at 1.42 Å (for S=O bonds, O is attached weakly to Ag at separation >2.4 Å), 1.48 Å (for S-O bonds, O is attached stronger to Ag at separation <2.2 Å) and 1.55 Å (for S-F bonds). The strength of the restraints allowed for a typical deviation of bond lengths of 0.005 Å and up to 5° for bond angles.
  • 20
    • 85153292007 scopus 로고    scopus 로고
    • note
    • 2 is thermally unstable and it partly decomposes even upon delicate grinding, which was necessary to obtain a good-quality IR spectrum and to load the capillary for Raman investigations. This spontaneous decomposition also occurs in the red laser beam used to excite the Raman spectra, so a low laser power (0.17 mW) was used to minimize this effect.
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    • 85153220585 scopus 로고    scopus 로고
    • MSc Thesis, Faculty of Chemistry, University of Warsaw
    • P. J. Malinowski, MSc Thesis, Faculty of Chemistry, University of Warsaw, 2008.
    • (2008)
    • Malinowski, P.J.1
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    • 85153253992 scopus 로고    scopus 로고
    • note
    • 2 is similar.
  • 27
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    • MSc Thesis, Faculty of Chemistry, University of Warsaw
    • D. Grzybowska, MSc Thesis, Faculty of Chemistry, University of Warsaw, 2007.
    • (2007)
    • Grzybowska, D.1
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    • 85153273778 scopus 로고    scopus 로고
    • note
    • The LSDA+U calculation leads to an overestimated value of J of +6.4 meV per FU.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.